Efficient Degradation of Methylene Blue Using La-PTC-HIna/Ti<sub>3</sub>C<sub>2</sub>Tx MXene: Adsorption and Photocatalytic Degradation
Isonicotinic acid is a pyridine carboxylic compound that can be used as a linker to construct coordination complexes. Adding isonicotinic acid (HIna) to the metal-organic framework (MOF) enhanced the MOF surface area, pore volume, and pore size and increased its catalytic activity. Ti3C2Tx MXene nan...
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| Format: | Article |
| Language: | English |
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Department of Chemistry, Universitas Gadjah Mada
2022-09-01
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| Series: | Indonesian Journal of Chemistry |
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| Online Access: | https://jurnal.ugm.ac.id/ijc/article/view/71692 |
| _version_ | 1811238259411386368 |
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| author | Agustino Zulys Adawiah Adawiah Nasruddin Nasruddin |
| author_facet | Agustino Zulys Adawiah Adawiah Nasruddin Nasruddin |
| author_sort | Agustino Zulys |
| collection | DOAJ |
| description | Isonicotinic acid is a pyridine carboxylic compound that can be used as a linker to construct coordination complexes. Adding isonicotinic acid (HIna) to the metal-organic framework (MOF) enhanced the MOF surface area, pore volume, and pore size and increased its catalytic activity. Ti3C2Tx MXene nanosheet with excellent metal conductivity was also employed on MOF to optimize its functionality. This work aims to synthesize MOF modulated isonicotinic acid La-PTC-HIna and design the new materials: La-PTC/Ti3C2Tx MXene and La-PTC-HIna/Ti3C2Tx MXene hybrid, then apply them for methylene blue photodegradation. La-PTC-HIna, La-PTC/Ti3C2Tx MXene, and La-PTC-HIna/Ti3C2Tx MXene were synthesized by the sonochemical method. MOF La-PTC-HIna has the highest methylene blue photocatalytic degradation activity than MOF La-PTC, Ti3C2Tx MXene, La-PTC/Ti3C2Tx MXene, and La-PTC-HIna/Ti3C2Tx MXene with degradation efficiency of 99.48% in 20 ppm methylene blue under visible irradiation for 210 min. This study reveals the La-PTC-HIna and La-PTC-HIna/Ti3C2Tx MXene as a new material that has the potential to remove methylene blue from an aqueous solution. |
| first_indexed | 2024-04-12T12:38:38Z |
| format | Article |
| id | doaj.art-8479308ba998453aa18b7f47f29a6d8e |
| institution | Directory Open Access Journal |
| issn | 1411-9420 2460-1578 |
| language | English |
| last_indexed | 2024-04-12T12:38:38Z |
| publishDate | 2022-09-01 |
| publisher | Department of Chemistry, Universitas Gadjah Mada |
| record_format | Article |
| series | Indonesian Journal of Chemistry |
| spelling | doaj.art-8479308ba998453aa18b7f47f29a6d8e2022-12-22T03:32:50ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782022-09-012251195120410.22146/ijc.7169232428Efficient Degradation of Methylene Blue Using La-PTC-HIna/Ti<sub>3</sub>C<sub>2</sub>Tx MXene: Adsorption and Photocatalytic DegradationAgustino Zulys0Adawiah Adawiah1Nasruddin Nasruddin2Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Indonesia, Depok, 16424, IndonesiaIntegrated Laboratory Centre, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95, Ciputat 15412, IndonesiaDepartment of Mechanical Engineering, Faculty of Engineering, Universitas Indonesia, Depok, 16424, IndonesiaIsonicotinic acid is a pyridine carboxylic compound that can be used as a linker to construct coordination complexes. Adding isonicotinic acid (HIna) to the metal-organic framework (MOF) enhanced the MOF surface area, pore volume, and pore size and increased its catalytic activity. Ti3C2Tx MXene nanosheet with excellent metal conductivity was also employed on MOF to optimize its functionality. This work aims to synthesize MOF modulated isonicotinic acid La-PTC-HIna and design the new materials: La-PTC/Ti3C2Tx MXene and La-PTC-HIna/Ti3C2Tx MXene hybrid, then apply them for methylene blue photodegradation. La-PTC-HIna, La-PTC/Ti3C2Tx MXene, and La-PTC-HIna/Ti3C2Tx MXene were synthesized by the sonochemical method. MOF La-PTC-HIna has the highest methylene blue photocatalytic degradation activity than MOF La-PTC, Ti3C2Tx MXene, La-PTC/Ti3C2Tx MXene, and La-PTC-HIna/Ti3C2Tx MXene with degradation efficiency of 99.48% in 20 ppm methylene blue under visible irradiation for 210 min. This study reveals the La-PTC-HIna and La-PTC-HIna/Ti3C2Tx MXene as a new material that has the potential to remove methylene blue from an aqueous solution.https://jurnal.ugm.ac.id/ijc/article/view/71692metal-organic frameworkti3c2tx mxenela-ptcla-ptc-hinala-ptc/ti3c2tx mxenela-ptc-hina/ti3c2tx mxene |
| spellingShingle | Agustino Zulys Adawiah Adawiah Nasruddin Nasruddin Efficient Degradation of Methylene Blue Using La-PTC-HIna/Ti<sub>3</sub>C<sub>2</sub>Tx MXene: Adsorption and Photocatalytic Degradation Indonesian Journal of Chemistry metal-organic framework ti3c2tx mxene la-ptc la-ptc-hina la-ptc/ti3c2tx mxene la-ptc-hina/ti3c2tx mxene |
| title | Efficient Degradation of Methylene Blue Using La-PTC-HIna/Ti<sub>3</sub>C<sub>2</sub>Tx MXene: Adsorption and Photocatalytic Degradation |
| title_full | Efficient Degradation of Methylene Blue Using La-PTC-HIna/Ti<sub>3</sub>C<sub>2</sub>Tx MXene: Adsorption and Photocatalytic Degradation |
| title_fullStr | Efficient Degradation of Methylene Blue Using La-PTC-HIna/Ti<sub>3</sub>C<sub>2</sub>Tx MXene: Adsorption and Photocatalytic Degradation |
| title_full_unstemmed | Efficient Degradation of Methylene Blue Using La-PTC-HIna/Ti<sub>3</sub>C<sub>2</sub>Tx MXene: Adsorption and Photocatalytic Degradation |
| title_short | Efficient Degradation of Methylene Blue Using La-PTC-HIna/Ti<sub>3</sub>C<sub>2</sub>Tx MXene: Adsorption and Photocatalytic Degradation |
| title_sort | efficient degradation of methylene blue using la ptc hina ti sub 3 sub c sub 2 sub tx mxene adsorption and photocatalytic degradation |
| topic | metal-organic framework ti3c2tx mxene la-ptc la-ptc-hina la-ptc/ti3c2tx mxene la-ptc-hina/ti3c2tx mxene |
| url | https://jurnal.ugm.ac.id/ijc/article/view/71692 |
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