A new coordination tetramer of copper(I) iodide and benzyldimethylamine: tetra-μ3-iodido-tetrakis[(benzyldimethylamine-κN)copper(I)]
The title compound, [Cu4I4(C9H13N)4], has a distorted cubane-like [Cu4I4] core structure. Each CuI atom is tetrahedrally coordinated by three I atoms and one N atom of an benzyldimethylamine ligand. Each I atom acts as a μ3-ligand, linking three CuI atoms. The Cu—I bond di...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809026208 |
| _version_ | 1828884660989460480 |
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| author | Jianguo Pan Yujie Cui Yuebao Li Shuying Yang |
| author_facet | Jianguo Pan Yujie Cui Yuebao Li Shuying Yang |
| author_sort | Jianguo Pan |
| collection | DOAJ |
| description | The title compound, [Cu4I4(C9H13N)4], has a distorted cubane-like [Cu4I4] core structure. Each CuI atom is tetrahedrally coordinated by three I atoms and one N atom of an benzyldimethylamine ligand. Each I atom acts as a μ3-ligand, linking three CuI atoms. The Cu—I bond distances vary between 2.6328 (7) and 2.7121 (6) Å, while the Cu—N bond distances vary between 2.107 (3) and 2.122 (3) Å. |
| first_indexed | 2024-12-13T11:12:14Z |
| format | Article |
| id | doaj.art-8548380d8ca2493c8e5090622fa71bec |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T11:12:14Z |
| publishDate | 2009-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-8548380d8ca2493c8e5090622fa71bec2022-12-21T23:48:42ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658m906m90610.1107/S1600536809026208A new coordination tetramer of copper(I) iodide and benzyldimethylamine: tetra-μ3-iodido-tetrakis[(benzyldimethylamine-κN)copper(I)]Jianguo PanYujie CuiYuebao LiShuying YangThe title compound, [Cu4I4(C9H13N)4], has a distorted cubane-like [Cu4I4] core structure. Each CuI atom is tetrahedrally coordinated by three I atoms and one N atom of an benzyldimethylamine ligand. Each I atom acts as a μ3-ligand, linking three CuI atoms. The Cu—I bond distances vary between 2.6328 (7) and 2.7121 (6) Å, while the Cu—N bond distances vary between 2.107 (3) and 2.122 (3) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536809026208 |
| spellingShingle | Jianguo Pan Yujie Cui Yuebao Li Shuying Yang A new coordination tetramer of copper(I) iodide and benzyldimethylamine: tetra-μ3-iodido-tetrakis[(benzyldimethylamine-κN)copper(I)] Acta Crystallographica Section E |
| title | A new coordination tetramer of copper(I) iodide and benzyldimethylamine: tetra-μ3-iodido-tetrakis[(benzyldimethylamine-κN)copper(I)] |
| title_full | A new coordination tetramer of copper(I) iodide and benzyldimethylamine: tetra-μ3-iodido-tetrakis[(benzyldimethylamine-κN)copper(I)] |
| title_fullStr | A new coordination tetramer of copper(I) iodide and benzyldimethylamine: tetra-μ3-iodido-tetrakis[(benzyldimethylamine-κN)copper(I)] |
| title_full_unstemmed | A new coordination tetramer of copper(I) iodide and benzyldimethylamine: tetra-μ3-iodido-tetrakis[(benzyldimethylamine-κN)copper(I)] |
| title_short | A new coordination tetramer of copper(I) iodide and benzyldimethylamine: tetra-μ3-iodido-tetrakis[(benzyldimethylamine-κN)copper(I)] |
| title_sort | new coordination tetramer of copper i iodide and benzyldimethylamine tetra amp 956 3 iodido tetrakis benzyldimethylamine amp 954 n copper i |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809026208 |
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