Thermochemical and Mechanical Properties of Pine Wood Treated by In Situ Polymerization of Methyl Methacrylate (MMA)
The impregnation of low-molecular-weight monomers prior to polymerize them inside the wood may be an efficient way to improve some important wood properties. This work aimed to determine some technological properties of wood-based composites (WPC) produced by in situ polymerization, using a pine woo...
Main Authors: | , , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2020-07-01
|
Series: | Forests |
Subjects: | |
Online Access: | https://www.mdpi.com/1999-4907/11/7/768 |
_version_ | 1797562100953907200 |
---|---|
author | Andrey Pereira Acosta Jalel Labidi Henrique Römer Schulz Ezequiel Gallio Kelvin Techera Barbosa Rafael Beltrame Rafael de Avila Delucis Darci Alberto Gatto |
author_facet | Andrey Pereira Acosta Jalel Labidi Henrique Römer Schulz Ezequiel Gallio Kelvin Techera Barbosa Rafael Beltrame Rafael de Avila Delucis Darci Alberto Gatto |
author_sort | Andrey Pereira Acosta |
collection | DOAJ |
description | The impregnation of low-molecular-weight monomers prior to polymerize them inside the wood may be an efficient way to improve some important wood properties. This work aimed to determine some technological properties of wood-based composites (WPC) produced by in situ polymerization, using a pine wood (<i>Pinus elliottii</i> Engelm.) impregnated with methyl methacrylate (MMA). For that, samples taken from both juvenile (JV) and mature (MT) pine woods were treated with MMA. Physical, mechanical, chemical, thermal and morphological features were evaluated. MMA-treated woods from both juvenile and mature woods presented superior physical, mechanical (expect brittleness) and thermal properties when compared to pristine ones. The infrared spectra and morphological analysis by scanning electron microscopy (SEM) confirmed the presence of the monomer inside the pine wood. The juvenile wood presented higher treatability than the mature wood, due to its higher content of intra- and inter-cellular spaces. |
first_indexed | 2024-03-10T18:23:49Z |
format | Article |
id | doaj.art-84a3b8d3291249bdb5d49700552d562b |
institution | Directory Open Access Journal |
issn | 1999-4907 |
language | English |
last_indexed | 2024-03-10T18:23:49Z |
publishDate | 2020-07-01 |
publisher | MDPI AG |
record_format | Article |
series | Forests |
spelling | doaj.art-84a3b8d3291249bdb5d49700552d562b2023-11-20T07:08:30ZengMDPI AGForests1999-49072020-07-0111776810.3390/f11070768Thermochemical and Mechanical Properties of Pine Wood Treated by In Situ Polymerization of Methyl Methacrylate (MMA)Andrey Pereira Acosta0Jalel Labidi1Henrique Römer Schulz2Ezequiel Gallio3Kelvin Techera Barbosa4Rafael Beltrame5Rafael de Avila Delucis6Darci Alberto Gatto7Postgraduate Program in Materials Science and Engineering, Federal University of Pelotas, Technological Development Center (CDTec), Pelotas 96010-290, BrazilChemical and Environmental Engineering Departement, University of the Basque Country (UPV/EHU), 20018 San Sebastian, SpainPostgraduate Program in Materials Science and Engineering, Federal University of Pelotas, Technological Development Center (CDTec), Pelotas 96010-290, BrazilPostgraduate Program in Materials Science and Engineering, Federal University of Pelotas, Technological Development Center (CDTec), Pelotas 96010-290, BrazilPostgraduate Program in Materials Science and Engineering, Federal University of Pelotas, Technological Development Center (CDTec), Pelotas 96010-290, BrazilPostgraduate Program in Materials Science and Engineering, Federal University of Pelotas, Technological Development Center (CDTec), Pelotas 96010-290, BrazilPostgraduate Program in Materials