[1,1′-Bis(diphenylphosphino)cobaltocenium-κ2P,P′]dichloridoplatinum(II) hexafluoridophosphate
The title bimetallic compound, [PtCl2{Co(C17H14P)2}]PF6, was obtained by reaction of 1,1′-bis(diphenylphosphino)cobaltocenium hexafluoridophosphate with bis(acetonitrile)dichloridoplatinum. The PtII ion is four-coordinated in a slightly distorted square-planar environment by two P atom...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809027925 |
| Summary: | The title bimetallic compound, [PtCl2{Co(C17H14P)2}]PF6, was obtained by reaction of 1,1′-bis(diphenylphosphino)cobaltocenium hexafluoridophosphate with bis(acetonitrile)dichloridoplatinum. The PtII ion is four-coordinated in a slightly distorted square-planar environment by two P atoms of the 1,1′-bis(diphenylphosphino)cobaltocenium moiety and two Cl atoms. In the crystal structure, molecules are linked by weak C—H...F and C—H...Cl hydrogen bonds. |
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| ISSN: | 1600-5368 |