Comparison of Pesticide Residue Levels in Red Wines from Canary Islands, Iberian Peninsula, and Cape Verde
In this work, the QuEChERS method coupled to liquid chromatography-time-of flight-mass spectrometry and gas chromatography-triple quadrupole-mass spectrometry were applied for the evaluation of pesticide residues and risk assessment in red wines. The methodologies were successfully validated for 173...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2020-10-01
|
| Series: | Foods |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2304-8158/9/11/1555 |
| _version_ | 1797549681777049600 |
|---|---|
| author | Álvaro Santana-Mayor Ruth Rodríguez-Ramos Bárbara Socas-Rodríguez Carlos Díaz-Romero Miguel Ángel Rodríguez-Delgado |
| author_facet | Álvaro Santana-Mayor Ruth Rodríguez-Ramos Bárbara Socas-Rodríguez Carlos Díaz-Romero Miguel Ángel Rodríguez-Delgado |
| author_sort | Álvaro Santana-Mayor |
| collection | DOAJ |
| description | In this work, the QuEChERS method coupled to liquid chromatography-time-of flight-mass spectrometry and gas chromatography-triple quadrupole-mass spectrometry were applied for the evaluation of pesticide residues and risk assessment in red wines. The methodologies were successfully validated for 173 pesticides. Recovery values were in the range 75–100% for almost all pesticides and limits of quantification were between 2.60 and 21.39 µg/kg, which are in good agreement with the maximum residue limits (MRLs) established by the European Commission for pesticides in wine grapes. Finally, the analysis of 84 red wine samples from the Canary Islands, the Iberian Peninsula, and Cape Verde was carried out, which found the presence of 31 pesticide residues. However, the risk assessment disclosed that despite the large number of pesticides and the concentrations found, which in some cases exceeded the MRLs, the consumption of these wines, without considering a possible cumulative effect, does not entail a risk to the consumers. |
| first_indexed | 2024-03-10T15:18:52Z |
| format | Article |
| id | doaj.art-83fc89cc7eff4932b51aeb8e16c90590 |
| institution | Directory Open Access Journal |
| issn | 2304-8158 |
| language | English |
| last_indexed | 2024-03-10T15:18:52Z |
| publishDate | 2020-10-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Foods |
| spelling | doaj.art-83fc89cc7eff4932b51aeb8e16c905902023-11-20T18:42:40ZengMDPI AGFoods2304-81582020-10-01911155510.3390/foods9111555Comparison of Pesticide Residue Levels in Red Wines from Canary Islands, Iberian Peninsula, and Cape VerdeÁlvaro Santana-Mayor0Ruth Rodríguez-Ramos1Bárbara Socas-Rodríguez2Carlos Díaz-Romero3Miguel Ángel Rodríguez-Delgado4Departamento de Química, Unidad Departamental de Química Analítica, Facultad de Ciencias, Universidad de La Laguna (ULL), Avenida Astrofísico Francisco Sánchez, s/n. 38206 San Cristóbal de La Laguna, Tenerife, SpainDepartamento de Química, Unidad Departamental de Química Analítica, Facultad de Ciencias, Universidad de La Laguna (ULL), Avenida Astrofísico Francisco Sánchez, s/n. 38206 San Cristóbal de La Laguna, Tenerife, SpainLaboratory of Foodomics, Institute of Food Science Research, CIAL, CSIC, Nicolás Cabrera 9, 28049 Madrid, SpainDepartamento de Ingeniería Química y Tecnología Farmacéutica, Unidad Departamental de Nutrición y Bromatología, Facultad de Ciencias, Universidad de La Laguna (ULL), Avenida Astrofísico Francisco Sánchez, s/n. 38206 San Cristóbal de La Laguna, Tenerife, SpainDepartamento de Química, Unidad Departamental de Química Analítica, Facultad de Ciencias, Universidad de La Laguna (ULL), Avenida Astrofísico Francisco Sánchez, s/n. 38206 San Cristóbal de La Laguna, Tenerife, SpainIn this work, the QuEChERS method coupled to liquid chromatography-time-of flight-mass spectrometry and gas chromatography-triple quadrupole-mass spectrometry were applied for the evaluation of pesticide residues and risk assessment in red wines. The methodologies were successfully validated for 173 pesticides. Recovery values were in the range 75–100% for almost all pesticides and limits of quantification were between 2.60 and 21.39 µg/kg, which are in good agreement with the maximum residue limits (MRLs) established by the European Commission for pesticides in wine grapes. Finally, the analysis of 84 red wine samples from the Canary Islands, the Iberian Peninsula, and Cape Verde was carried out, which found the presence of 31 pesticide residues. However, the risk assessment disclosed that despite the large number of pesticides and the concentrations found, which in some cases exceeded the MRLs, the consumption of these wines, without considering a possible cumulative effect, does not entail a risk to the consumers.https://www.mdpi.com/2304-8158/9/11/1555organic contaminantsalcoholic beveragespesticide occurrenceagricultural contaminationMacaronesiaSpain |
| spellingShingle | Álvaro Santana-Mayor Ruth Rodríguez-Ramos Bárbara Socas-Rodríguez Carlos Díaz-Romero Miguel Ángel Rodríguez-Delgado Comparison of Pesticide Residue Levels in Red Wines from Canary Islands, Iberian Peninsula, and Cape Verde Foods organic contaminants alcoholic beverages pesticide occurrence agricultural contamination Macaronesia Spain |
| title | Comparison of Pesticide Residue Levels in Red Wines from Canary Islands, Iberian Peninsula, and Cape Verde |
| title_full | Comparison of Pesticide Residue Levels in Red Wines from Canary Islands, Iberian Peninsula, and Cape Verde |
| title_fullStr | Comparison of Pesticide Residue Levels in Red Wines from Canary Islands, Iberian Peninsula, and Cape Verde |
| title_full_unstemmed | Comparison of Pesticide Residue Levels in Red Wines from Canary Islands, Iberian Peninsula, and Cape Verde |
| title_short | Comparison of Pesticide Residue Levels in Red Wines from Canary Islands, Iberian Peninsula, and Cape Verde |
| title_sort | comparison of pesticide residue levels in red wines from canary islands iberian peninsula and cape verde |
| topic | organic contaminants alcoholic beverages pesticide occurrence agricultural contamination Macaronesia Spain |
| url | https://www.mdpi.com/2304-8158/9/11/1555 |
| work_keys_str_mv | AT alvarosantanamayor comparisonofpesticideresiduelevelsinredwinesfromcanaryislandsiberianpeninsulaandcapeverde AT ruthrodriguezramos comparisonofpesticideresiduelevelsinredwinesfromcanaryislandsiberianpeninsulaandcapeverde AT barbarasocasrodriguez comparisonofpesticideresiduelevelsinredwinesfromcanaryislandsiberianpeninsulaandcapeverde AT carlosdiazromero comparisonofpesticideresiduelevelsinredwinesfromcanaryislandsiberianpeninsulaandcapeverde AT miguelangelrodriguezdelgado comparisonofpesticideresiduelevelsinredwinesfromcanaryislandsiberianpeninsulaandcapeverde |