Tetraquinolinium ditelluro(VI)octavanadate(V) octahydrate
In the title compound, (C9H8N)4[Te2V8O28]·8H2O, the complete heteropolyanion is generated by a crystallographic inversion centre. One of the two quniolinium ions forms an N—H...Op (p = polyoxidometallate) hydrogen bond and the other an N—H...Ow (w = water) hydrogen bond....
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813027347 |
| Summary: | In the title compound, (C9H8N)4[Te2V8O28]·8H2O, the complete heteropolyanion is generated by a crystallographic inversion centre. One of the two quniolinium ions forms an N—H...Op (p = polyoxidometallate) hydrogen bond and the other an N—H...Ow (w = water) hydrogen bond. The water molecules further link the components by O—H...Op and O—H...Ow hydrogen bonds. A number of C—H...O interactions and aromatic π–π stacking interactions [shortest centroid–centroid separation = 3.541 (7) Å] are also observed. Together, these generate a three-dimensional network. |
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| ISSN: | 1600-5368 |