Environmental and cost analysis for polyhydroxyalkanoate production from glycerol byproduct: A case study from integrated soap and biodiesel plants

This work focuses on the sustainable integrated production of bioplastic, also known as Polyhydroxyalkanoate (PHA). Glycerol by-product generates from soap production and biodiesel production plant were utilized as the feedstock to overcome the current drawbacks in PHA production. Different purities...

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Main Authors: Thamasha Navodya Kolonnage, Irene Mei Leng Chew
Format: Article
Language:English
Published: Elsevier 2023-06-01
Series:Cleaner Environmental Systems
Online Access:http://www.sciencedirect.com/science/article/pii/S266678942300017X
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author Thamasha Navodya Kolonnage
Irene Mei Leng Chew
author_facet Thamasha Navodya Kolonnage
Irene Mei Leng Chew
author_sort Thamasha Navodya Kolonnage
collection DOAJ
description This work focuses on the sustainable integrated production of bioplastic, also known as Polyhydroxyalkanoate (PHA). Glycerol by-product generates from soap production and biodiesel production plant were utilized as the feedstock to overcome the current drawbacks in PHA production. Different purities of glycerol (i.e,16 wt%, 40 wt% and 60 wt%) were undergone pretreatment steps such as acidification, filtration, evaporation, hexane washing, methanol recovery and ion exchange to obtain 98 wt% of glycerol prior to PHA production. Capital of equipment purchase was estimated by using correlation and graphical method. It was found that, cost of chemical purchase for pretreatment has a high impact on the overall economy of the production. Economic feasibility of all proposed process routes was assessed by calculating the Payback period. Lastly, environmental impact of each pretreatment method was assessed by conducting an LCA by setting the annual target of 750,000 kg as the functional unit. Global warming potential, acidification potential and ecotoxicity of freshwater were chosen as the impact categories in this process. It was found that route 4 with feedstock purity of 60 wt% CG and pretreatment steps of methanol recovery, neutralization, centrifugation, water evaporation and distillation was found to be the most economically and environmentally sustainable among the assessed process routes.
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spelling doaj.art-83fdfc2d4e064038aed6f5eaa77864c02023-06-15T04:57:25ZengElsevierCleaner Environmental Systems2666-78942023-06-019100123Environmental and cost analysis for polyhydroxyalkanoate production from glycerol byproduct: A case study from integrated soap and biodiesel plantsThamasha Navodya Kolonnage0Irene Mei Leng Chew1Department of Chemical Engineering, School of Engineering, Monash University Malaysia, Jalan Lagoon Selatan, Bandar Sunway, 47500, Subang Jaya, Selangor D.E., MalaysiaCorresponding author.; Department of Chemical Engineering, School of Engineering, Monash University Malaysia, Jalan Lagoon Selatan, Bandar Sunway, 47500, Subang Jaya, Selangor D.E., MalaysiaThis work focuses on the sustainable integrated production of bioplastic, also known as Polyhydroxyalkanoate (PHA). Glycerol by-product generates from soap production and biodiesel production plant were utilized as the feedstock to overcome the current drawbacks in PHA production. Different purities of glycerol (i.e,16 wt%, 40 wt% and 60 wt%) were undergone pretreatment steps such as acidification, filtration, evaporation, hexane washing, methanol recovery and ion exchange to obtain 98 wt% of glycerol prior to PHA production. Capital of equipment purchase was estimated by using correlation and graphical method. It was found that, cost of chemical purchase for pretreatment has a high impact on the overall economy of the production. Economic feasibility of all proposed process routes was assessed by calculating the Payback period. Lastly, environmental impact of each pretreatment method was assessed by conducting an LCA by setting the annual target of 750,000 kg as the functional unit. Global warming potential, acidification potential and ecotoxicity of freshwater were chosen as the impact categories in this process. It was found that route 4 with feedstock purity of 60 wt% CG and pretreatment steps of methanol recovery, neutralization, centrifugation, water evaporation and distillation was found to be the most economically and environmentally sustainable among the assessed process routes.http://www.sciencedirect.com/science/article/pii/S266678942300017X
spellingShingle Thamasha Navodya Kolonnage
Irene Mei Leng Chew
Environmental and cost analysis for polyhydroxyalkanoate production from glycerol byproduct: A case study from integrated soap and biodiesel plants
Cleaner Environmental Systems
title Environmental and cost analysis for polyhydroxyalkanoate production from glycerol byproduct: A case study from integrated soap and biodiesel plants
title_full Environmental and cost analysis for polyhydroxyalkanoate production from glycerol byproduct: A case study from integrated soap and biodiesel plants
title_fullStr Environmental and cost analysis for polyhydroxyalkanoate production from glycerol byproduct: A case study from integrated soap and biodiesel plants
title_full_unstemmed Environmental and cost analysis for polyhydroxyalkanoate production from glycerol byproduct: A case study from integrated soap and biodiesel plants
title_short Environmental and cost analysis for polyhydroxyalkanoate production from glycerol byproduct: A case study from integrated soap and biodiesel plants
title_sort environmental and cost analysis for polyhydroxyalkanoate production from glycerol byproduct a case study from integrated soap and biodiesel plants
url http://www.sciencedirect.com/science/article/pii/S266678942300017X
work_keys_str_mv AT thamashanavodyakolonnage environmentalandcostanalysisforpolyhydroxyalkanoateproductionfromglycerolbyproductacasestudyfromintegratedsoapandbiodieselplants
AT irenemeilengchew environmentalandcostanalysisforpolyhydroxyalkanoateproductionfromglycerolbyproductacasestudyfromintegratedsoapandbiodieselplants