Aqua(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)(nitrato-κO)(nitrato-κ2O,O′)zinc
In the title compound, [Zn(NO3)2(C12H12N2)(H2O)], the ZnII atom is six-coordinated in a distorted octahedral geometry by two N atoms from a chelating 4,4′-dimethyl-2,2′-bipyridine ligand, one water O atom, one O atom from a monodentate nitrate anion and two O atoms from a...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-12-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811050227 |
| _version_ | 1818914749043179520 |
|---|---|
| author | Sadif A. Shirvan Sara Haydari Dezfuli |
| author_facet | Sadif A. Shirvan Sara Haydari Dezfuli |
| author_sort | Sadif A. Shirvan |
| collection | DOAJ |
| description | In the title compound, [Zn(NO3)2(C12H12N2)(H2O)], the ZnII atom is six-coordinated in a distorted octahedral geometry by two N atoms from a chelating 4,4′-dimethyl-2,2′-bipyridine ligand, one water O atom, one O atom from a monodentate nitrate anion and two O atoms from a chelating nitrate anion. In the crystal, there are aromatic π–π contacts between the pyridine rings [centroid–centroid distances = 3.9577 (13) Å] and intermolecular O—H...O and C—H...O hydrogen bonds. |
| first_indexed | 2024-12-19T23:51:19Z |
| format | Article |
| id | doaj.art-84de2f7618484c579b2a22b3091e109e |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T23:51:19Z |
| publishDate | 2011-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-84de2f7618484c579b2a22b3091e109e2022-12-21T20:01:08ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712m1866m186710.1107/S1600536811050227Aqua(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)(nitrato-κO)(nitrato-κ2O,O′)zincSadif A. ShirvanSara Haydari DezfuliIn the title compound, [Zn(NO3)2(C12H12N2)(H2O)], the ZnII atom is six-coordinated in a distorted octahedral geometry by two N atoms from a chelating 4,4′-dimethyl-2,2′-bipyridine ligand, one water O atom, one O atom from a monodentate nitrate anion and two O atoms from a chelating nitrate anion. In the crystal, there are aromatic π–π contacts between the pyridine rings [centroid–centroid distances = 3.9577 (13) Å] and intermolecular O—H...O and C—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536811050227 |
| spellingShingle | Sadif A. Shirvan Sara Haydari Dezfuli Aqua(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)(nitrato-κO)(nitrato-κ2O,O′)zinc Acta Crystallographica Section E |
| title | Aqua(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)(nitrato-κO)(nitrato-κ2O,O′)zinc |
| title_full | Aqua(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)(nitrato-κO)(nitrato-κ2O,O′)zinc |
| title_fullStr | Aqua(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)(nitrato-κO)(nitrato-κ2O,O′)zinc |
| title_full_unstemmed | Aqua(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)(nitrato-κO)(nitrato-κ2O,O′)zinc |
| title_short | Aqua(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)(nitrato-κO)(nitrato-κ2O,O′)zinc |
| title_sort | aqua 4 4 amp 8242 dimethyl 2 2 amp 8242 bipyridine amp 954 2n n amp 8242 nitrato amp 954 o nitrato amp 954 2o o amp 8242 zinc |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811050227 |
| work_keys_str_mv | AT sadifashirvan aqua44amp8242dimethyl22amp8242bipyridineamp9542nnamp8242nitratoamp954onitratoamp9542ooamp8242zinc AT sarahaydaridezfuli aqua44amp8242dimethyl22amp8242bipyridineamp9542nnamp8242nitratoamp954onitratoamp9542ooamp8242zinc |