Phototransistor Behavior in CIGS Solar Cells and the Effect of the Back Contact Barrier

In this paper, the impact of the back contact barrier on the performance of Cu (In, Ga) Se<sub>2</sub> solar cells is addressed. This effect is clearly visible at lower temperatures, but it also influences the fundamental parameters of a solar cell, such as open-circuit voltage, fill fac...

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Main Authors: Ricardo Vidal Lorbada, Thomas Walter, David Fuertes Marrón, Dennis Muecke, Tetiana Lavrenko, Oliver Salomon, Raymund Schaeffler
Format: Article
Language:English
Published: MDPI AG 2020-09-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/13/18/4753
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author Ricardo Vidal Lorbada
Thomas Walter
David Fuertes Marrón
Dennis Muecke
Tetiana Lavrenko
Oliver Salomon
Raymund Schaeffler
author_facet Ricardo Vidal Lorbada
Thomas Walter
David Fuertes Marrón
Dennis Muecke
Tetiana Lavrenko
Oliver Salomon
Raymund Schaeffler
author_sort Ricardo Vidal Lorbada
collection DOAJ
description In this paper, the impact of the back contact barrier on the performance of Cu (In, Ga) Se<sub>2</sub> solar cells is addressed. This effect is clearly visible at lower temperatures, but it also influences the fundamental parameters of a solar cell, such as open-circuit voltage, fill factor and the efficiency at normal operation conditions. A phototransistor model was proposed in previous works and could satisfactorily explain specific effects associated with the back contact barrier, such as the dependence of the saturated current in the forward bias on the illumination level. The effect of this contribution is also studied in this research in the context of metastable parameter drift, typical for Cu (In, Ga) Se<sub>2</sub> thin-film solar cells, as a consequence of different bias or light soaking treatments under high-temperature conditions. The impact of the back contact barrier on Cu (In, Ga) Se<sub>2</sub> thin-film solar cells is analyzed based on experimental measurements as well as numerical simulations with Technology Computer-Aided Design (TCAD). A barrier-lowering model for the molybdenum/Cu (In, Ga) Se<sub>2</sub> Schottky interface was proposed to reach a better agreement between the simulations and the experimental results. Thus, in this work, the phototransistor behavior is discussed further in the context of metastabilities supported by numerical simulations.
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spelling doaj.art-867489f5342247d19183bc1faa9682f22023-11-20T13:29:01ZengMDPI AGEnergies1996-10732020-09-011318475310.3390/en13184753Phototransistor Behavior in CIGS Solar Cells and the Effect of the Back Contact BarrierRicardo Vidal Lorbada0Thomas Walter1David Fuertes Marrón2Dennis Muecke3Tetiana Lavrenko4Oliver Salomon5Raymund Schaeffler6Instituto de Energía Solar—ETSIT, Universidad Politécnica de Madrid, Avenida Complutense 30, 28040 Madrid, SpainInstitute of Mechatronics and Medical Engineering, Ulm University of Applied Sciences, Albert-Einstein-Allee 55, 89081 Ulm, GermanyInstituto de Energía Solar—ETSIT, Universidad Politécnica de Madrid, Avenida Complutense 30, 28040 Madrid, SpainInstitute of Mechatronics and Medical Engineering, Ulm University of Applied Sciences, Albert-Einstein-Allee 55, 89081 Ulm, GermanyInstitute of Mechatronics and Medical Engineering, Ulm University of Applied Sciences, Albert-Einstein-Allee 55, 89081 Ulm, GermanyZentrum für Sonnenenergie und Wasserstoff, Meitnerstr. 1, 70563 Stuttgart, GermanyNice Solar Energy GmbH, Alfred-Leikam-Str. 25, 74523 Schwäbisch Hall, GermanyIn this paper, the impact of the back contact barrier on the performance of Cu (In, Ga) Se<sub>2</sub> solar cells is addressed. This effect is clearly visible at lower temperatures, but it also influences the fundamental parameters of a solar cell, such as open-circuit voltage, fill factor and the efficiency at normal operation conditions. A phototransistor model was proposed in previous works and could satisfactorily explain specific effects associated with the back contact barrier, such as the dependence of the saturated current in the forward bias on the illumination level. The effect of this contribution is also studied in this research in the context of metastable parameter drift, typical for Cu (In, Ga) Se<sub>2</sub> thin-film solar cells, as a consequence of different bias or light soaking treatments under high-temperature conditions. The impact of the back contact barrier on Cu (In, Ga) Se<sub>2</sub> thin-film solar cells is analyzed based on experimental measurements as well as numerical simulations with Technology Computer-Aided Design (TCAD). A barrier-lowering model for the molybdenum/Cu (In, Ga) Se<sub>2</sub> Schottky interface was proposed to reach a better agreement between the simulations and the experimental results. Thus, in this work, the phototransistor behavior is discussed further in the context of metastabilities supported by numerical simulations.https://www.mdpi.com/1996-1073/13/18/4753photovoltaicsthin-filmsCIGSback contactbarrierphototransistor
spellingShingle Ricardo Vidal Lorbada
Thomas Walter
David Fuertes Marrón
Dennis Muecke
Tetiana Lavrenko
Oliver Salomon
Raymund Schaeffler
Phototransistor Behavior in CIGS Solar Cells and the Effect of the Back Contact Barrier
Energies
photovoltaics
thin-films
CIGS
back contact
barrier
phototransistor
title Phototransistor Behavior in CIGS Solar Cells and the Effect of the Back Contact Barrier
title_full Phototransistor Behavior in CIGS Solar Cells and the Effect of the Back Contact Barrier
title_fullStr Phototransistor Behavior in CIGS Solar Cells and the Effect of the Back Contact Barrier
title_full_unstemmed Phototransistor Behavior in CIGS Solar Cells and the Effect of the Back Contact Barrier
title_short Phototransistor Behavior in CIGS Solar Cells and the Effect of the Back Contact Barrier
title_sort phototransistor behavior in cigs solar cells and the effect of the back contact barrier
topic photovoltaics
thin-films
CIGS
back contact
barrier
phototransistor
url https://www.mdpi.com/1996-1073/13/18/4753
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