Polyethylenimine-Ethoxylated Interfacial Layer for Efficient Electron Collection in SnO<sub>2</sub>-Based Inverted Organic Solar Cells

In this work, we studied inverted organic solar cells based on bulk heterojunction using poly(3-hexylthiophene-2,5-diyl):[6,6]-phenyl-C71-butyric acid methyl ester (P3HT:PCBM) as an active layer and a novel cathode buffer bilayer consisting of tin dioxide (SnO<sub>2</sub>) combined with...

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Bibliographic Details
Main Authors: Ikram Anefnaf, Safae Aazou, Guy Schmerber, Siham Refki, Nicolas Zimmermann, Thomas Heiser, Gérald Ferblantier, Abdelilah Slaoui, Aziz Dinia, Mohammed Abd-Lefdil, Zouheir Sekkat
Format: Article
Language:English
Published: MDPI AG 2020-08-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/10/9/731
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Summary:In this work, we studied inverted organic solar cells based on bulk heterojunction using poly(3-hexylthiophene-2,5-diyl):[6,6]-phenyl-C71-butyric acid methyl ester (P3HT:PCBM) as an active layer and a novel cathode buffer bilayer consisting of tin dioxide (SnO<sub>2</sub>) combined with polyethylenimine-ethoxylated (PEIE) to overcome the limitations of the single cathode buffer layer. The combination of SnO<sub>2</sub> with PEIE is a promising approach that improves the charge carrier collection and reduces the recombination. The efficient device, which is prepared with a cathode buffer bilayer of 20 nm SnO<sub>2</sub> combined with 10 nm PEIE, achieved Jsc = 7.86 mA/cm<sup>2</sup>, Voc = 574 mV and PCE = 2.84%. The obtained results exceed the performances of reference solar cell using only a single cathode layer of either SnO<sub>2</sub> or PEIE.
ISSN:2073-4352