Hydro/ Solvothermal Synthesis and Crystal Structure of New Ni(II) Coordination Polymer Containing Pamoic Acid and Ethylenediamine Mixed Ligands : {[Ni(µ-pam)(en)2]·H2O}n
The new coordination polymers arranged from flexible pamoic acid, namely {[Ni(µ-pam)(en)2]·H2O}n (1), (H2pam= pamoic acid, en= ethylenediamine), have been synthesized under hydro/ solvothermal conditions and characterized by elemental analysis, simultaneous TG, DTA techniques, IR spectroscopy, and X...
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| Format: | Article |
| Language: | English |
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Turkish Chemical Society
2017-08-01
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| Series: | Journal of the Turkish Chemical Society, Section A: Chemistry |
| Subjects: | |
| Online Access: | http://dergipark.gov.tr/jotcsa/issue/30155/296299 |
| _version_ | 1797923329496055808 |
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| author | Yasemin Tümer Onur Şahin |
| author_facet | Yasemin Tümer Onur Şahin |
| author_sort | Yasemin Tümer |
| collection | DOAJ |
| description | The new coordination polymers arranged from flexible pamoic acid, namely {[Ni(µ-pam)(en)2]·H2O}n (1), (H2pam= pamoic acid, en= ethylenediamine), have been synthesized under hydro/ solvothermal conditions and characterized by elemental analysis, simultaneous TG, DTA techniques, IR spectroscopy, and X-ray crystallography. X-ray single crystal structure analysis of 1 shows that the Ni(II) ions are bridged by pamoic acid ligands to generate 1dimensional (1D) coordination polymer running parallel to the direction, with the Ni∙∙∙Ni separation is 14.057 Å. Adjacent 1D chains are connected by N-H···O and O-H···O hydrogen bonds to establishing 3 dimensional (3D) supramolecular network. |
| first_indexed | 2024-04-10T14:44:47Z |
| format | Article |
| id | doaj.art-8562a0f3b96b4a2f8e0c2aff6b6b446a |
| institution | Directory Open Access Journal |
| issn | 2149-0120 |
| language | English |
| last_indexed | 2024-04-10T14:44:47Z |
| publishDate | 2017-08-01 |
| publisher | Turkish Chemical Society |
| record_format | Article |
| series | Journal of the Turkish Chemical Society, Section A: Chemistry |
| spelling | doaj.art-8562a0f3b96b4a2f8e0c2aff6b6b446a2023-02-15T16:07:56ZengTurkish Chemical SocietyJournal of the Turkish Chemical Society, Section A: Chemistry2149-01202017-08-014386987610.18596/jotcsa.296299Hydro/ Solvothermal Synthesis and Crystal Structure of New Ni(II) Coordination Polymer Containing Pamoic Acid and Ethylenediamine Mixed Ligands : {[Ni(µ-pam)(en)2]·H2O}nYasemin Tümer0Onur Şahin1Karabuk UniversitySinop UniversityThe new coordination polymers arranged from flexible pamoic acid, namely {[Ni(µ-pam)(en)2]·H2O}n (1), (H2pam= pamoic acid, en= ethylenediamine), have been synthesized under hydro/ solvothermal conditions and characterized by elemental analysis, simultaneous TG, DTA techniques, IR spectroscopy, and X-ray crystallography. X-ray single crystal structure analysis of 1 shows that the Ni(II) ions are bridged by pamoic acid ligands to generate 1dimensional (1D) coordination polymer running parallel to the direction, with the Ni∙∙∙Ni separation is 14.057 Å. Adjacent 1D chains are connected by N-H···O and O-H···O hydrogen bonds to establishing 3 dimensional (3D) supramolecular network.http://dergipark.gov.tr/jotcsa/issue/30155/296299Hydro/ solvothermal synthesiscoordination polymerspamoic acid |
| spellingShingle | Yasemin Tümer Onur Şahin Hydro/ Solvothermal Synthesis and Crystal Structure of New Ni(II) Coordination Polymer Containing Pamoic Acid and Ethylenediamine Mixed Ligands : {[Ni(µ-pam)(en)2]·H2O}n Journal of the Turkish Chemical Society, Section A: Chemistry Hydro/ solvothermal synthesis coordination polymers pamoic acid |
| title | Hydro/ Solvothermal Synthesis and Crystal Structure of New Ni(II) Coordination Polymer Containing Pamoic Acid and Ethylenediamine Mixed Ligands : {[Ni(µ-pam)(en)2]·H2O}n |
| title_full | Hydro/ Solvothermal Synthesis and Crystal Structure of New Ni(II) Coordination Polymer Containing Pamoic Acid and Ethylenediamine Mixed Ligands : {[Ni(µ-pam)(en)2]·H2O}n |
| title_fullStr | Hydro/ Solvothermal Synthesis and Crystal Structure of New Ni(II) Coordination Polymer Containing Pamoic Acid and Ethylenediamine Mixed Ligands : {[Ni(µ-pam)(en)2]·H2O}n |
| title_full_unstemmed | Hydro/ Solvothermal Synthesis and Crystal Structure of New Ni(II) Coordination Polymer Containing Pamoic Acid and Ethylenediamine Mixed Ligands : {[Ni(µ-pam)(en)2]·H2O}n |
| title_short | Hydro/ Solvothermal Synthesis and Crystal Structure of New Ni(II) Coordination Polymer Containing Pamoic Acid and Ethylenediamine Mixed Ligands : {[Ni(µ-pam)(en)2]·H2O}n |
| title_sort | hydro solvothermal synthesis and crystal structure of new ni ii coordination polymer containing pamoic acid and ethylenediamine mixed ligands ni µ pam en 2 ·h2o n |
| topic | Hydro/ solvothermal synthesis coordination polymers pamoic acid |
| url | http://dergipark.gov.tr/jotcsa/issue/30155/296299 |
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