Polypropylene and silica short fibers composites

The mechanical properties of composites strongly depend on the type of filler-polymeric matrix interface. An interface characterized by a strong bond between the filler and the matrix generally results in better mechanical properties. In this work, polypropylene, PP, was used as polymeric matrix and...

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Main Authors: Mariana Gava Segatelli, Cristiane Aparecida da Silva, Inez Valéria Pagotto Yoshida, Maria do Carmo Gonçalves
Format: Article
Language:English
Published: Universidade Estadual de Londrina 2012-04-01
Series:Semina: Ciências Exatas e Tecnológicas
Subjects:
Online Access:http://www.uel.br/revistas/uel/index.php/semexatas/article/view/8965/10383
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author Mariana Gava Segatelli
Cristiane Aparecida da Silva
Inez Valéria Pagotto Yoshida
Maria do Carmo Gonçalves
author_facet Mariana Gava Segatelli
Cristiane Aparecida da Silva
Inez Valéria Pagotto Yoshida
Maria do Carmo Gonçalves
author_sort Mariana Gava Segatelli
collection DOAJ
description The mechanical properties of composites strongly depend on the type of filler-polymeric matrix interface. An interface characterized by a strong bond between the filler and the matrix generally results in better mechanical properties. In this work, polypropylene, PP, was used as polymeric matrix and silica short fibers, SF, which are amorphous biogenic silica, were employed as filler. In order to promote a better filler-matrix interfacial adhesion, these fibers were previously modified with vinyltrimethoxysilane. The composites were prepared by extrusion and injection molding processes and their mechanical properties were evaluated according to tensile testing, ASTM D 268, by means a fractional factorial design (25-1). The studied factors included fiber content in the matrix, fiber surface modification, injection flow and testing rate. The composite cryogenic fractured surfaces were investigated by field emission scanning electron microscopy, FESEM. The fiber modification promoted a better fiber-matrix interfacial adhesion, resulting in optimized mechanical properties in relation to the others. In this way, the fiber modification was the most important factor on the mechanical performance of the composites.
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spelling doaj.art-8479caeb82aa4c14a7cfe792bf3d09e82022-12-22T01:07:19ZengUniversidade Estadual de LondrinaSemina: Ciências Exatas e Tecnológicas1676-54511679-03752012-04-0133195102Polypropylene and silica short fibers compositesMariana Gava SegatelliCristiane Aparecida da SilvaInez Valéria Pagotto YoshidaMaria do Carmo GonçalvesThe mechanical properties of composites strongly depend on the type of filler-polymeric matrix interface. An interface characterized by a strong bond between the filler and the matrix generally results in better mechanical properties. In this work, polypropylene, PP, was used as polymeric matrix and silica short fibers, SF, which are amorphous biogenic silica, were employed as filler. In order to promote a better filler-matrix interfacial adhesion, these fibers were previously modified with vinyltrimethoxysilane. The composites were prepared by extrusion and injection molding processes and their mechanical properties were evaluated according to tensile testing, ASTM D 268, by means a fractional factorial design (25-1). The studied factors included fiber content in the matrix, fiber surface modification, injection flow and testing rate. The composite cryogenic fractured surfaces were investigated by field emission scanning electron microscopy, FESEM. The fiber modification promoted a better fiber-matrix interfacial adhesion, resulting in optimized mechanical properties in relation to the others. In this way, the fiber modification was the most important factor on the mechanical performance of the composites.http://www.uel.br/revistas/uel/index.php/semexatas/article/view/8965/10383Silica short fibersPolypropyleneFractional factorial design
spellingShingle Mariana Gava Segatelli
Cristiane Aparecida da Silva
Inez Valéria Pagotto Yoshida
Maria do Carmo Gonçalves
Polypropylene and silica short fibers composites
Semina: Ciências Exatas e Tecnológicas
Silica short fibers
Polypropylene
Fractional factorial design
title Polypropylene and silica short fibers composites
title_full Polypropylene and silica short fibers composites
title_fullStr Polypropylene and silica short fibers composites
title_full_unstemmed Polypropylene and silica short fibers composites
title_short Polypropylene and silica short fibers composites
title_sort polypropylene and silica short fibers composites
topic Silica short fibers
Polypropylene
Fractional factorial design
url http://www.uel.br/revistas/uel/index.php/semexatas/article/view/8965/10383
work_keys_str_mv AT marianagavasegatelli polypropyleneandsilicashortfiberscomposites
AT cristianeaparecidadasilva polypropyleneandsilicashortfiberscomposites
AT inezvaleriapagottoyoshida polypropyleneandsilicashortfiberscomposites
AT mariadocarmogoncalves polypropyleneandsilicashortfiberscomposites