Synthesis of Optically and Redox Active Polyenaminones from Diamines and α,α’-Bis[(dimethylamino)methylidene]cyclohexanediones

Synthesis of Optically and Redox Active Polyenaminones from Diamines and α,α’-Bis[(dimethylamino)methylidene]cyclohexanediones

New oligo- and polyenaminones with <i>M<sub>w</sub></i> ~ 7–50 KDa were prepared in high yields by transaminative amino-enaminone polymerization of regioisomeric bis[(dimethylamino)methylidene]cyclohexanediones with alkylene and phenylenediamines. The polymers obtained are pr...

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Bibliographic Details
Main Authors: Urša Štanfel, Tomaž Kotnik, Sebastijan Ričko, Uroš Grošelj, Bogdan Štefane, Klemen Pirnat, Ema Žagar, Boštjan Genorio, Jurij Svete
Format: Article
Language:English
Published: MDPI AG 2022-10-01
Series:Polymers
Subjects:
polyenaminones
transaminative polymerisation
bis-enaminones
diamines
UV shielding
redox activity
Online Access:https://www.mdpi.com/2073-4360/14/19/4120

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