Effect of clay on the fractions of potentially toxic elements in contaminated soil

The aim of the study was to evaluate the effect of clay as an amendment to decrease the mobility and plant availability of potentially toxic elements (PTEs). Kaolinite and vermiculite were added at a 9% application rate to a contaminated garden soil from Kutná Hora. Half of the original soil was aci...

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Main Authors: Kateřina Vejvodová, Ondřej Drábek, Christopher Ash, Václav Tejnecký, Karel Němeček, Luboš Borůvka
Format: Article
Language:English
Published: Czech Academy of Agricultural Sciences 2021-03-01
Series:Soil and Water Research
Subjects:
Online Access:https://swr.agriculturejournals.cz/artkey/swr-202101-0001_effect-of-clay-on-the-fractions-of-potentially-toxic-elements-in-contaminated-soil.php
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author Kateřina Vejvodová
Ondřej Drábek
Christopher Ash
Václav Tejnecký
Karel Němeček
Luboš Borůvka
author_facet Kateřina Vejvodová
Ondřej Drábek
Christopher Ash
Václav Tejnecký
Karel Němeček
Luboš Borůvka
author_sort Kateřina Vejvodová
collection DOAJ
description The aim of the study was to evaluate the effect of clay as an amendment to decrease the mobility and plant availability of potentially toxic elements (PTEs). Kaolinite and vermiculite were added at a 9% application rate to a contaminated garden soil from Kutná Hora. Half of the original soil was acidified by the addition of HNO3, to observe the effect of the pH on the adsorption of the PTEs. The samples were analysed four times over an eight-week period to evaluate the effect of the clay additions on the As, Cd, Pb and Zn plant availability and different fractions of the BCR sequential extraction. The results indicate that the PTEs were mainly bound by ion/cation exchange on the edges of the clay minerals and onto the Fe/Mn oxides and organic fractions in the soils. The significance (P < 0.05) of the pH was observed for the plant availability of the PTE, especially on the As and Cd. A comparison of the vermiculite in the form of chunks and as powder displayed the most statistically significant results, where the vermiculite powder significantly decreased the plant availability of the As, Cd and Pb, while the opposite effect was observed for the Zn.
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spelling doaj.art-86651295e7c843b995f276348c426c202023-02-23T03:48:47ZengCzech Academy of Agricultural SciencesSoil and Water Research1801-53951805-93842021-03-0116111010.17221/13/2020-SWRswr-202101-0001Effect of clay on the fractions of potentially toxic elements in contaminated soilKateřina VejvodováOndřej Drábek0Christopher Ash1Václav Tejnecký2Karel Němeček3Luboš Borůvka4Department of Soil Science and Soil Protection, Faculty of Agrobiology, Food and Natural Resources, Czech University of Life Sciences Prague, Prague, Czech RepublicDepartment of Soil Science and Soil Protection, Faculty of Agrobiology, Food and Natural Resources, Czech University of Life Sciences Prague, Prague, Czech RepublicDepartment of Soil Science and Soil Protection, Faculty of Agrobiology, Food and Natural Resources, Czech University of Life Sciences Prague, Prague, Czech RepublicDepartment of Soil Science and Soil Protection, Faculty of Agrobiology, Food and Natural Resources, Czech University of Life Sciences Prague, Prague, Czech RepublicDepartment of Soil Science and Soil Protection, Faculty of Agrobiology, Food and Natural Resources, Czech University of Life Sciences Prague, Prague, Czech RepublicThe aim of the study was to evaluate the effect of clay as an amendment to decrease the mobility and plant availability of potentially toxic elements (PTEs). Kaolinite and vermiculite were added at a 9% application rate to a contaminated garden soil from Kutná Hora. Half of the original soil was acidified by the addition of HNO3, to observe the effect of the pH on the adsorption of the PTEs. The samples were analysed four times over an eight-week period to evaluate the effect of the clay additions on the As, Cd, Pb and Zn plant availability and different fractions of the BCR sequential extraction. The results indicate that the PTEs were mainly bound by ion/cation exchange on the edges of the clay minerals and onto the Fe/Mn oxides and organic fractions in the soils. The significance (P < 0.05) of the pH was observed for the plant availability of the PTE, especially on the As and Cd. A comparison of the vermiculite in the form of chunks and as powder displayed the most statistically significant results, where the vermiculite powder significantly decreased the plant availability of the As, Cd and Pb, while the opposite effect was observed for the Zn.https://swr.agriculturejournals.cz/artkey/swr-202101-0001_effect-of-clay-on-the-fractions-of-potentially-toxic-elements-in-contaminated-soil.phpclay amendmentcontaminationplant availabilityptesoil acidification
spellingShingle Kateřina Vejvodová
Ondřej Drábek
Christopher Ash
Václav Tejnecký
Karel Němeček
Luboš Borůvka
Effect of clay on the fractions of potentially toxic elements in contaminated soil
Soil and Water Research
clay amendment
contamination
plant availability
pte
soil acidification
title Effect of clay on the fractions of potentially toxic elements in contaminated soil
title_full Effect of clay on the fractions of potentially toxic elements in contaminated soil
title_fullStr Effect of clay on the fractions of potentially toxic elements in contaminated soil
title_full_unstemmed Effect of clay on the fractions of potentially toxic elements in contaminated soil
title_short Effect of clay on the fractions of potentially toxic elements in contaminated soil
title_sort effect of clay on the fractions of potentially toxic elements in contaminated soil
topic clay amendment
contamination
plant availability
pte
soil acidification
url https://swr.agriculturejournals.cz/artkey/swr-202101-0001_effect-of-clay-on-the-fractions-of-potentially-toxic-elements-in-contaminated-soil.php
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AT ondrejdrabek effectofclayonthefractionsofpotentiallytoxicelementsincontaminatedsoil
AT christopherash effectofclayonthefractionsofpotentiallytoxicelementsincontaminatedsoil
AT vaclavtejnecky effectofclayonthefractionsofpotentiallytoxicelementsincontaminatedsoil
AT karelnemecek effectofclayonthefractionsofpotentiallytoxicelementsincontaminatedsoil
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