Science and Engineering, Federal University of Pelotas, Technological Development Center (CDTec), Pelotas 96010-290, BrazilPostgraduate Program in Materials Science and Engineering, Federal University of Pelotas, Technological Development Center (CDTec), Pelotas 96010-290, BrazilThe impregnation of low-molecular-weight monomers prior to polymerize them inside the wood may be an efficient way to improve some important wood properties. This work aimed to determine some technological properties of wood-based composites (WPC) produced by in situ polymerization, using a pine wood (<i>Pinus elliottii</i> Engelm.) impregnated with methyl methacrylate (MMA). For that, samples taken from both juvenile (JV) and mature (MT) pine woods were treated with MMA. Physical, mechanical, chemical, thermal and morphological features were evaluated. MMA-treated woods from both juvenile and mature woods presented superior physical, mechanical (expect brittleness) and thermal properties when compared to pristine ones. The infrared spectra and morphological analysis by scanning electron microscopy (SEM) confirmed the presence of the monomer inside the pine wood. The juvenile wood presented higher treatability than the mature wood, due to its higher content of intra- and inter-cellular spaces.https://www.mdpi.com/1999-4907/11/7/768thermal stabilityjuvenile woodinfrared spectroscopyin situ polymerizationwood quality |
spellingShingle | Andrey Pereira Acosta Jalel Labidi Henrique Römer Schulz Ezequiel Gallio Kelvin Techera Barbosa Rafael Beltrame Rafael de Avila Delucis Darci Alberto Gatto Thermochemical and Mechanical Properties of Pine Wood Treated by In Situ Polymerization of Methyl Methacrylate (MMA) Forests thermal stability juvenile wood infrared spectroscopy in situ polymerization wood quality |
title | Thermochemical and Mechanical Properties of Pine Wood Treated by In Situ Polymerization of Methyl Methacrylate (MMA) |
title_full | Thermochemical and Mechanical Properties of Pine Wood Treated by In Situ Polymerization of Methyl Methacrylate (MMA) |
title_fullStr | Thermochemical and Mechanical Properties of Pine Wood Treated by In Situ Polymerization of Methyl Methacrylate (MMA) |
title_full_unstemmed | Thermochemical and Mechanical Properties of Pine Wood Treated by In Situ Polymerization of Methyl Methacrylate (MMA) |
title_short | Thermochemical and Mechanical Properties of Pine Wood Treated by In Situ Polymerization of Methyl Methacrylate (MMA) |
title_sort | thermochemical and mechanical properties of pine wood treated by in situ polymerization of methyl methacrylate mma |
topic | thermal stability juvenile wood infrared spectroscopy in situ polymerization wood quality |
url | https://www.mdpi.com/1999-4907/11/7/768 |
work_keys_str_mv | AT andreypereiraacosta thermochemicalandmechanicalpropertiesofpinewoodtreatedbyinsitupolymerizationofmethylmethacrylatemma AT jalellabidi thermochemicalandmechanicalpropertiesofpinewoodtreatedbyinsitupolymerizationofmethylmethacrylatemma AT henriqueromerschulz thermochemicalandmechanicalpropertiesofpinewoodtreatedbyinsitupolymerizationofmethylmethacrylatemma AT ezequielgallio thermochemicalandmechanicalpropertiesofpinewoodtreatedbyinsitupolymerizationofmethylmethacrylatemma AT kelvintecherabarbosa thermochemicalandmechanicalpropertiesofpinewoodtreatedbyinsitupolymerizationofmethylmethacrylatemma AT rafaelbeltrame thermochemicalandmechanicalpropertiesofpinewoodtreatedbyinsitupolymerizationofmethylmethacrylatemma AT rafaeldeaviladelucis thermochemicalandmechanicalpropertiesofpinewoodtreatedbyinsitupolymerizationofmethylmethacrylatemma AT darcialbertogatto thermochemicalandmechanicalpropertiesofpinewoodtreatedbyinsitupolymerizationofmethylmethacrylatemma |