Tetraquinolinium ditelluro(VI)octavanadate(V) octahydrate
In the title compound, (C9H8N)4[Te2V8O28]·8H2O, the complete heteropolyanion is generated by a crystallographic inversion centre. One of the two quniolinium ions forms an N—H...Op (p = polyoxidometallate) hydrogen bond and the other an N—H...Ow (w = water) hydrogen bond....
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813027347 |
| _version_ | 1798019086187233280 |
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| author | Sirine Toumi Samah Akriche Toumi Mohamed Rzaigui |
| author_facet | Sirine Toumi Samah Akriche Toumi Mohamed Rzaigui |
| author_sort | Sirine Toumi |
| collection | DOAJ |
| description | In the title compound, (C9H8N)4[Te2V8O28]·8H2O, the complete heteropolyanion is generated by a crystallographic inversion centre. One of the two quniolinium ions forms an N—H...Op (p = polyoxidometallate) hydrogen bond and the other an N—H...Ow (w = water) hydrogen bond. The water molecules further link the components by O—H...Op and O—H...Ow hydrogen bonds. A number of C—H...O interactions and aromatic π–π stacking interactions [shortest centroid–centroid separation = 3.541 (7) Å] are also observed. Together, these generate a three-dimensional network. |
| first_indexed | 2024-04-11T16:34:50Z |
| format | Article |
| id | doaj.art-851311abeea9457a9a9d39bdb0938ddb |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:34:50Z |
| publishDate | 2013-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-851311abeea9457a9a9d39bdb0938ddb2022-12-22T04:13:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-11-016911m595m59610.1107/S1600536813027347Tetraquinolinium ditelluro(VI)octavanadate(V) octahydrateSirine ToumiSamah Akriche ToumiMohamed RzaiguiIn the title compound, (C9H8N)4[Te2V8O28]·8H2O, the complete heteropolyanion is generated by a crystallographic inversion centre. One of the two quniolinium ions forms an N—H...Op (p = polyoxidometallate) hydrogen bond and the other an N—H...Ow (w = water) hydrogen bond. The water molecules further link the components by O—H...Op and O—H...Ow hydrogen bonds. A number of C—H...O interactions and aromatic π–π stacking interactions [shortest centroid–centroid separation = 3.541 (7) Å] are also observed. Together, these generate a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536813027347 |
| spellingShingle | Sirine Toumi Samah Akriche Toumi Mohamed Rzaigui Tetraquinolinium ditelluro(VI)octavanadate(V) octahydrate Acta Crystallographica Section E |
| title | Tetraquinolinium ditelluro(VI)octavanadate(V) octahydrate |
| title_full | Tetraquinolinium ditelluro(VI)octavanadate(V) octahydrate |
| title_fullStr | Tetraquinolinium ditelluro(VI)octavanadate(V) octahydrate |
| title_full_unstemmed | Tetraquinolinium ditelluro(VI)octavanadate(V) octahydrate |
| title_short | Tetraquinolinium ditelluro(VI)octavanadate(V) octahydrate |
| title_sort | tetraquinolinium ditelluro vi octavanadate v octahydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813027347 |
| work_keys_str_mv | AT sirinetoumi tetraquinoliniumditellurovioctavanadatevoctahydrate AT samahakrichetoumi tetraquinoliniumditellurovioctavanadatevoctahydrate AT mohamedrzaigui tetraquinoliniumditellurovioctavanadatevoctahydrate |