Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyliminomethyl-κN)phenolato-κO]palladium(II)
In the title complex, [Pd(C20H15N4O)2], the PdII atom is tetracoordinated by two N atoms and two O atoms from two bidentate imine–benzotriazole phenolate ligands, forming a square-planar environment. The asymmetric unit contains two half-molecules in both of which the PdII atom lies on...
Main Authors: | , , |
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Format: | Article |
Language: | English |
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International Union of Crystallography
2011-12-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811049555 |
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author | Jing-Kai Su Chen-Yu Li Bao-Tsan Ko |
author_facet | Jing-Kai Su Chen-Yu Li Bao-Tsan Ko |
author_sort | Jing-Kai Su |
collection | DOAJ |
description | In the title complex, [Pd(C20H15N4O)2], the PdII atom is tetracoordinated by two N atoms and two O atoms from two bidentate imine–benzotriazole phenolate ligands, forming a square-planar environment. The asymmetric unit contains two half-molecules in both of which the PdII atom lies on a centre of symmetry. The average distances between the PdII atom and the coordinated O and N atoms are 1.9831 (12) and 2.012 (2) Å, respectively. |
first_indexed | 2024-04-11T18:45:19Z |
format | Article |
id | doaj.art-8530372024164a7ba9f2d6a9da28e6de |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-04-11T18:45:19Z |
publishDate | 2011-12-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-8530372024164a7ba9f2d6a9da28e6de2022-12-22T04:08:50ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712m1831m183110.1107/S1600536811049555Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyliminomethyl-κN)phenolato-κO]palladium(II)Jing-Kai SuChen-Yu LiBao-Tsan KoIn the title complex, [Pd(C20H15N4O)2], the PdII atom is tetracoordinated by two N atoms and two O atoms from two bidentate imine–benzotriazole phenolate ligands, forming a square-planar environment. The asymmetric unit contains two half-molecules in both of which the PdII atom lies on a centre of symmetry. The average distances between the PdII atom and the coordinated O and N atoms are 1.9831 (12) and 2.012 (2) Å, respectively.http://scripts.iucr.org/cgi-bin/paper?S1600536811049555 |
spellingShingle | Jing-Kai Su Chen-Yu Li Bao-Tsan Ko Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyliminomethyl-κN)phenolato-κO]palladium(II) Acta Crystallographica Section E |
title | Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyliminomethyl-κN)phenolato-κO]palladium(II) |
title_full | Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyliminomethyl-κN)phenolato-κO]palladium(II) |
title_fullStr | Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyliminomethyl-κN)phenolato-κO]palladium(II) |
title_full_unstemmed | Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyliminomethyl-κN)phenolato-κO]palladium(II) |
title_short | Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyliminomethyl-κN)phenolato-κO]palladium(II) |
title_sort | bis 2 2h benzotriazol 2 yl 4 methyl 6 phenyliminomethyl amp 954 n phenolato amp 954 o palladium ii |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536811049555 |
work_keys_str_mv | AT jingkaisu bis22hbenzotriazol2yl4methyl6phenyliminomethylamp954nphenolatoamp954opalladiumii AT chenyuli bis22hbenzotriazol2yl4methyl6phenyliminomethylamp954nphenolatoamp954opalladiumii AT baotsanko bis22hbenzotriazol2yl4methyl6phenyliminomethylamp954nphenolatoamp954opalladiumii |