Thermochemical and Mechanical Properties of Pine Wood Treated by In Situ Polymerization of Methyl Methacrylate (MMA)

The impregnation of low-molecular-weight monomers prior to polymerize them inside the wood may be an efficient way to improve some important wood properties. This work aimed to determine some technological properties of wood-based composites (WPC) produced by in situ polymerization, using a pine woo...

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Main Authors: Andrey Pereira Acosta, Jalel Labidi, Henrique Römer Schulz, Ezequiel Gallio, Kelvin Techera Barbosa, Rafael Beltrame, Rafael de Avila Delucis, Darci Alberto Gatto
Format: Article
Language:English
Published: MDPI AG 2020-07-01
Series:Forests
Subjects:
Online Access:https://www.mdpi.com/1999-4907/11/7/768
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author Andrey Pereira Acosta
Jalel Labidi
Henrique Römer Schulz
Ezequiel Gallio
Kelvin Techera Barbosa
Rafael Beltrame
Rafael de Avila Delucis
Darci Alberto Gatto
author_facet Andrey Pereira Acosta
Jalel Labidi
Henrique Römer Schulz
Ezequiel Gallio
Kelvin Techera Barbosa
Rafael Beltrame
Rafael de Avila Delucis
Darci Alberto Gatto
author_sort Andrey Pereira Acosta
collection DOAJ
description The impregnation of low-molecular-weight monomers prior to polymerize them inside the wood may be an efficient way to improve some important wood properties. This work aimed to determine some technological properties of wood-based composites (WPC) produced by in situ polymerization, using a pine wood (<i>Pinus elliottii</i> Engelm.) impregnated with methyl methacrylate (MMA). For that, samples taken from both juvenile (JV) and mature (MT) pine woods were treated with MMA. Physical, mechanical, chemical, thermal and morphological features were evaluated. MMA-treated woods from both juvenile and mature woods presented superior physical, mechanical (expect brittleness) and thermal properties when compared to pristine ones. The infrared spectra and morphological analysis by scanning electron microscopy (SEM) confirmed the presence of the monomer inside the pine wood. The juvenile wood presented higher treatability than the mature wood, due to its higher content of intra- and inter-cellular spaces.
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spelling doaj.art-84a3b8d3291249bdb5d49700552d562b2023-11-20T07:08:30ZengMDPI AGForests1999-49072020-07-0111776810.3390/f11070768Thermochemical and Mechanical Properties of Pine Wood Treated by In Situ Polymerization of Methyl Methacrylate (MMA)Andrey Pereira Acosta0Jalel Labidi1Henrique Römer Schulz2Ezequiel Gallio3Kelvin Techera Barbosa4Rafael Beltrame5Rafael de Avila Delucis6Darci Alberto Gatto7Postgraduate Program in Materials Science and Engineering, Federal University of Pelotas, Technological Development Center (CDTec), Pelotas 96010-290, BrazilChemical and Environmental Engineering Departement, University of the Basque Country (UPV/EHU), 20018 San Sebastian, SpainPostgraduate Program in Materials Science and Engineering, Federal University of Pelotas, Technological Development Center (CDTec), Pelotas 96010-290, BrazilPostgraduate Program in Materials Science and Engineering, Federal University of Pelotas, Technological Development Center (CDTec), Pelotas 96010-290, BrazilPostgraduate Program in Materials Science and Engineering, Federal University of Pelotas, Technological Development Center (CDTec), Pelotas 96010-290, BrazilPostgraduate Program in Materials Science and Engineering, Federal University of Pelotas, Technological Development Center (CDTec), Pelotas 96010-290, BrazilPostgraduate Program in Materials Science and Engineering, Federal University of Pelotas, Technological Development Center (CDTec), Pelotas 96010-290, BrazilPostgraduate Program in Materials Science and Engineering, Federal University of Pelotas, Technological Development Center (CDTec), Pelotas 96010-290, BrazilThe impregnation of low-molecular-weight monomers prior to polymerize them inside the wood may be an efficient way to improve some important wood properties. This work aimed to determine some technological properties of wood-based composites (WPC) produced by in situ polymerization, using a pine wood (<i>Pinus elliottii</i> Engelm.) impregnated with methyl methacrylate (MMA). For that, samples taken from both juvenile (JV) and mature (MT) pine woods were treated with MMA. Physical, mechanical, chemical, thermal and morphological features were evaluated. MMA-treated woods from both juvenile and mature woods presented superior physical, mechanical (expect brittleness) and thermal properties when compared to pristine ones. The infrared spectra and morphological analysis by scanning electron microscopy (SEM) confirmed the presence of the monomer inside the pine wood. The juvenile wood presented higher treatability than the mature wood, due to its higher content of intra- and inter-cellular spaces.https://www.mdpi.com/1999-4907/11/7/768thermal stabilityjuvenile woodinfrared spectroscopyin situ polymerizationwood quality
spellingShingle Andrey Pereira Acosta
Jalel Labidi
Henrique Römer Schulz
Ezequiel Gallio
Kelvin Techera Barbosa
Rafael Beltrame
Rafael de Avila Delucis
Darci Alberto Gatto
Thermochemical and Mechanical Properties of Pine Wood Treated by In Situ Polymerization of Methyl Methacrylate (MMA)
Forests
thermal stability
juvenile wood
infrared spectroscopy
in situ polymerization
wood quality
title Thermochemical and Mechanical Properties of Pine Wood Treated by In Situ Polymerization of Methyl Methacrylate (MMA)
title_full Thermochemical and Mechanical Properties of Pine Wood Treated by In Situ Polymerization of Methyl Methacrylate (MMA)
title_fullStr Thermochemical and Mechanical Properties of Pine Wood Treated by In Situ Polymerization of Methyl Methacrylate (MMA)
title_full_unstemmed Thermochemical and Mechanical Properties of Pine Wood Treated by In Situ Polymerization of Methyl Methacrylate (MMA)
title_short Thermochemical and Mechanical Properties of Pine Wood Treated by In Situ Polymerization of Methyl Methacrylate (MMA)
title_sort thermochemical and mechanical properties of pine wood treated by in situ polymerization of methyl methacrylate mma
topic thermal stability
juvenile wood
infrared spectroscopy
in situ polymerization
wood quality
url https://www.mdpi.com/1999-4907/11/7/768
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