Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetrapyridinetricopper(II)
There are two half-molecules in the asymmetric unit of the title compound, [Cu3(C13H9N2O3)2(C5H5N)4], and crystallographic inversion symmetry completes each trinuclear molecule. In both molecules, the central Cu atom (site symmetry overline{1}) adopts a distorted trans-CuO2N4 octahedral geometry, ar...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-11-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680904389X |
| _version_ | 1819281383253606400 |
|---|---|
| author | Jin-Ping Gao Wen Zhang Xue-Feng Shi Da-Cheng Li |
| author_facet | Jin-Ping Gao Wen Zhang Xue-Feng Shi Da-Cheng Li |
| author_sort | Jin-Ping Gao |
| collection | DOAJ |
| description | There are two half-molecules in the asymmetric unit of the title compound, [Cu3(C13H9N2O3)2(C5H5N)4], and crystallographic inversion symmetry completes each trinuclear molecule. In both molecules, the central Cu atom (site symmetry overline{1}) adopts a distorted trans-CuO2N4 octahedral geometry, arising from its coordination by two N,O-bidentate aroylhydrazine ligands and two pyridine molecules. The peripheral Cu atoms adopt trans-CuN2O2 square-planar coordinations arising from an N,O,O-tridentate ligand (that also bonds to the central Cu atom) and a pyridine molecule. |
| first_indexed | 2024-12-24T00:58:49Z |
| format | Article |
| id | doaj.art-84201a01fb3f492da0148c75f10eb178 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:58:49Z |
| publishDate | 2009-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-84201a01fb3f492da0148c75f10eb1782022-12-21T17:23:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1455m145510.1107/S160053680904389XBis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetrapyridinetricopper(II)Jin-Ping GaoWen ZhangXue-Feng ShiDa-Cheng LiThere are two half-molecules in the asymmetric unit of the title compound, [Cu3(C13H9N2O3)2(C5H5N)4], and crystallographic inversion symmetry completes each trinuclear molecule. In both molecules, the central Cu atom (site symmetry overline{1}) adopts a distorted trans-CuO2N4 octahedral geometry, arising from its coordination by two N,O-bidentate aroylhydrazine ligands and two pyridine molecules. The peripheral Cu atoms adopt trans-CuN2O2 square-planar coordinations arising from an N,O,O-tridentate ligand (that also bonds to the central Cu atom) and a pyridine molecule.http://scripts.iucr.org/cgi-bin/paper?S160053680904389X |
| spellingShingle | Jin-Ping Gao Wen Zhang Xue-Feng Shi Da-Cheng Li Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetrapyridinetricopper(II) Acta Crystallographica Section E |
| title | Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetrapyridinetricopper(II) |
| title_full | Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetrapyridinetricopper(II) |
| title_fullStr | Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetrapyridinetricopper(II) |
| title_full_unstemmed | Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetrapyridinetricopper(II) |
| title_short | Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetrapyridinetricopper(II) |
| title_sort | bis amp 956 n amp 8242 acetyl 1 oxidonaphthalene 2 carbohydrazidato 3 amp 8722 tetrapyridinetricopper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053680904389X |
| work_keys_str_mv | AT jinpinggao bisamp956namp8242acetyl1oxidonaphthalene2carbohydrazidato3amp8722tetrapyridinetricopperii AT wenzhang bisamp956namp8242acetyl1oxidonaphthalene2carbohydrazidato3amp8722tetrapyridinetricopperii AT xuefengshi bisamp956namp8242acetyl1oxidonaphthalene2carbohydrazidato3amp8722tetrapyridinetricopperii AT dachengli bisamp956namp8242acetyl1oxidonaphthalene2carbohydrazidato3amp8722tetrapyridinetricopperii |