Styrene Epoxidation Over Heterogeneous Manganese(III) Complexes

The manganes(III) complex functionalised with 2,3-dihydropyridazine has been encapsulated in the supercages of the NaY zeolite using two different procedures, flexible ligand and in situ complex. The parent zeolite and the encapsulated manganese(III) complexes were screened as catalysts for styrene...

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Bibliographic Details
Main Authors: Kuźniarska-Biernacka I., Lisinska-Czekaj A., Czekaj D., Alves M. José, Fonseca A. Mauricio, Neves I. Correia
Format: Article
Language:English
Published: Polish Academy of Sciences 2016-09-01
Series:Archives of Metallurgy and Materials
Online Access:http://www.degruyter.com/view/j/amm.2016.61.issue-3/amm-2016-0242/amm-2016-0242.xml?format=INT
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Summary:The manganes(III) complex functionalised with 2,3-dihydropyridazine has been encapsulated in the supercages of the NaY zeolite using two different procedures, flexible ligand and in situ complex. The parent zeolite and the encapsulated manganese(III) complexes were screened as catalysts for styrene oxidation by using t-BOOH as the oxygen source in acetonitrile. Under the optimized conditions, the catalysts exhibited moderate activity with high selectivity to benzaldehyde
ISSN:2300-1909