In situ characterizations of solid–solid interfaces in solid‐state batteries using synchrotron X‐ray techniques
Abstract The solid–solid electrode–electrolyte interface represents an important component in solid‐state batteries (SSBs), as ionic diffusion, reaction, transformation, and restructuring could all take place. As these processes strongly influence the battery performance, studying the evolution of t...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Wiley
2021-10-01
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| Series: | Carbon Energy |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/cey2.131 |
| _version_ | 1819038879106203648 |
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| author | Marcos Lucero Shen Qiu Zhenxing Feng |
| author_facet | Marcos Lucero Shen Qiu Zhenxing Feng |
| author_sort | Marcos Lucero |
| collection | DOAJ |
| description | Abstract The solid–solid electrode–electrolyte interface represents an important component in solid‐state batteries (SSBs), as ionic diffusion, reaction, transformation, and restructuring could all take place. As these processes strongly influence the battery performance, studying the evolution of the solid–solid interfaces, particularly in situ during battery operation, can provide insights to establish the structure–property relationship for SSBs. Synchrotron X‐ray techniques, owing to their unique penetration power and diverse approaches, are suitable to investigate the buried interfaces and examine structural, compositional, and morphological changes. In this review, we will discuss various surface‐sensitive synchrotron‐based scattering, spectroscopy, and imaging methods for the in situ characterization of solid–solid interfaces and how this information can be correlated to the electrochemical properties of SSBs. The goal is to overview the advantages and disadvantages of each technique by highlighting representative examples, so that similar strategies can be applied by battery researchers and beyond to study similar solid‐solid interface systems. |
| first_indexed | 2024-12-21T08:44:19Z |
| format | Article |
| id | doaj.art-84693ff9605440d89744960e1db91ad7 |
| institution | Directory Open Access Journal |
| issn | 2637-9368 |
| language | English |
| last_indexed | 2024-12-21T08:44:19Z |
| publishDate | 2021-10-01 |
| publisher | Wiley |
| record_format | Article |
| series | Carbon Energy |
| spelling | doaj.art-84693ff9605440d89744960e1db91ad72022-12-21T19:09:53ZengWileyCarbon Energy2637-93682021-10-013576278310.1002/cey2.131In situ characterizations of solid–solid interfaces in solid‐state batteries using synchrotron X‐ray techniquesMarcos Lucero0Shen Qiu1Zhenxing Feng2School of Chemical, Biological, and Environmental Engineering Oregon State University Corvallis Oregon USASchool of Chemical, Biological, and Environmental Engineering Oregon State University Corvallis Oregon USASchool of Chemical, Biological, and Environmental Engineering Oregon State University Corvallis Oregon USAAbstract The solid–solid electrode–electrolyte interface represents an important component in solid‐state batteries (SSBs), as ionic diffusion, reaction, transformation, and restructuring could all take place. As these processes strongly influence the battery performance, studying the evolution of the solid–solid interfaces, particularly in situ during battery operation, can provide insights to establish the structure–property relationship for SSBs. Synchrotron X‐ray techniques, owing to their unique penetration power and diverse approaches, are suitable to investigate the buried interfaces and examine structural, compositional, and morphological changes. In this review, we will discuss various surface‐sensitive synchrotron‐based scattering, spectroscopy, and imaging methods for the in situ characterization of solid–solid interfaces and how this information can be correlated to the electrochemical properties of SSBs. The goal is to overview the advantages and disadvantages of each technique by highlighting representative examples, so that similar strategies can be applied by battery researchers and beyond to study similar solid‐solid interface systems.https://doi.org/10.1002/cey2.131in situ characterizationssolid‐state batterysolid–solid interfacesynchrotron X‐ray |
| spellingShingle | Marcos Lucero Shen Qiu Zhenxing Feng In situ characterizations of solid–solid interfaces in solid‐state batteries using synchrotron X‐ray techniques Carbon Energy in situ characterizations solid‐state battery solid–solid interface synchrotron X‐ray |
| title | In situ characterizations of solid–solid interfaces in solid‐state batteries using synchrotron X‐ray techniques |
| title_full | In situ characterizations of solid–solid interfaces in solid‐state batteries using synchrotron X‐ray techniques |
| title_fullStr | In situ characterizations of solid–solid interfaces in solid‐state batteries using synchrotron X‐ray techniques |
| title_full_unstemmed | In situ characterizations of solid–solid interfaces in solid‐state batteries using synchrotron X‐ray techniques |
| title_short | In situ characterizations of solid–solid interfaces in solid‐state batteries using synchrotron X‐ray techniques |
| title_sort | in situ characterizations of solid solid interfaces in solid state batteries using synchrotron x ray techniques |
| topic | in situ characterizations solid‐state battery solid–solid interface synchrotron X‐ray |
| url | https://doi.org/10.1002/cey2.131 |
| work_keys_str_mv | AT marcoslucero insitucharacterizationsofsolidsolidinterfacesinsolidstatebatteriesusingsynchrotronxraytechniques AT shenqiu insitucharacterizationsofsolidsolidinterfacesinsolidstatebatteriesusingsynchrotronxraytechniques AT zhenxingfeng insitucharacterizationsofsolidsolidinterfacesinsolidstatebatteriesusingsynchrotronxraytechniques |