Preparation and Performance Evaluation of a Temperature and Salt Resistant Hydrophobic Associative Weak Polymer Gel System

We targeted high-temperature and highly saline old oil fields, whose environmental conditions could be attributed to the significantly high heterogeneity cause by long-term water flooding. The Huabei Oilfield was chosen as the research object. We developed a hydrophobic functional monomer–polymer wi...

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Main Authors: Jiqiang Zhi, Yikun Liu, Jinfeng Chen, Lifeng Bo, Guohui Qu, Nan Jiang, Weizhong He
Format: Article
Language:English
Published: MDPI AG 2023-03-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/28/7/3125
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author Jiqiang Zhi
Yikun Liu
Jinfeng Chen
Lifeng Bo
Guohui Qu
Nan Jiang
Weizhong He
author_facet Jiqiang Zhi
Yikun Liu
Jinfeng Chen
Lifeng Bo
Guohui Qu
Nan Jiang
Weizhong He
author_sort Jiqiang Zhi
collection DOAJ
description We targeted high-temperature and highly saline old oil fields, whose environmental conditions could be attributed to the significantly high heterogeneity cause by long-term water flooding. The Huabei Oilfield was chosen as the research object. We developed a hydrophobic functional monomer–polymer with temperature and salt resistance by introducing the temperature-resistant and salt-resistant monomer NVP and a hydrophobic functional monomer into the main chain for copolymerization. We used a crosslinking agent with phenolic resin to prepare a weak gel system that showed temperature and salt resistance and investigated its temperature and salt resistance, infective property, plugging performance, liquid flow ability, micropore throat migration, and plugging characteristics. The results obtained using the infrared spectroscopy technique revealed the successful preparation of the phenolic resin crosslinker. The weak gel exhibited good temperature and salt resistance when the polymer concentration was 2000 mg/L, the cohesion ratio was 1:1.5, the additive concentration was 2000 mg/L, the reservoir temperature was 120 °C, and the injected water salinity was 40,300.86 mg/L. The average viscosity retention rate of the 90-day weak gel reached more than 80% and its microstructure was examined. The coreflow experiment results revealed that the weak gel system was characterized by good infectivity. After plugging the weak gel, the effect on the direction of the liquid flow was evident and the flow rate of the low permeability layer increased to a maximum of 48.63% under conditions of varying permeability levels. A significant improvement in the water absorption profile was achieved. The plugging was carried out through a sand-filling pipe under varying permeability conditions and the pressure measuring points in the sand-filling pipe were sucessfully pressurized. The migration ability of the weak gel was good and the blocking rate was >85%.
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spelling doaj.art-84fb39da0a074121aaa93f531c9f30342023-11-17T17:13:54ZengMDPI AGMolecules1420-30492023-03-01287312510.3390/molecules28073125Preparation and Performance Evaluation of a Temperature and Salt Resistant Hydrophobic Associative Weak Polymer Gel SystemJiqiang Zhi0Yikun Liu1Jinfeng Chen2Lifeng Bo3Guohui Qu4Nan Jiang5Weizhong He6School of Petroleum Engineering, Northeast Petroleum University, Daqing 163318, ChinaSchool of Petroleum Engineering, Northeast Petroleum University, Daqing 163318, ChinaSchool of Petroleum Engineering, Northeast Petroleum University, Daqing 163318, ChinaSchool of Petroleum Engineering, Northeast Petroleum University, Daqing 163318, ChinaSchool of Petroleum Engineering, Northeast Petroleum University, Daqing 163318, ChinaSchool of Electrical Engineering & Information, Northeast Petroleum University, Daqing 163318, ChinaSchool of Petroleum Engineering, Northeast Petroleum University, Daqing 163318, ChinaWe targeted high-temperature and highly saline old oil fields, whose environmental conditions could be attributed to the significantly high heterogeneity cause by long-term water flooding. The Huabei Oilfield was chosen as the research object. We developed a hydrophobic functional monomer–polymer with temperature and salt resistance by introducing the temperature-resistant and salt-resistant monomer NVP and a hydrophobic functional monomer into the main chain for copolymerization. We used a crosslinking agent with phenolic resin to prepare a weak gel system that showed temperature and salt resistance and investigated its temperature and salt resistance, infective property, plugging performance, liquid flow ability, micropore throat migration, and plugging characteristics. The results obtained using the infrared spectroscopy technique revealed the successful preparation of the phenolic resin crosslinker. The weak gel exhibited good temperature and salt resistance when the polymer concentration was 2000 mg/L, the cohesion ratio was 1:1.5, the additive concentration was 2000 mg/L, the reservoir temperature was 120 °C, and the injected water salinity was 40,300.86 mg/L. The average viscosity retention rate of the 90-day weak gel reached more than 80% and its microstructure was examined. The coreflow experiment results revealed that the weak gel system was characterized by good infectivity. After plugging the weak gel, the effect on the direction of the liquid flow was evident and the flow rate of the low permeability layer increased to a maximum of 48.63% under conditions of varying permeability levels. A significant improvement in the water absorption profile was achieved. The plugging was carried out through a sand-filling pipe under varying permeability conditions and the pressure measuring points in the sand-filling pipe were sucessfully pressurized. The migration ability of the weak gel was good and the blocking rate was >85%.https://www.mdpi.com/1420-3049/28/7/3125temperature and salt toleranceweak gel preparationprofile controlfluid flow directionplugging performance
spellingShingle Jiqiang Zhi
Yikun Liu
Jinfeng Chen
Lifeng Bo
Guohui Qu
Nan Jiang
Weizhong He
Preparation and Performance Evaluation of a Temperature and Salt Resistant Hydrophobic Associative Weak Polymer Gel System
Molecules
temperature and salt tolerance
weak gel preparation
profile control
fluid flow direction
plugging performance
title Preparation and Performance Evaluation of a Temperature and Salt Resistant Hydrophobic Associative Weak Polymer Gel System
title_full Preparation and Performance Evaluation of a Temperature and Salt Resistant Hydrophobic Associative Weak Polymer Gel System
title_fullStr Preparation and Performance Evaluation of a Temperature and Salt Resistant Hydrophobic Associative Weak Polymer Gel System
title_full_unstemmed Preparation and Performance Evaluation of a Temperature and Salt Resistant Hydrophobic Associative Weak Polymer Gel System
title_short Preparation and Performance Evaluation of a Temperature and Salt Resistant Hydrophobic Associative Weak Polymer Gel System
title_sort preparation and performance evaluation of a temperature and salt resistant hydrophobic associative weak polymer gel system
topic temperature and salt tolerance
weak gel preparation
profile control
fluid flow direction
plugging performance
url https://www.mdpi.com/1420-3049/28/7/3125
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AT jinfengchen preparationandperformanceevaluationofatemperatureandsaltresistanthydrophobicassociativeweakpolymergelsystem
AT lifengbo preparationandperformanceevaluationofatemperatureandsaltresistanthydrophobicassociativeweakpolymergelsystem
AT guohuiqu preparationandperformanceevaluationofatemperatureandsaltresistanthydrophobicassociativeweakpolymergelsystem
AT nanjiang preparationandperformanceevaluationofatemperatureandsaltresistanthydrophobicassociativeweakpolymergelsystem
AT weizhonghe preparationandperformanceevaluationofatemperatureandsaltresistanthydrophobicassociativeweakpolymergelsystem