Diethyl 7,7′-dichloro-4-oxo-4H-[1,4′-biquinoline]-3,3′-dicarboxylate
In the title compound, C24H18Cl2N2O5, the quinoline and quinolinone moieties are nearly perpendicular to each other, forming a dihedral angle of 82.36 (3)°. In the crystal, molecules form a halogen bond between a Cl atom of a quinolinone moiety and the N atom of the quinoline moiety of the inversion...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814010320 |
| _version_ | 1819003319021993984 |
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| author | Yoshinobu Ishikawa Yasuhiro Sugisawa |
| author_facet | Yoshinobu Ishikawa Yasuhiro Sugisawa |
| author_sort | Yoshinobu Ishikawa |
| collection | DOAJ |
| description | In the title compound, C24H18Cl2N2O5, the quinoline and quinolinone moieties are nearly perpendicular to each other, forming a dihedral angle of 82.36 (3)°. In the crystal, molecules form a halogen bond between a Cl atom of a quinolinone moiety and the N atom of the quinoline moiety of the inversion equivalent [Cl...N = 3.106 (3) Å]. The molecules also form two kinds of C—H...O hydrogen-bonded centrosymmetric inversion dimers, making chains along the c-axis direction which are further interlinked by the halogen bonds into layers parallel to the bc plane. |
| first_indexed | 2024-12-20T23:19:06Z |
| format | Article |
| id | doaj.art-853cda488b414d21aec1af3a96407e4f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T23:19:06Z |
| publishDate | 2014-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-853cda488b414d21aec1af3a96407e4f2022-12-21T19:23:35ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-06-01706o655o65510.1107/S1600536814010320ld2125Diethyl 7,7′-dichloro-4-oxo-4H-[1,4′-biquinoline]-3,3′-dicarboxylateYoshinobu Ishikawa0Yasuhiro Sugisawa1School of Pharmaceutical Sciences, University of Shizuoka, 52-1 Yada, Suruga-ku, Shizuoka 422-8526, JapanSchool of Pharmaceutical Sciences, University of Shizuoka, 52-1 Yada, Suruga-ku, Shizuoka 422-8526, JapanIn the title compound, C24H18Cl2N2O5, the quinoline and quinolinone moieties are nearly perpendicular to each other, forming a dihedral angle of 82.36 (3)°. In the crystal, molecules form a halogen bond between a Cl atom of a quinolinone moiety and the N atom of the quinoline moiety of the inversion equivalent [Cl...N = 3.106 (3) Å]. The molecules also form two kinds of C—H...O hydrogen-bonded centrosymmetric inversion dimers, making chains along the c-axis direction which are further interlinked by the halogen bonds into layers parallel to the bc plane.http://scripts.iucr.org/cgi-bin/paper?S1600536814010320 |
| spellingShingle | Yoshinobu Ishikawa Yasuhiro Sugisawa Diethyl 7,7′-dichloro-4-oxo-4H-[1,4′-biquinoline]-3,3′-dicarboxylate Acta Crystallographica Section E |
| title | Diethyl 7,7′-dichloro-4-oxo-4H-[1,4′-biquinoline]-3,3′-dicarboxylate |
| title_full | Diethyl 7,7′-dichloro-4-oxo-4H-[1,4′-biquinoline]-3,3′-dicarboxylate |
| title_fullStr | Diethyl 7,7′-dichloro-4-oxo-4H-[1,4′-biquinoline]-3,3′-dicarboxylate |
| title_full_unstemmed | Diethyl 7,7′-dichloro-4-oxo-4H-[1,4′-biquinoline]-3,3′-dicarboxylate |
| title_short | Diethyl 7,7′-dichloro-4-oxo-4H-[1,4′-biquinoline]-3,3′-dicarboxylate |
| title_sort | diethyl 7 7 dichloro 4 oxo 4h 1 4 biquinoline 3 3 dicarboxylate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814010320 |
| work_keys_str_mv | AT yoshinobuishikawa diethyl77dichloro4oxo4h14biquinoline33dicarboxylate AT yasuhirosugisawa diethyl77dichloro4oxo4h14biquinoline33dicarboxylate |