Cathodic Aromatic C,C Cross-Coupling Reaction via Single Electron Transfer Pathway
We have successfully developed a novel cathodic cross-coupling reaction of aryl halides with arenes. Utilization of the cathodic single electron transfer (SET) mechanism for activation of aryl halides enables the cross-coupling reaction to proceed without the need for any transition metal catalysts...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2017-03-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/22/3/413 |
| _version_ | 1819139318574219264 |
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| author | Yang Qu Hiroyuki Tateno Yoshimasa Matsumura Tsuneo Kashiwagi Mahito Atobe |
| author_facet | Yang Qu Hiroyuki Tateno Yoshimasa Matsumura Tsuneo Kashiwagi Mahito Atobe |
| author_sort | Yang Qu |
| collection | DOAJ |
| description | We have successfully developed a novel cathodic cross-coupling reaction of aryl halides with arenes. Utilization of the cathodic single electron transfer (SET) mechanism for activation of aryl halides enables the cross-coupling reaction to proceed without the need for any transition metal catalysts or single electron donors in a mild condition. The SET from a cathode to an aryl halide initiates a radical chain by giving an anion radical of the aryl halide. The following propagation cycle also consists entirely of anion radical intermediates. |
| first_indexed | 2024-12-22T11:20:46Z |
| format | Article |
| id | doaj.art-83bf8457570e48b2a009f9b9d212f751 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-22T11:20:46Z |
| publishDate | 2017-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-83bf8457570e48b2a009f9b9d212f7512022-12-21T18:27:53ZengMDPI AGMolecules1420-30492017-03-0122341310.3390/molecules22030413molecules22030413Cathodic Aromatic C,C Cross-Coupling Reaction via Single Electron Transfer PathwayYang Qu0Hiroyuki Tateno1Yoshimasa Matsumura2Tsuneo Kashiwagi3Mahito Atobe4Graduate School of Environment and Information Sciences, Yokohama National University, 79-7, Tokiwadai, Hodogaya-ku, Yokohama 240851, JapanGraduate School of Environment and Information Sciences, Yokohama National University, 79-7, Tokiwadai, Hodogaya-ku, Yokohama 240851, JapanGraduate School of Environment and Information Sciences, Yokohama National University, 79-7, Tokiwadai, Hodogaya-ku, Yokohama 240851, JapanGraduate School of Environment and Information Sciences, Yokohama National University, 79-7, Tokiwadai, Hodogaya-ku, Yokohama 240851, JapanGraduate School of Environment and Information Sciences, Yokohama National University, 79-7, Tokiwadai, Hodogaya-ku, Yokohama 240851, JapanWe have successfully developed a novel cathodic cross-coupling reaction of aryl halides with arenes. Utilization of the cathodic single electron transfer (SET) mechanism for activation of aryl halides enables the cross-coupling reaction to proceed without the need for any transition metal catalysts or single electron donors in a mild condition. The SET from a cathode to an aryl halide initiates a radical chain by giving an anion radical of the aryl halide. The following propagation cycle also consists entirely of anion radical intermediates.http://www.mdpi.com/1420-3049/22/3/413electrochemical synthesissingle electron transferC,C cross-coupling |
| spellingShingle | Yang Qu Hiroyuki Tateno Yoshimasa Matsumura Tsuneo Kashiwagi Mahito Atobe Cathodic Aromatic C,C Cross-Coupling Reaction via Single Electron Transfer Pathway Molecules electrochemical synthesis single electron transfer C,C cross-coupling |
| title | Cathodic Aromatic C,C Cross-Coupling Reaction via Single Electron Transfer Pathway |
| title_full | Cathodic Aromatic C,C Cross-Coupling Reaction via Single Electron Transfer Pathway |
| title_fullStr | Cathodic Aromatic C,C Cross-Coupling Reaction via Single Electron Transfer Pathway |
| title_full_unstemmed | Cathodic Aromatic C,C Cross-Coupling Reaction via Single Electron Transfer Pathway |
| title_short | Cathodic Aromatic C,C Cross-Coupling Reaction via Single Electron Transfer Pathway |
| title_sort | cathodic aromatic c c cross coupling reaction via single electron transfer pathway |
| topic | electrochemical synthesis single electron transfer C,C cross-coupling |
| url | http://www.mdpi.com/1420-3049/22/3/413 |
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