Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ4N)antimony(V) hemi{di-μ-chlorido-bis[trichloridoantimonate(III)]} dichloromethane monosolvate
The asymmetric unit of the title complex, [Sb(C44H28N4)Cl2][Sb2Cl8]0.5·CH2Cl2, is composed of a SbV complex cation wherein the Sb atom is hexacoordinated by four N atoms of the pyrrole rings of the tetraphenylporphyrinate (TPP) ligands and two chloride ions, a half di-μ-chl...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812018351 |
| _version_ | 1818958443830050816 |
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| author | Raoudha Soury Mohamed Sahah Belkhiria Habib Nasri Masood Parvez |
| author_facet | Raoudha Soury Mohamed Sahah Belkhiria Habib Nasri Masood Parvez |
| author_sort | Raoudha Soury |
| collection | DOAJ |
| description | The asymmetric unit of the title complex, [Sb(C44H28N4)Cl2][Sb2Cl8]0.5·CH2Cl2, is composed of a SbV complex cation wherein the Sb atom is hexacoordinated by four N atoms of the pyrrole rings of the tetraphenylporphyrinate (TPP) ligands and two chloride ions, a half di-μ-chlorido-bis[trichloridoantimonate(III)] counter-anion and a dichloromethane solvent molecule. In the cation, the average Sb—N distance is 2.066 (2) Å, while the Sb—Cl distances are 2.3410 (11) and 2.3639 (12) Å. The central unit of the cation, SbN4C20, is far from being planar, with deviations of atoms from the least-squares plane ranging from −0.110 (4) to 0.124 (4) Å. The Sb—Cl distances in the anion, which is located about an inversion center, lie in the wide range 2.3715 (13)–2.7489 (13) Å, the longest distances being between the Sb and bridging Cl atoms. The crystal structure is stabilized by intermolecular C—H...Cl interactions involving the cations, the anions and the solvent molecules. The solvent molecule is disordered over two orientations in a 0.901 (13):0.099 (13) ratio. |
| first_indexed | 2024-12-20T11:25:50Z |
| format | Article |
| id | doaj.art-864ac0fb4394489d94143e41b1818427 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:25:50Z |
| publishDate | 2012-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-864ac0fb4394489d94143e41b18184272022-12-21T19:42:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686m717m71810.1107/S1600536812018351Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ4N)antimony(V) hemi{di-μ-chlorido-bis[trichloridoantimonate(III)]} dichloromethane monosolvateRaoudha SouryMohamed Sahah BelkhiriaHabib NasriMasood ParvezThe asymmetric unit of the title complex, [Sb(C44H28N4)Cl2][Sb2Cl8]0.5·CH2Cl2, is composed of a SbV complex cation wherein the Sb atom is hexacoordinated by four N atoms of the pyrrole rings of the tetraphenylporphyrinate (TPP) ligands and two chloride ions, a half di-μ-chlorido-bis[trichloridoantimonate(III)] counter-anion and a dichloromethane solvent molecule. In the cation, the average Sb—N distance is 2.066 (2) Å, while the Sb—Cl distances are 2.3410 (11) and 2.3639 (12) Å. The central unit of the cation, SbN4C20, is far from being planar, with deviations of atoms from the least-squares plane ranging from −0.110 (4) to 0.124 (4) Å. The Sb—Cl distances in the anion, which is located about an inversion center, lie in the wide range 2.3715 (13)–2.7489 (13) Å, the longest distances being between the Sb and bridging Cl atoms. The crystal structure is stabilized by intermolecular C—H...Cl interactions involving the cations, the anions and the solvent molecules. The solvent molecule is disordered over two orientations in a 0.901 (13):0.099 (13) ratio.http://scripts.iucr.org/cgi-bin/paper?S1600536812018351 |
| spellingShingle | Raoudha Soury Mohamed Sahah Belkhiria Habib Nasri Masood Parvez Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ4N)antimony(V) hemi{di-μ-chlorido-bis[trichloridoantimonate(III)]} dichloromethane monosolvate Acta Crystallographica Section E |
| title | Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ4N)antimony(V) hemi{di-μ-chlorido-bis[trichloridoantimonate(III)]} dichloromethane monosolvate |
| title_full | Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ4N)antimony(V) hemi{di-μ-chlorido-bis[trichloridoantimonate(III)]} dichloromethane monosolvate |
| title_fullStr | Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ4N)antimony(V) hemi{di-μ-chlorido-bis[trichloridoantimonate(III)]} dichloromethane monosolvate |
| title_full_unstemmed | Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ4N)antimony(V) hemi{di-μ-chlorido-bis[trichloridoantimonate(III)]} dichloromethane monosolvate |
| title_short | Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ4N)antimony(V) hemi{di-μ-chlorido-bis[trichloridoantimonate(III)]} dichloromethane monosolvate |
| title_sort | dichlorido 5 10 15 20 tetraphenylporphyrinato amp 954 4n antimony v hemi di amp 956 chlorido bis trichloridoantimonate iii dichloromethane monosolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812018351 |
| work_keys_str_mv | AT raoudhasoury dichlorido5101520tetraphenylporphyrinatoamp9544nantimonyvhemidiamp956chloridobistrichloridoantimonateiiidichloromethanemonosolvate AT mohamedsahahbelkhiria dichlorido5101520tetraphenylporphyrinatoamp9544nantimonyvhemidiamp956chloridobistrichloridoantimonateiiidichloromethanemonosolvate AT habibnasri dichlorido5101520tetraphenylporphyrinatoamp9544nantimonyvhemidiamp956chloridobistrichloridoantimonateiiidichloromethanemonosolvate AT masoodparvez dichlorido5101520tetraphenylporphyrinatoamp9544nantimonyvhemidiamp956chloridobistrichloridoantimonateiiidichloromethanemonosolvate |