Local electrochemical deposition of copper from sulfate solution

Local electrochemical deposition is a type of electroplating used to plate metal locally or form metal objects using electrochemical principles at a short distance from the working electrode. In this work, deposition of the copper spot was modelled using COMSOL software and experimentally tested in...

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Main Authors: Georgii Vasyliev, Viktoria Vorobyova, Dmytro Uschapovskiy, Olga Linyucheva
Format: Article
Language:English
Published: International Association of Physical Chemists (IAPC) 2022-06-01
Series:Journal of Electrochemical Science and Engineering
Subjects:
Online Access:https://pub.iapchem.org/ojs/index.php/JESE/article/view/1352
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author Georgii Vasyliev
Viktoria Vorobyova
Dmytro Uschapovskiy
Olga Linyucheva
author_facet Georgii Vasyliev
Viktoria Vorobyova
Dmytro Uschapovskiy
Olga Linyucheva
author_sort Georgii Vasyliev
collection DOAJ
description Local electrochemical deposition is a type of electroplating used to plate metal locally or form metal objects using electrochemical principles at a short distance from the working electrode. In this work, deposition of the copper spot was modelled using COMSOL software and experimentally tested in copper sulfate electrolyte using soluble copper anode. The working capillary diameter was 4 mm and the interelectrode distance was 5 mm. The deposited copper of 100 µm height was investigated using the 3D-profilometry technique. The geometry of deposited metal was found to be in good accordance with the COMSOL model. The inclusions of anodic sludge were responsible for the surface inhomogeneity of the deposited copper.  
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spelling doaj.art-850b212520b1407c8da88a470d41b9172022-12-22T03:31:35ZengInternational Association of Physical Chemists (IAPC)Journal of Electrochemical Science and Engineering1847-92862022-06-0110.5599/jese.1352Local electrochemical deposition of copper from sulfate solutionGeorgii Vasyliev0Viktoria Vorobyova1Dmytro Uschapovskiy2Olga Linyucheva3National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, 37, Prospect Peremohy, Kyiv-56, 03056, UkraineNational Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, 37, Prospect Peremohy, Kyiv-56, 03056, UkraineNational Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, 37, Prospect Peremohy, Kyiv-56, 03056, UkraineNational Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, 37, Prospect Peremohy, Kyiv-56, 03056, Ukraine Local electrochemical deposition is a type of electroplating used to plate metal locally or form metal objects using electrochemical principles at a short distance from the working electrode. In this work, deposition of the copper spot was modelled using COMSOL software and experimentally tested in copper sulfate electrolyte using soluble copper anode. The working capillary diameter was 4 mm and the interelectrode distance was 5 mm. The deposited copper of 100 µm height was investigated using the 3D-profilometry technique. The geometry of deposited metal was found to be in good accordance with the COMSOL model. The inclusions of anodic sludge were responsible for the surface inhomogeneity of the deposited copper.   https://pub.iapchem.org/ojs/index.php/JESE/article/view/1352LECDadditive manufacturingCOMSOLcopper platingthrowing poweranodic sludge
spellingShingle Georgii Vasyliev
Viktoria Vorobyova
Dmytro Uschapovskiy
Olga Linyucheva
Local electrochemical deposition of copper from sulfate solution
Journal of Electrochemical Science and Engineering
LECD
additive manufacturing
COMSOL
copper plating
throwing power
anodic sludge
title Local electrochemical deposition of copper from sulfate solution
title_full Local electrochemical deposition of copper from sulfate solution
title_fullStr Local electrochemical deposition of copper from sulfate solution
title_full_unstemmed Local electrochemical deposition of copper from sulfate solution
title_short Local electrochemical deposition of copper from sulfate solution
title_sort local electrochemical deposition of copper from sulfate solution
topic LECD
additive manufacturing
COMSOL
copper plating
throwing power
anodic sludge
url https://pub.iapchem.org/ojs/index.php/JESE/article/view/1352
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AT viktoriavorobyova localelectrochemicaldepositionofcopperfromsulfatesolution
AT dmytrouschapovskiy localelectrochemicaldepositionofcopperfromsulfatesolution
AT olgalinyucheva localelectrochemicaldepositionofcopperfromsulfatesolution