Alkali-Activated Mortars for Sustainable Building Solutions: Effect of Binder Composition on Technical Performance

There is a growing interest in the construction sector in the use of sustainable binders as an alternative to ordinary Portland cement, the production of which is highly impacting on the environment, due to high carbon dioxide emissions and energy consumption. Alkali-activated binders, especially th...

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Main Authors: Agnese Attanasio, Livio Pascali, Vito Tarantino, Wanda Arena, Alessandro Largo
Format: Article
Language:English
Published: MDPI AG 2018-02-01
Series:Environments
Subjects:
Online Access:http://www.mdpi.com/2076-3298/5/3/35
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author Agnese Attanasio
Livio Pascali
Vito Tarantino
Wanda Arena
Alessandro Largo
author_facet Agnese Attanasio
Livio Pascali
Vito Tarantino
Wanda Arena
Alessandro Largo
author_sort Agnese Attanasio
collection DOAJ
description There is a growing interest in the construction sector in the use of sustainable binders as an alternative to ordinary Portland cement, the production of which is highly impacting on the environment, due to high carbon dioxide emissions and energy consumption. Alkali-activated binders, especially those resulting from low-cost industrial by-products, such as coal fly ash or metallurgical slag, represent a sustainable option for cement replacement, though their use is more challenging, due to some technological issues related to workability or curing conditions. This paper presents sustainable alkali-activated mortars cured in room conditions and based on metakaolin, fly ash, and furnace slag (both by-products resulting from local sources) and relevant blends, aiming at their real scale application in the building sector. The effect of binder composition—gradually adjusted taking into consideration technical and environmental aspects (use of industrial by-products in place of natural materials in the view of resources saving)—on the performance (workability, compressive strength) of different mortar formulations, is discussed in detail. Some guidelines for the design of cement-free binders are given, taking into consideration the effect of each investigated alumino-silicate component. The technical feasibility to produce the mortars with standard procedures and equipment, the curing in room conditions, the promising results achieved in terms of workability and mechanical performance (from 20.0 MPa up to 52.0 MPa), confirm the potential of such materials for practical applications (masonry mortars of class M20 and Md). The cement-free binders resulting from this study can be used as reference for the development of mortars and concrete formulations for sustainable building materials production.
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spelling doaj.art-865fb23c07a14a34bdbe5fab3072b6a72022-12-22T04:23:00ZengMDPI AGEnvironments2076-32982018-02-01533510.3390/environments5030035environments5030035Alkali-Activated Mortars for Sustainable Building Solutions: Effect of Binder Composition on Technical PerformanceAgnese Attanasio0Livio Pascali1Vito Tarantino2Wanda Arena3Alessandro Largo4Diagnostic and Civil Engineering Area, Materials and Structures Engineering Department, CETMA—Technologies Design and Materials European Research Centre, 72100 Brindisi, ItalyCivil, Chemical, Environmental and Materials Engineering Department, University of Bologna, 40136 Bologna, ItalyDiagnostic and Civil Engineering Area, Materials and Structures Engineering Department, CETMA—Technologies Design and Materials European Research Centre, 72100 Brindisi, ItalyDiagnostic and Civil Engineering Area, Materials and Structures Engineering Department, CETMA—Technologies Design and Materials European Research Centre, 72100 Brindisi, ItalyDiagnostic and Civil Engineering Area, Materials and Structures Engineering Department, CETMA—Technologies Design and Materials European Research Centre, 72100 Brindisi, ItalyThere is a growing interest in the construction sector in the use of sustainable binders as an alternative to ordinary Portland cement, the production of which is highly impacting on the environment, due to high carbon dioxide emissions and energy consumption. Alkali-activated binders, especially those resulting from low-cost industrial by-products, such as coal fly ash or metallurgical slag, represent a sustainable option for cement replacement, though their use is more challenging, due to some technological issues related to workability or curing conditions. This paper presents sustainable alkali-activated mortars cured in room conditions and based on metakaolin, fly ash, and furnace slag (both by-products resulting from local sources) and relevant blends, aiming at their real scale application in the building sector. The effect of binder composition—gradually adjusted taking into consideration technical and environmental aspects (use of industrial by-products in place of natural materials in the view of resources saving)—on the performance (workability, compressive strength) of different mortar formulations, is discussed in detail. Some guidelines for the design of cement-free binders are given, taking into consideration the effect of each investigated alumino-silicate component. The technical feasibility to produce the mortars with standard procedures and equipment, the curing in room conditions, the promising results achieved in terms of workability and mechanical performance (from 20.0 MPa up to 52.0 MPa), confirm the potential of such materials for practical applications (masonry mortars of class M20 and Md). The cement-free binders resulting from this study can be used as reference for the development of mortars and concrete formulations for sustainable building materials production.http://www.mdpi.com/2076-3298/5/3/35alkali-activated binderscement-free mortarsenvironmentresource efficiencysecondary raw materials
spellingShingle Agnese Attanasio
Livio Pascali
Vito Tarantino
Wanda Arena
Alessandro Largo
Alkali-Activated Mortars for Sustainable Building Solutions: Effect of Binder Composition on Technical Performance
Environments
alkali-activated binders
cement-free mortars
environment
resource efficiency
secondary raw materials
title Alkali-Activated Mortars for Sustainable Building Solutions: Effect of Binder Composition on Technical Performance
title_full Alkali-Activated Mortars for Sustainable Building Solutions: Effect of Binder Composition on Technical Performance
title_fullStr Alkali-Activated Mortars for Sustainable Building Solutions: Effect of Binder Composition on Technical Performance
title_full_unstemmed Alkali-Activated Mortars for Sustainable Building Solutions: Effect of Binder Composition on Technical Performance
title_short Alkali-Activated Mortars for Sustainable Building Solutions: Effect of Binder Composition on Technical Performance
title_sort alkali activated mortars for sustainable building solutions effect of binder composition on technical performance
topic alkali-activated binders
cement-free mortars
environment
resource efficiency
secondary raw materials
url http://www.mdpi.com/2076-3298/5/3/35
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AT liviopascali alkaliactivatedmortarsforsustainablebuildingsolutionseffectofbindercompositionontechnicalperformance
AT vitotarantino alkaliactivatedmortarsforsustainablebuildingsolutionseffectofbindercompositionontechnicalperformance
AT wandaarena alkaliactivatedmortarsforsustainablebuildingsolutionseffectofbindercompositionontechnicalperformance
AT alessandrolargo alkaliactivatedmortarsforsustainablebuildingsolutionseffectofbindercompositionontechnicalperformance