cis-(9S,10S)-Methyl 1-propyl-1,2,3,4-tetrahydro-β-carboline-3-carboxylate
The title compound, C16H20N2O2, was synthesized from (S)-tryptophan methyl ester hydrochloride and butyraldehyde. The absolute configuration 9S,10S was assigned on the basis of the unchanging chirality of the C9 centre. The NH group of the indole ring is involved in intermolecular N—H...O...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807066020 |
| _version_ | 1818941318417612800 |
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| author | Naeema Khan Andreas Fischer Sadaf Saeed Mashooda Hasan Samina Alam |
| author_facet | Naeema Khan Andreas Fischer Sadaf Saeed Mashooda Hasan Samina Alam |
| author_sort | Naeema Khan |
| collection | DOAJ |
| description | The title compound, C16H20N2O2, was synthesized from (S)-tryptophan methyl ester hydrochloride and butyraldehyde. The absolute configuration 9S,10S was assigned on the basis of the unchanging chirality of the C9 centre. The NH group of the indole ring is involved in intermolecular N—H...O hydrogen bonding, while the NH group of the six-membered ring is not. This latter ring has a half-chair conformation. |
| first_indexed | 2024-12-20T06:53:38Z |
| format | Article |
| id | doaj.art-83dd699310e44a1c868a897bf15389e2 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T06:53:38Z |
| publishDate | 2008-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-83dd699310e44a1c868a897bf15389e22022-12-21T19:49:27ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642o361o36110.1107/S1600536807066020cis-(9S,10S)-Methyl 1-propyl-1,2,3,4-tetrahydro-β-carboline-3-carboxylateNaeema KhanAndreas FischerSadaf SaeedMashooda HasanSamina AlamThe title compound, C16H20N2O2, was synthesized from (S)-tryptophan methyl ester hydrochloride and butyraldehyde. The absolute configuration 9S,10S was assigned on the basis of the unchanging chirality of the C9 centre. The NH group of the indole ring is involved in intermolecular N—H...O hydrogen bonding, while the NH group of the six-membered ring is not. This latter ring has a half-chair conformation.http://scripts.iucr.org/cgi-bin/paper?S1600536807066020 |
| spellingShingle | Naeema Khan Andreas Fischer Sadaf Saeed Mashooda Hasan Samina Alam cis-(9S,10S)-Methyl 1-propyl-1,2,3,4-tetrahydro-β-carboline-3-carboxylate Acta Crystallographica Section E |
| title | cis-(9S,10S)-Methyl 1-propyl-1,2,3,4-tetrahydro-β-carboline-3-carboxylate |
| title_full | cis-(9S,10S)-Methyl 1-propyl-1,2,3,4-tetrahydro-β-carboline-3-carboxylate |
| title_fullStr | cis-(9S,10S)-Methyl 1-propyl-1,2,3,4-tetrahydro-β-carboline-3-carboxylate |
| title_full_unstemmed | cis-(9S,10S)-Methyl 1-propyl-1,2,3,4-tetrahydro-β-carboline-3-carboxylate |
| title_short | cis-(9S,10S)-Methyl 1-propyl-1,2,3,4-tetrahydro-β-carboline-3-carboxylate |
| title_sort | cis 9s 10s methyl 1 propyl 1 2 3 4 tetrahydro 946 carboline 3 carboxylate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536807066020 |
| work_keys_str_mv | AT naeemakhan cis9s10smethyl1propyl1234tetrahydro946carboline3carboxylate AT andreasfischer cis9s10smethyl1propyl1234tetrahydro946carboline3carboxylate AT sadafsaeed cis9s10smethyl1propyl1234tetrahydro946carboline3carboxylate AT mashoodahasan cis9s10smethyl1propyl1234tetrahydro946carboline3carboxylate AT saminaalam cis9s10smethyl1propyl1234tetrahydro946carboline3carboxylate |