Methyl 2-(3-chloro-2-methylanilino)pyridine-3-carboxylate
The title compound, C14H13ClN2O2, was obtained during an attempt to grow single crystals of 4-acetylphenyl 2-[(3-chloro-2-methylphenyl)amino]nicotinate in methanol, and was probably generated by alcoholysis. Two intramolecular hydrogen bonds are formed, one between the N—H group and the carbonyl O a...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2021-05-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314621005393 |
| Summary: | The title compound, C14H13ClN2O2, was obtained during an attempt to grow single crystals of 4-acetylphenyl 2-[(3-chloro-2-methylphenyl)amino]nicotinate in methanol, and was probably generated by alcoholysis. Two intramolecular hydrogen bonds are formed, one between the N—H group and the carbonyl O atom of the ester and the other between the ortho sp2CH group of the benzene ring and the pyridine N atom. Aromatic π–π stacking [shortest centroid–centroid separation = 3.598 (2) Å] is observed in the extended structure. |
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| ISSN: | 2414-3146 |