Bis(nitrato-κO)(5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diaminium-κ4N1,N4,N8,N11)copper(II) dinitrate tetrahydrate
In the title compound, [Cu(NO3)2(C14H36N6)](NO3)2·4H2O, the CuII atom, lying on an inversion center, is six-coordinated in a distorted octahedral environment by four N atoms from a centrosymmetric 14-membered tetraazacyclotetradecane macrocyclic ligand and two O atoms from two nitrate a...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-07-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810023342 |
| _version_ | 1819125675751112704 |
|---|---|
| author | Xiang-Yun Liu Hong-Ying Chu |
| author_facet | Xiang-Yun Liu Hong-Ying Chu |
| author_sort | Xiang-Yun Liu |
| collection | DOAJ |
| description | In the title compound, [Cu(NO3)2(C14H36N6)](NO3)2·4H2O, the CuII atom, lying on an inversion center, is six-coordinated in a distorted octahedral environment by four N atoms from a centrosymmetric 14-membered tetraazacyclotetradecane macrocyclic ligand and two O atoms from two nitrate anions. The supramolecular network is consolidated by extensive O—H...O and N—H...O hydrogen-bonding interactions. |
| first_indexed | 2024-12-22T07:43:55Z |
| format | Article |
| id | doaj.art-842f6756368b4909b842d03551cb77c0 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T07:43:55Z |
| publishDate | 2010-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-842f6756368b4909b842d03551cb77c02022-12-21T18:33:41ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667m837m83710.1107/S1600536810023342Bis(nitrato-κO)(5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diaminium-κ4N1,N4,N8,N11)copper(II) dinitrate tetrahydrateXiang-Yun LiuHong-Ying ChuIn the title compound, [Cu(NO3)2(C14H36N6)](NO3)2·4H2O, the CuII atom, lying on an inversion center, is six-coordinated in a distorted octahedral environment by four N atoms from a centrosymmetric 14-membered tetraazacyclotetradecane macrocyclic ligand and two O atoms from two nitrate anions. The supramolecular network is consolidated by extensive O—H...O and N—H...O hydrogen-bonding interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536810023342 |
| spellingShingle | Xiang-Yun Liu Hong-Ying Chu Bis(nitrato-κO)(5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diaminium-κ4N1,N4,N8,N11)copper(II) dinitrate tetrahydrate Acta Crystallographica Section E |
| title | Bis(nitrato-κO)(5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diaminium-κ4N1,N4,N8,N11)copper(II) dinitrate tetrahydrate |
| title_full | Bis(nitrato-κO)(5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diaminium-κ4N1,N4,N8,N11)copper(II) dinitrate tetrahydrate |
| title_fullStr | Bis(nitrato-κO)(5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diaminium-κ4N1,N4,N8,N11)copper(II) dinitrate tetrahydrate |
| title_full_unstemmed | Bis(nitrato-κO)(5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diaminium-κ4N1,N4,N8,N11)copper(II) dinitrate tetrahydrate |
| title_short | Bis(nitrato-κO)(5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diaminium-κ4N1,N4,N8,N11)copper(II) dinitrate tetrahydrate |
| title_sort | bis nitrato amp 954 o 5 7 12 14 tetramethyl 1 4 8 11 tetraazacyclotetradecane 6 13 diaminium amp 954 4n1 n4 n8 n11 copper ii dinitrate tetrahydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810023342 |
| work_keys_str_mv | AT xiangyunliu bisnitratoamp954o571214tetramethyl14811tetraazacyclotetradecane613diaminiumamp9544n1n4n8n11copperiidinitratetetrahydrate AT hongyingchu bisnitratoamp954o571214tetramethyl14811tetraazacyclotetradecane613diaminiumamp9544n1n4n8n11copperiidinitratetetrahydrate |