Multi-Scale Analysis of the Dependence of Water Quality on Land Use Using Linear and Mixed Models

Land use influences water quality in streams at different spatial scales and varies in time and space. Water quality has long been associated with agricultural and urban land uses in catchments. The effects of developed, forest, pasture, and agricultural land use on nitrogen, nitrate, and nitrite (N...

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Main Authors: Johann Alexander Vera Mercado, Bernard Engel
Format: Article
Language:English
Published: MDPI AG 2021-09-01
Series:Water
Subjects:
Online Access:https://www.mdpi.com/2073-4441/13/19/2618
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author Johann Alexander Vera Mercado
Bernard Engel
author_facet Johann Alexander Vera Mercado
Bernard Engel
author_sort Johann Alexander Vera Mercado
collection DOAJ
description Land use influences water quality in streams at different spatial scales and varies in time and space. Water quality has long been associated with agricultural and urban land uses in catchments. The effects of developed, forest, pasture, and agricultural land use on nitrogen, nitrate, and nitrite (NNN); total phosphorus (TP); total suspended solids (TSS); chemical oxygen demand (COD); dissolved oxygen (DO) and total Kjeldahl nitrogen (TKN) concentrations and their sensitivity were quantified to spatial pattern differences. The linear mixed modeling framework was used to examine the importance of spatial extent on models with water quality parameters as the response variable and land use types as the predictor variable. The results indicated that land use categories on different water quality parameters were significant and dependent on the selected spatial scales. Land use exhibited a strong association with total phosphorus and total suspended solids for close reach distances. Phosphorus is not highly soluble, and it binds strongly to fine soil particles, which are transported by water via runoff. Nitrogen, nitrate, and nitrite, dissolved oxygen, chemical oxygen demand, and total Kjeldahl nitrogen concentrations were better predicted for further reach distances, such as 45 or 50 km, where the best model of nitrogen, nitrate, and nitrite is consistent with the high mobility of NO<sub>3</sub><sup>−</sup>.
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spelling doaj.art-839b6e5ddddc45a78d11240f227b3abc2023-11-22T16:59:57ZengMDPI AGWater2073-44412021-09-011319261810.3390/w13192618Multi-Scale Analysis of the Dependence of Water Quality on Land Use Using Linear and Mixed ModelsJohann Alexander Vera Mercado0Bernard Engel1Department of Agricultural & Biological Engineering, Purdue University, West Lafayette, IN 47906, USADepartment of Agricultural & Biological Engineering, Purdue University, West Lafayette, IN 47906, USALand use influences water quality in streams at different spatial scales and varies in time and space. Water quality has long been associated with agricultural and urban land uses in catchments. The effects of developed, forest, pasture, and agricultural land use on nitrogen, nitrate, and nitrite (NNN); total phosphorus (TP); total suspended solids (TSS); chemical oxygen demand (COD); dissolved oxygen (DO) and total Kjeldahl nitrogen (TKN) concentrations and their sensitivity were quantified to spatial pattern differences. The linear mixed modeling framework was used to examine the importance of spatial extent on models with water quality parameters as the response variable and land use types as the predictor variable. The results indicated that land use categories on different water quality parameters were significant and dependent on the selected spatial scales. Land use exhibited a strong association with total phosphorus and total suspended solids for close reach distances. Phosphorus is not highly soluble, and it binds strongly to fine soil particles, which are transported by water via runoff. Nitrogen, nitrate, and nitrite, dissolved oxygen, chemical oxygen demand, and total Kjeldahl nitrogen concentrations were better predicted for further reach distances, such as 45 or 50 km, where the best model of nitrogen, nitrate, and nitrite is consistent with the high mobility of NO<sub>3</sub><sup>−</sup>.https://www.mdpi.com/2073-4441/13/19/2618land uselinear mixed modelspatial scale effectswater quality
spellingShingle Johann Alexander Vera Mercado
Bernard Engel
Multi-Scale Analysis of the Dependence of Water Quality on Land Use Using Linear and Mixed Models
Water
land use
linear mixed model
spatial scale effects
water quality
title Multi-Scale Analysis of the Dependence of Water Quality on Land Use Using Linear and Mixed Models
title_full Multi-Scale Analysis of the Dependence of Water Quality on Land Use Using Linear and Mixed Models
title_fullStr Multi-Scale Analysis of the Dependence of Water Quality on Land Use Using Linear and Mixed Models
title_full_unstemmed Multi-Scale Analysis of the Dependence of Water Quality on Land Use Using Linear and Mixed Models
title_short Multi-Scale Analysis of the Dependence of Water Quality on Land Use Using Linear and Mixed Models
title_sort multi scale analysis of the dependence of water quality on land use using linear and mixed models
topic land use
linear mixed model
spatial scale effects
water quality
url https://www.mdpi.com/2073-4441/13/19/2618
work_keys_str_mv AT johannalexanderveramercado multiscaleanalysisofthedependenceofwaterqualityonlanduseusinglinearandmixedmodels
AT bernardengel multiscaleanalysisofthedependenceofwaterqualityonlanduseusinglinearandmixedmodels