Imidazolium-based Ionic Liquids Impregnated in Silica and Alumina Supports for CO2 Capture
Ionic liquids (ILs) physical immobilization in solid materials is a key strategy for developing efficient and low cost CO2 capture processes. In this work, two porous commercial substrates with different characteristics (silica and alumina) were impregnated with ILs by physical wet method. Imidazoli...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
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Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)
2019-11-01
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| Series: | Materials Research |
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| Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392019000700253&tlng=en |
| _version_ | 1819243443843497984 |
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| author | Bárbara Burlini Polesso Rafael Duczinski Franciele Longaray Bernard Henrique Zucchetti Ferrari Murilo da Luz Felipe Dalla Vecchia Sonia Maria Cabral de Menezes Sandra Einloft |
| author_facet | Bárbara Burlini Polesso Rafael Duczinski Franciele Longaray Bernard Henrique Zucchetti Ferrari Murilo da Luz Felipe Dalla Vecchia Sonia Maria Cabral de Menezes Sandra Einloft |
| author_sort | Bárbara Burlini Polesso |
| collection | DOAJ |
| description | Ionic liquids (ILs) physical immobilization in solid materials is a key strategy for developing efficient and low cost CO2 capture processes. In this work, two porous commercial substrates with different characteristics (silica and alumina) were impregnated with ILs by physical wet method. Imidazolium based IL combined with [Br]- and [Tf2N]- anions were used in impregnation process. CO2 sorption capacity and selectivity (CO2/N2) of these materials were investigated. The best results regarding CO2/N2 selectivity and CO2 sorption were obtained with [Tf2N]- anion. In relation to solid support, commercial alumina exhibited enhanced CO2 uptake and higher selective capacity (CO2/N2) (6.1 (± 0.1)). Combination of commercial alumina as support and 20 wt% of mbmim [Tf2N] resulted in higher CO2/N2 selectivity of 9.5 ± 1.0. In addition, this material also showed fast sorption kinetics when compared to pure IL besides reuse capacity. |
| first_indexed | 2024-12-23T14:55:47Z |
| format | Article |
| id | doaj.art-84ffd677ab1140088136fcfb3b0822a7 |
| institution | Directory Open Access Journal |
| issn | 1516-1439 |
| language | English |
| last_indexed | 2024-12-23T14:55:47Z |
| publishDate | 2019-11-01 |
| publisher | Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) |
| record_format | Article |
| series | Materials Research |
| spelling | doaj.art-84ffd677ab1140088136fcfb3b0822a72022-12-21T17:42:46ZengAssociação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)Materials Research1516-14392019-11-0122suppl 110.1590/1980-5373-mr-2018-0810Imidazolium-based Ionic Liquids Impregnated in Silica and Alumina Supports for CO2 CaptureBárbara Burlini PolessoRafael DuczinskiFranciele Longaray BernardHenrique Zucchetti FerrariMurilo da LuzFelipe Dalla VecchiaSonia Maria Cabral de MenezesSandra Einlofthttps://orcid.org/0000-0003-1364-0325Ionic liquids (ILs) physical immobilization in solid materials is a key strategy for developing efficient and low cost CO2 capture processes. In this work, two porous commercial substrates with different characteristics (silica and alumina) were impregnated with ILs by physical wet method. Imidazolium based IL combined with [Br]- and [Tf2N]- anions were used in impregnation process. CO2 sorption capacity and selectivity (CO2/N2) of these materials were investigated. The best results regarding CO2/N2 selectivity and CO2 sorption were obtained with [Tf2N]- anion. In relation to solid support, commercial alumina exhibited enhanced CO2 uptake and higher selective capacity (CO2/N2) (6.1 (± 0.1)). Combination of commercial alumina as support and 20 wt% of mbmim [Tf2N] resulted in higher CO2/N2 selectivity of 9.5 ± 1.0. In addition, this material also showed fast sorption kinetics when compared to pure IL besides reuse capacity.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392019000700253&tlng=enporous materialsionic liquidsCO2 capture |
| spellingShingle | Bárbara Burlini Polesso Rafael Duczinski Franciele Longaray Bernard Henrique Zucchetti Ferrari Murilo da Luz Felipe Dalla Vecchia Sonia Maria Cabral de Menezes Sandra Einloft Imidazolium-based Ionic Liquids Impregnated in Silica and Alumina Supports for CO2 Capture Materials Research porous materials ionic liquids CO2 capture |
| title | Imidazolium-based Ionic Liquids Impregnated in Silica and Alumina Supports for CO2 Capture |
| title_full | Imidazolium-based Ionic Liquids Impregnated in Silica and Alumina Supports for CO2 Capture |
| title_fullStr | Imidazolium-based Ionic Liquids Impregnated in Silica and Alumina Supports for CO2 Capture |
| title_full_unstemmed | Imidazolium-based Ionic Liquids Impregnated in Silica and Alumina Supports for CO2 Capture |
| title_short | Imidazolium-based Ionic Liquids Impregnated in Silica and Alumina Supports for CO2 Capture |
| title_sort | imidazolium based ionic liquids impregnated in silica and alumina supports for co2 capture |
| topic | porous materials ionic liquids CO2 capture |
| url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392019000700253&tlng=en |
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