Laser Terahertz Emission Microscope for Imaging Grain Heterogeneity: A Case Study of CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub> Perovskite Semiconductors

Strong terahertz (THz) emission from the methylammonium lead iodide (MAPbI<sub>3</sub>) perovskite semiconductors has been observed following above-bandgap photoexcitation, yet local THz responses of crystalline microstructures are absent. We implement laser THz emission microscope (LTEM...

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Bibliographic Details
Main Authors: Zhaoyu Liu, Liang Luo, Joongmok Park, Richard H. J. Kim, Zhaoning Song, Deniz Turan, Mona Jarrahi, Yanfa Yan, Jigang Wang
Format: Article
Language:English
Published: MDPI AG 2022-10-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/12/10/1462
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Summary:Strong terahertz (THz) emission from the methylammonium lead iodide (MAPbI<sub>3</sub>) perovskite semiconductors has been observed following above-bandgap photoexcitation, yet local THz responses of crystalline microstructures are absent. We implement laser THz emission microscope (LTEM), yet-to-be applied to the perovskite semiconductors, as a novel and complementary tool to evaluate the electronic and grain heterogeneity of MAPbI<sub>3</sub> thin films. Two MAPbI<sub>3</sub> samples with different grain sizes are studied. Using this approach, we show that the one with a larger grain size gives more uniform THz radiation. More significant spatial THz intensity fluctuation is observed for the sample with a smaller grain size.
ISSN:2073-4352