2-Methyl-N-(3-methylphenyl)benzamide
In the structure of the title compound (N3MP2MBA), C15H15NO, the conformation of the N—H bond is anti to the meta-methyl substituent in the aniline ring and that of the C=O bond is syn to the ortho-methyl substituent in the benzoyl ring, while the conformations of the N—H and C=O...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808003103 |
| _version_ | 1828436958122082304 |
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| author | Hartmut Fuess B. P. Sowmya Sabine Foro B. Thimme Gowda |
| author_facet | Hartmut Fuess B. P. Sowmya Sabine Foro B. Thimme Gowda |
| author_sort | Hartmut Fuess |
| collection | DOAJ |
| description | In the structure of the title compound (N3MP2MBA), C15H15NO, the conformation of the N—H bond is anti to the meta-methyl substituent in the aniline ring and that of the C=O bond is syn to the ortho-methyl substituent in the benzoyl ring, while the conformations of the N—H and C=O bonds are anti to each other. The bond parameters in N3MP2MBA are similar to those in 2-methyl-N-phenylbenzamide, N-(3,4-dimethylphenyl)benzamide and other benzanilides. The amide group, –NHCO–, makes a dihedral angle of 55.2 (7)° with the benzoyl ring, while the dihedral angle between the two benzene rings (benzoyl and aniline) is 36.2 (1)°. N—H...O hydrogen bonds give rise to infinite chains running along the b axis of the crystal structure. |
| first_indexed | 2024-12-10T19:36:32Z |
| format | Article |
| id | doaj.art-8557820e3bca4d4499e64bfccab20976 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T19:36:32Z |
| publishDate | 2008-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-8557820e3bca4d4499e64bfccab209762022-12-22T01:36:07ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642o541o54110.1107/S16005368080031032-Methyl-N-(3-methylphenyl)benzamideHartmut FuessB. P. SowmyaSabine ForoB. Thimme GowdaIn the structure of the title compound (N3MP2MBA), C15H15NO, the conformation of the N—H bond is anti to the meta-methyl substituent in the aniline ring and that of the C=O bond is syn to the ortho-methyl substituent in the benzoyl ring, while the conformations of the N—H and C=O bonds are anti to each other. The bond parameters in N3MP2MBA are similar to those in 2-methyl-N-phenylbenzamide, N-(3,4-dimethylphenyl)benzamide and other benzanilides. The amide group, –NHCO–, makes a dihedral angle of 55.2 (7)° with the benzoyl ring, while the dihedral angle between the two benzene rings (benzoyl and aniline) is 36.2 (1)°. N—H...O hydrogen bonds give rise to infinite chains running along the b axis of the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536808003103 |
| spellingShingle | Hartmut Fuess B. P. Sowmya Sabine Foro B. Thimme Gowda 2-Methyl-N-(3-methylphenyl)benzamide Acta Crystallographica Section E |
| title | 2-Methyl-N-(3-methylphenyl)benzamide |
| title_full | 2-Methyl-N-(3-methylphenyl)benzamide |
| title_fullStr | 2-Methyl-N-(3-methylphenyl)benzamide |
| title_full_unstemmed | 2-Methyl-N-(3-methylphenyl)benzamide |
| title_short | 2-Methyl-N-(3-methylphenyl)benzamide |
| title_sort | 2 methyl n 3 methylphenyl benzamide |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808003103 |
| work_keys_str_mv | AT hartmutfuess 2methyln3methylphenylbenzamide AT bpsowmya 2methyln3methylphenylbenzamide AT sabineforo 2methyln3methylphenylbenzamide AT bthimmegowda 2methyln3methylphenylbenzamide |