Summary: | In this work, we studied inverted organic solar cells based on bulk heterojunction using poly(3-hexylthiophene-2,5-diyl):[6,6]-phenyl-C71-butyric acid methyl ester (P3HT:PCBM) as an active layer and a novel cathode buffer bilayer consisting of tin dioxide (SnO<sub>2</sub>) combined with polyethylenimine-ethoxylated (PEIE) to overcome the limitations of the single cathode buffer layer. The combination of SnO<sub>2</sub> with PEIE is a promising approach that improves the charge carrier collection and reduces the recombination. The efficient device, which is prepared with a cathode buffer bilayer of 20 nm SnO<sub>2</sub> combined with 10 nm PEIE, achieved Jsc = 7.86 mA/cm<sup>2</sup>, Voc = 574 mV and PCE = 2.84%. The obtained results exceed the performances of reference solar cell using only a single cathode layer of either SnO<sub>2</sub> or PEIE.
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