(<i>Z</i>)-2-(1-(5-Methyl-1-(4-nitrophenyl)-1<i>H</i>-1,2,3-triazol-4-yl)ethylidene)-<i>N</i>-phenylhydrazine-1-carbothioamide

(<i>Z</i>)-2-(1-(5-Methyl-1-(4-nitrophenyl)-1<i>H</i>-1,2,3-triazol-4-yl)ethylidene)-<i>N</i>-phenylhydrazine-1-carbothioamide

Reaction of equimolar equivalents of 1-(5-methyl-1-(4-nitrophenyl)-1<i>H</i>-1,2,3-triazol-4-yl)ethan-1-one (<b>1</b>) and <i>N</i>-phenylhydrazinecarbothioamide (<b>2</b>) in boiling ethanol containing a catalytic amount of concentrated hydrochloric a...

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Bibliographic Details
Main Authors:	Benson M. Kariuki, Bakr F. Abdel-Wahab, Mohamed S. Bekheit, Gamal A. El-Hiti
Format:	Article
Language:	English
Published:	MDPI AG 2022-10-01
Series:	Molbank
Subjects:	synthesis 1,2,3-triazole <i>N</i>-phenylhydrazinecarbothioamide X-ray diffraction heterocycles hydrazones
Online Access:	https://www.mdpi.com/1422-8599/2022/4/M1462

Description
Summary:	Reaction of equimolar equivalents of 1-(5-methyl-1-(4-nitrophenyl)-1<i>H</i>-1,2,3-triazol-4-yl)ethan-1-one (<b>1</b>) and <i>N</i>-phenylhydrazinecarbothioamide (<b>2</b>) in boiling ethanol containing a catalytic amount of concentrated hydrochloric acid for 4 h gave (<i>Z</i>)-2-(1-(5-methyl-1-(4-nitrophenyl)-1<i>H</i>-1,2,3-triazol-4-yl)ethylidene)-<i>N</i>-phenylhydrazine-1-carbothioamide (<b>3</b>) with 88% yield. The structure of <b>3</b> was established using single-crystal X-ray diffraction and magnetic resonance spectroscopy.
ISSN:	1422-8599