Diastereoselective Synthesis of 2-Phenylselenenyl-1,3-anti-Diols and 2-Phenylselenenyl-1,3-anti-Azido-Alcohols via Hydroxyand Azido-Selenenylation Reactions
A method to synthesize 2-phenylselenenyl-1,3-anti-diols and 2-phenyl- selenenyl-1,3-anti-azidoalcohols via hydroxy- or azido-selenenylation of trans-allylic alcohols is reported. Moreover, the first example of hydroxyl-selenenylation of an allylic azide is presented. Yields ranging from moderate to...
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| Format: | Article |
| Language: | English |
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MDPI AG
2005-02-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/10/2/383/ |
| _version_ | 1818291374213038080 |
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| author | Renato Noto Paolo Lo Meo Michelangelo Gruttadauria Carmela Aprile Serena Riela |
| author_facet | Renato Noto Paolo Lo Meo Michelangelo Gruttadauria Carmela Aprile Serena Riela |
| author_sort | Renato Noto |
| collection | DOAJ |
| description | A method to synthesize 2-phenylselenenyl-1,3-anti-diols and 2-phenyl- selenenyl-1,3-anti-azidoalcohols via hydroxy- or azido-selenenylation of trans-allylic alcohols is reported. Moreover, the first example of hydroxyl-selenenylation of an allylic azide is presented. Yields ranging from moderate to good and diastereomeric ratios up to 95:5 are achieved. |
| first_indexed | 2024-12-13T02:43:03Z |
| format | Article |
| id | doaj.art-851be70d3489429c82f61a99cfa3301c |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-13T02:43:03Z |
| publishDate | 2005-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-851be70d3489429c82f61a99cfa3301c2022-12-22T00:02:15ZengMDPI AGMolecules1420-30492005-02-0110238339310.3390/10020383Diastereoselective Synthesis of 2-Phenylselenenyl-1,3-anti-Diols and 2-Phenylselenenyl-1,3-anti-Azido-Alcohols via Hydroxyand Azido-Selenenylation ReactionsRenato NotoPaolo Lo MeoMichelangelo GruttadauriaCarmela AprileSerena RielaA method to synthesize 2-phenylselenenyl-1,3-anti-diols and 2-phenyl- selenenyl-1,3-anti-azidoalcohols via hydroxy- or azido-selenenylation of trans-allylic alcohols is reported. Moreover, the first example of hydroxyl-selenenylation of an allylic azide is presented. Yields ranging from moderate to good and diastereomeric ratios up to 95:5 are achieved.http://www.mdpi.com/1420-3049/10/2/383/Azidesdiolsseleniraniun ion. |
| spellingShingle | Renato Noto Paolo Lo Meo Michelangelo Gruttadauria Carmela Aprile Serena Riela Diastereoselective Synthesis of 2-Phenylselenenyl-1,3-anti-Diols and 2-Phenylselenenyl-1,3-anti-Azido-Alcohols via Hydroxyand Azido-Selenenylation Reactions Molecules Azides diols seleniraniun ion. |
| title | Diastereoselective Synthesis of 2-Phenylselenenyl-1,3-anti-Diols and 2-Phenylselenenyl-1,3-anti-Azido-Alcohols via Hydroxyand Azido-Selenenylation Reactions |
| title_full | Diastereoselective Synthesis of 2-Phenylselenenyl-1,3-anti-Diols and 2-Phenylselenenyl-1,3-anti-Azido-Alcohols via Hydroxyand Azido-Selenenylation Reactions |
| title_fullStr | Diastereoselective Synthesis of 2-Phenylselenenyl-1,3-anti-Diols and 2-Phenylselenenyl-1,3-anti-Azido-Alcohols via Hydroxyand Azido-Selenenylation Reactions |
| title_full_unstemmed | Diastereoselective Synthesis of 2-Phenylselenenyl-1,3-anti-Diols and 2-Phenylselenenyl-1,3-anti-Azido-Alcohols via Hydroxyand Azido-Selenenylation Reactions |
| title_short | Diastereoselective Synthesis of 2-Phenylselenenyl-1,3-anti-Diols and 2-Phenylselenenyl-1,3-anti-Azido-Alcohols via Hydroxyand Azido-Selenenylation Reactions |
| title_sort | diastereoselective synthesis of 2 phenylselenenyl 1 3 anti diols and 2 phenylselenenyl 1 3 anti azido alcohols via hydroxyand azido selenenylation reactions |
| topic | Azides diols seleniraniun ion. |
| url | http://www.mdpi.com/1420-3049/10/2/383/ |
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