Molecular and morphological characterization of hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose
The objective of this work was to characterize the morphology and molecular composition of the hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose. The produced hydrochar consists mainly of aggregate microspheres with about 2.0 µm in diameter, with aliphatic and aromatic...
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Format: | Article |
Language: | English |
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Embrapa Informação Tecnológica
2012-05-01
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Series: | Pesquisa Agropecuária Brasileira |
Subjects: | |
Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-204X2012000500008&lng=en&tlng=en |
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author | Marcela Guiotoku Fabricio Augusto Hansel Etelvino Henrique Novotny Claudia Maria Branco de Freitas Maia |
author_facet | Marcela Guiotoku Fabricio Augusto Hansel Etelvino Henrique Novotny Claudia Maria Branco de Freitas Maia |
author_sort | Marcela Guiotoku |
collection | DOAJ |
description | The objective of this work was to characterize the morphology and molecular composition of the hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose. The produced hydrochar consists mainly of aggregate microspheres with about 2.0 µm in diameter, with aliphatic and aromatic structures and the presence of carbonyl functional groups. The aromatic groups are formed mainly by benzofuran-like structures, being chemically different from common cellulose char. Microwave-assisted hydrothermal carbonization yields a functionalized carbon-rich material similar to that produced by the conventional hydrothermal process. |
first_indexed | 2024-12-21T13:28:54Z |
format | Article |
id | doaj.art-83a86d9859624b55b7c80eaa8b7208d0 |
institution | Directory Open Access Journal |
issn | 1678-3921 |
language | English |
last_indexed | 2024-12-21T13:28:54Z |
publishDate | 2012-05-01 |
publisher | Embrapa Informação Tecnológica |
record_format | Article |
series | Pesquisa Agropecuária Brasileira |
spelling | doaj.art-83a86d9859624b55b7c80eaa8b7208d02022-12-21T19:02:22ZengEmbrapa Informação TecnológicaPesquisa Agropecuária Brasileira1678-39212012-05-0147568769210.1590/S0100-204X2012000500008S0100-204X2012000500008Molecular and morphological characterization of hydrochar produced by microwave-assisted hydrothermal carbonization of celluloseMarcela Guiotoku0Fabricio Augusto Hansel1Etelvino Henrique Novotny2Claudia Maria Branco de Freitas Maia3EmbrapaEmbrapaEmbrapaEmbrapaThe objective of this work was to characterize the morphology and molecular composition of the hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose. The produced hydrochar consists mainly of aggregate microspheres with about 2.0 µm in diameter, with aliphatic and aromatic structures and the presence of carbonyl functional groups. The aromatic groups are formed mainly by benzofuran-like structures, being chemically different from common cellulose char. Microwave-assisted hydrothermal carbonization yields a functionalized carbon-rich material similar to that produced by the conventional hydrothermal process.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-204X2012000500008&lng=en&tlng=enterra preta de índio"biochar"carvão vegetalcromatografia gasosaespectrometria de massaressonância magnética nuclear |
spellingShingle | Marcela Guiotoku Fabricio Augusto Hansel Etelvino Henrique Novotny Claudia Maria Branco de Freitas Maia Molecular and morphological characterization of hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose Pesquisa Agropecuária Brasileira terra preta de índio "biochar" carvão vegetal cromatografia gasosa espectrometria de massa ressonância magnética nuclear |
title | Molecular and morphological characterization of hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose |
title_full | Molecular and morphological characterization of hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose |
title_fullStr | Molecular and morphological characterization of hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose |
title_full_unstemmed | Molecular and morphological characterization of hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose |
title_short | Molecular and morphological characterization of hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose |
title_sort | molecular and morphological characterization of hydrochar produced by microwave assisted hydrothermal carbonization of cellulose |
topic | terra preta de índio "biochar" carvão vegetal cromatografia gasosa espectrometria de massa ressonância magnética nuclear |
url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-204X2012000500008&lng=en&tlng=en |
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