High porosity micro- and macro-cellular copper foams with semi-open cell microstructure toward its physical and mechanical properties

Herein, a powder compacting method was developed to fabricate high porosity micro- and macro-cellular copper foams using CaCO _3 space holder. The cold compacted precursors were heated at different temperatures under the nitrogen atmosphere. The effects of precursor compaction pressure, space holder...

Full description

Bibliographic Details
Main Authors: Yasaman Saberi, Hamid Oveisi
Format: Article
Language:English
Published: IOP Publishing 2020-01-01
Series:Materials Research Express
Subjects:
Online Access:https://doi.org/10.1088/2053-1591/ab636e
_version_ 1797747083710562304
author Yasaman Saberi
Hamid Oveisi
author_facet Yasaman Saberi
Hamid Oveisi
author_sort Yasaman Saberi
collection DOAJ
description Herein, a powder compacting method was developed to fabricate high porosity micro- and macro-cellular copper foams using CaCO _3 space holder. The cold compacted precursors were heated at different temperatures under the nitrogen atmosphere. The effects of precursor compaction pressure, space holder content and sintering temperature on cell microstructure, relative density, compressive and physical properties were investigated. The scanning electron microscopy (SEM) images showed a uniform distribution of interconnected pores with sizes of pores and channels less than 50 microns formed the semi-open cell structure of the fabricated foams. The evaluation of the foaming agent content, 0 to 20 (wt%), in precursor materials showed relatively large changes in the porosity percentage (27%–50%), with the utilitarian strength (43 MPa) and densification strain (40%) of the copper foams. For specimens having 20 wt% CaCO _3 , tuning the sintering temperature (600 °C) and compacting pressure (500 MPa) of precursors tailored superior porosity percent (47%), remarkable compressive stress (501 MPa) and high thermal (43.8 W m ^−1 .k), and electrical conductivity (0.06 × 10 ^8 Ω ^−1 m ^−1 ) owing to a desirable foaming process. A massive gas release during the CaCO _3 decomposition and the strengthened cell walls of the copper foams during the sintering resulted in the high porosity and strength of the fabricated foams. The presented fabrication method and our results are the core elements for the development of new high porosity metal foams that can help the development of the future application of copper foams for a long-life anode for lithium-ion batteries, catalysis, and thermal and electrical performances as electronic cooling materials.
first_indexed 2024-03-12T15:47:06Z
format Article
id doaj.art-84bccd0d9a7c4f458c45f2fd33f714b3
institution Directory Open Access Journal
issn 2053-1591
language English
last_indexed 2024-03-12T15:47:06Z
publishDate 2020-01-01
publisher IOP Publishing
record_format Article
series Materials Research Express
spelling doaj.art-84bccd0d9a7c4f458c45f2fd33f714b32023-08-09T15:24:29ZengIOP PublishingMaterials Research Express2053-15912020-01-017101654910.1088/2053-1591/ab636eHigh porosity micro- and macro-cellular copper foams with semi-open cell microstructure toward its physical and mechanical propertiesYasaman Saberi0Hamid Oveisi1https://orcid.org/0000-0002-0996-7811Department of Materials & Polymer Engineering, Hakim Sabzevari University , Sabzevar 9617976487, IranDepartment of Materials & Polymer Engineering, Hakim Sabzevari University , Sabzevar 9617976487, IranHerein, a powder compacting method was developed to fabricate high porosity micro- and macro-cellular copper foams using CaCO _3 space holder. The cold compacted precursors were heated at different temperatures under the nitrogen atmosphere. The effects of precursor compaction pressure, space holder content and sintering temperature on cell microstructure, relative density, compressive and physical properties were investigated. The scanning electron microscopy (SEM) images showed a uniform distribution of interconnected pores with sizes of pores and channels less than 50 microns formed the semi-open cell structure of the fabricated foams. The evaluation of the foaming agent content, 0 to 20 (wt%), in precursor materials showed relatively large changes in the porosity percentage (27%–50%), with the utilitarian strength (43 MPa) and densification strain (40%) of the copper foams. For specimens having 20 wt% CaCO _3 , tuning the sintering temperature (600 °C) and compacting pressure (500 MPa) of precursors tailored superior porosity percent (47%), remarkable compressive stress (501 MPa) and high thermal (43.8 W m ^−1 .k), and electrical conductivity (0.06 × 10 ^8 Ω ^−1 m ^−1 ) owing to a desirable foaming process. A massive gas release during the CaCO _3 decomposition and the strengthened cell walls of the copper foams during the sintering resulted in the high porosity and strength of the fabricated foams. The presented fabrication method and our results are the core elements for the development of new high porosity metal foams that can help the development of the future application of copper foams for a long-life anode for lithium-ion batteries, catalysis, and thermal and electrical performances as electronic cooling materials.https://doi.org/10.1088/2053-1591/ab636ecellular materialscopper foampowder metallurgyphysical propertiesmechanical properties
spellingShingle Yasaman Saberi
Hamid Oveisi
High porosity micro- and macro-cellular copper foams with semi-open cell microstructure toward its physical and mechanical properties
Materials Research Express
cellular materials
copper foam
powder metallurgy
physical properties
mechanical properties
title High porosity micro- and macro-cellular copper foams with semi-open cell microstructure toward its physical and mechanical properties
title_full High porosity micro- and macro-cellular copper foams with semi-open cell microstructure toward its physical and mechanical properties
title_fullStr High porosity micro- and macro-cellular copper foams with semi-open cell microstructure toward its physical and mechanical properties
title_full_unstemmed High porosity micro- and macro-cellular copper foams with semi-open cell microstructure toward its physical and mechanical properties
title_short High porosity micro- and macro-cellular copper foams with semi-open cell microstructure toward its physical and mechanical properties
title_sort high porosity micro and macro cellular copper foams with semi open cell microstructure toward its physical and mechanical properties
topic cellular materials
copper foam
powder metallurgy
physical properties
mechanical properties
url https://doi.org/10.1088/2053-1591/ab636e
work_keys_str_mv AT yasamansaberi highporositymicroandmacrocellularcopperfoamswithsemiopencellmicrostructuretowarditsphysicalandmechanicalproperties
AT hamidoveisi highporositymicroandmacrocellularcopperfoamswithsemiopencellmicrostructuretowarditsphysicalandmechanicalproperties