Bis[triaqua(1H-1,2,4-triazole-3,5-dicarboxylato-κ2O3,N4)copper(II)] di-μ-aqua-bis[diaqua(1H-1,2,4-triazole-3,5-dicarboxylato-κ2O3,N4)copper(II)]
In the title compound, [Cu(C4HN3O4)(H2O)3]2[Cu2(C4HN3O4)2(H2O)6], both monomeric and dimeric molecules are present in the solid state. In the monomeric compound, the CuII atom is five-coordinated in a square-pyramidal configuration by one O atom and one N atom from one 1H-1,2,4-triazole-3,5-dicarbox...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809026993 |
| _version_ | 1819281463654219776 |
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| author | Qiu Jin Pu-Hui Xie Xin Li Li-Xia Xie |
| author_facet | Qiu Jin Pu-Hui Xie Xin Li Li-Xia Xie |
| author_sort | Qiu Jin |
| collection | DOAJ |
| description | In the title compound, [Cu(C4HN3O4)(H2O)3]2[Cu2(C4HN3O4)2(H2O)6], both monomeric and dimeric molecules are present in the solid state. In the monomeric compound, the CuII atom is five-coordinated in a square-pyramidal configuration by one O atom and one N atom from one 1H-1,2,4-triazole-3,5-dicarboxylate (TZDCA2−) ligand and three O atoms from water molecules. In the centrosymmetric binuclear complex, each CuII atom is six-coordinated in an octahedral geometry by one O atom and one N atom from one TZDCA2− ligand and four O atoms from water molecules, two of which bridge the CuII atoms. In the structure, there are intramolecular O—H...O and N—H...O hydrogen bonds, and in the crystal, intermolecular O—H...O, O—H...N and N—H...O hydrogen bonds link symmetry-related molecules, forming a three-dimensional supramolecular structure. |
| first_indexed | 2024-12-24T01:00:06Z |
| format | Article |
| id | doaj.art-839a56b3c0614fa39bc47437ff863039 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T01:00:06Z |
| publishDate | 2009-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-839a56b3c0614fa39bc47437ff8630392022-12-21T17:23:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658m928m92910.1107/S1600536809026993Bis[triaqua(1H-1,2,4-triazole-3,5-dicarboxylato-κ2O3,N4)copper(II)] di-μ-aqua-bis[diaqua(1H-1,2,4-triazole-3,5-dicarboxylato-κ2O3,N4)copper(II)]Qiu JinPu-Hui XieXin LiLi-Xia XieIn the title compound, [Cu(C4HN3O4)(H2O)3]2[Cu2(C4HN3O4)2(H2O)6], both monomeric and dimeric molecules are present in the solid state. In the monomeric compound, the CuII atom is five-coordinated in a square-pyramidal configuration by one O atom and one N atom from one 1H-1,2,4-triazole-3,5-dicarboxylate (TZDCA2−) ligand and three O atoms from water molecules. In the centrosymmetric binuclear complex, each CuII atom is six-coordinated in an octahedral geometry by one O atom and one N atom from one TZDCA2− ligand and four O atoms from water molecules, two of which bridge the CuII atoms. In the structure, there are intramolecular O—H...O and N—H...O hydrogen bonds, and in the crystal, intermolecular O—H...O, O—H...N and N—H...O hydrogen bonds link symmetry-related molecules, forming a three-dimensional supramolecular structure.http://scripts.iucr.org/cgi-bin/paper?S1600536809026993 |
| spellingShingle | Qiu Jin Pu-Hui Xie Xin Li Li-Xia Xie Bis[triaqua(1H-1,2,4-triazole-3,5-dicarboxylato-κ2O3,N4)copper(II)] di-μ-aqua-bis[diaqua(1H-1,2,4-triazole-3,5-dicarboxylato-κ2O3,N4)copper(II)] Acta Crystallographica Section E |
| title | Bis[triaqua(1H-1,2,4-triazole-3,5-dicarboxylato-κ2O3,N4)copper(II)] di-μ-aqua-bis[diaqua(1H-1,2,4-triazole-3,5-dicarboxylato-κ2O3,N4)copper(II)] |
| title_full | Bis[triaqua(1H-1,2,4-triazole-3,5-dicarboxylato-κ2O3,N4)copper(II)] di-μ-aqua-bis[diaqua(1H-1,2,4-triazole-3,5-dicarboxylato-κ2O3,N4)copper(II)] |
| title_fullStr | Bis[triaqua(1H-1,2,4-triazole-3,5-dicarboxylato-κ2O3,N4)copper(II)] di-μ-aqua-bis[diaqua(1H-1,2,4-triazole-3,5-dicarboxylato-κ2O3,N4)copper(II)] |
| title_full_unstemmed | Bis[triaqua(1H-1,2,4-triazole-3,5-dicarboxylato-κ2O3,N4)copper(II)] di-μ-aqua-bis[diaqua(1H-1,2,4-triazole-3,5-dicarboxylato-κ2O3,N4)copper(II)] |
| title_short | Bis[triaqua(1H-1,2,4-triazole-3,5-dicarboxylato-κ2O3,N4)copper(II)] di-μ-aqua-bis[diaqua(1H-1,2,4-triazole-3,5-dicarboxylato-κ2O3,N4)copper(II)] |
| title_sort | bis triaqua 1h 1 2 4 triazole 3 5 dicarboxylato amp 954 2o3 n4 copper ii di amp 956 aqua bis diaqua 1h 1 2 4 triazole 3 5 dicarboxylato amp 954 2o3 n4 copper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809026993 |
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