Application of novel metal–organic frameworks containing sulfonic acid pendings in synthesis of chromeno[4,3-d]pyrimidines via back to back anomeric based oxidation
Through task-specific design and synthesis of mesoporous catalysts, we introduce a novel metal–organic framework serving as a heterogeneous catalyst. In this study, Co(BDC-NH(CH2)3SO3H was meticulously prepared through the condensation reaction of 1,4-butane sultone and Co(BDC-NH2) utilizing a post-...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2024-03-01
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| Series: | Arabian Journal of Chemistry |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S1878535224000376 |
| _version_ | 1827351345313611776 |
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| author | Fatemeh Jalili Hassan Sepehrmansourie Mahmoud Zarei Mohammad Ali Zolfigol Ardeshir Khazaei Mohammad Ali As'Habi |
| author_facet | Fatemeh Jalili Hassan Sepehrmansourie Mahmoud Zarei Mohammad Ali Zolfigol Ardeshir Khazaei Mohammad Ali As'Habi |
| author_sort | Fatemeh Jalili |
| collection | DOAJ |
| description | Through task-specific design and synthesis of mesoporous catalysts, we introduce a novel metal–organic framework serving as a heterogeneous catalyst. In this study, Co(BDC-NH(CH2)3SO3H was meticulously prepared through the condensation reaction of 1,4-butane sultone and Co(BDC-NH2) utilizing a post-modification method. The thorough examination of these parameters ensures a detailed understanding of the catalyst's properties. Subsequently, the catalytic activity was explored in the synthesis of chromeno[4,3-d]pyrimidine derivatives employing a cooperative vinylogous anomeric-based oxidation mechanism. This research not only presents a new and efficient catalyst but also contributes valuable insights into the synthesis of biologically relevant chromeno[4,3-d]pyrimidine derivatives. |
| first_indexed | 2024-03-08T02:01:42Z |
| format | Article |
| id | doaj.art-83769b3d864f42fcbd1bf91d249354c9 |
| institution | Directory Open Access Journal |
| issn | 1878-5352 |
| language | English |
| last_indexed | 2024-03-08T02:01:42Z |
| publishDate | 2024-03-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Arabian Journal of Chemistry |
| spelling | doaj.art-83769b3d864f42fcbd1bf91d249354c92024-02-14T05:16:14ZengElsevierArabian Journal of Chemistry1878-53522024-03-01173105635Application of novel metal–organic frameworks containing sulfonic acid pendings in synthesis of chromeno[4,3-d]pyrimidines via back to back anomeric based oxidationFatemeh Jalili0Hassan Sepehrmansourie1Mahmoud Zarei2Mohammad Ali Zolfigol3Ardeshir Khazaei4Mohammad Ali As'Habi5Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali-Sina University, 6517838965 Hamedan, IranDepartment of Organic Chemistry, Faculty of Chemistry, Bu-Ali-Sina University, 6517838965 Hamedan, IranDepartment of Chemistry, Faculty of Science, University of Qom, Qom 37185-359, IranDepartment of Organic Chemistry, Faculty of Chemistry, Bu-Ali-Sina University, 6517838965 Hamedan, IranDepartment of Organic Chemistry, Faculty of Chemistry, Bu-Ali-Sina University, 6517838965 Hamedan, IranDepartment of Phytochemistry, Medicinal Plant and Drugs Research Institute, Shahid Beheshti University, Evin, Tehran 1983963113, IranThrough task-specific design and synthesis of mesoporous catalysts, we introduce a novel metal–organic framework serving as a heterogeneous catalyst. In this study, Co(BDC-NH(CH2)3SO3H was meticulously prepared through the condensation reaction of 1,4-butane sultone and Co(BDC-NH2) utilizing a post-modification method. The thorough examination of these parameters ensures a detailed understanding of the catalyst's properties. Subsequently, the catalytic activity was explored in the synthesis of chromeno[4,3-d]pyrimidine derivatives employing a cooperative vinylogous anomeric-based oxidation mechanism. This research not only presents a new and efficient catalyst but also contributes valuable insights into the synthesis of biologically relevant chromeno[4,3-d]pyrimidine derivatives.http://www.sciencedirect.com/science/article/pii/S1878535224000376Anomeric effectChromeno[4,3-d]pyrimidinsCooperative vinylogous anomeric-based oxidationCo(BDC-NH(CH2)4SO3H)Heterogeneous catalystMetal-organic frameworks (MOFs) |
| spellingShingle | Fatemeh Jalili Hassan Sepehrmansourie Mahmoud Zarei Mohammad Ali Zolfigol Ardeshir Khazaei Mohammad Ali As'Habi Application of novel metal–organic frameworks containing sulfonic acid pendings in synthesis of chromeno[4,3-d]pyrimidines via back to back anomeric based oxidation Arabian Journal of Chemistry Anomeric effect Chromeno[4,3-d]pyrimidins Cooperative vinylogous anomeric-based oxidation Co(BDC-NH(CH2)4SO3H) Heterogeneous catalyst Metal-organic frameworks (MOFs) |
| title | Application of novel metal–organic frameworks containing sulfonic acid pendings in synthesis of chromeno[4,3-d]pyrimidines via back to back anomeric based oxidation |
| title_full | Application of novel metal–organic frameworks containing sulfonic acid pendings in synthesis of chromeno[4,3-d]pyrimidines via back to back anomeric based oxidation |
| title_fullStr | Application of novel metal–organic frameworks containing sulfonic acid pendings in synthesis of chromeno[4,3-d]pyrimidines via back to back anomeric based oxidation |
| title_full_unstemmed | Application of novel metal–organic frameworks containing sulfonic acid pendings in synthesis of chromeno[4,3-d]pyrimidines via back to back anomeric based oxidation |
| title_short | Application of novel metal–organic frameworks containing sulfonic acid pendings in synthesis of chromeno[4,3-d]pyrimidines via back to back anomeric based oxidation |
| title_sort | application of novel metal organic frameworks containing sulfonic acid pendings in synthesis of chromeno 4 3 d pyrimidines via back to back anomeric based oxidation |
| topic | Anomeric effect Chromeno[4,3-d]pyrimidins Cooperative vinylogous anomeric-based oxidation Co(BDC-NH(CH2)4SO3H) Heterogeneous catalyst Metal-organic frameworks (MOFs) |
| url | http://www.sciencedirect.com/science/article/pii/S1878535224000376 |
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