A New 2d Coordination Polymer Based on Zinc(Ii), 1,2,3-Benzenetricarboxylic Acid And 4,4ʹ-Bis(Imidazol-1-Ylmethyl)Biphenyl: Synthesis and Crystal Structure
The solvothermal reaction of zinc(II) nitrate with 1,2,3-benzenetricarboxylic acid (1,2,3-H3BTC) and 4,4ʹ-bis(imidazol-1-ylmethyl)biphenyl (BIBPh) produced a crystalline solid {[Zn3(BIBPh)3(BTC)2]∙H2O}n. The product has been structurally characterised and investigated by X-ray diffraction, IR and th...
| Main Author: | |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Academy of Sciences of Moldova, Institute of Chemistry
2023-06-01
|
| Series: | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
| Subjects: | |
| Online Access: |
http://cjm.ichem.md/sites/default/files/article_files/ChemJMold_10.19261cjm.2022.1021-Voda.pdf
|
| _version_ | 1797743180659032064 |
|---|---|
| author | Irina Voda |
| author_facet | Irina Voda |
| author_sort | Irina Voda |
| collection | DOAJ |
| description | The solvothermal reaction of zinc(II) nitrate with 1,2,3-benzenetricarboxylic acid (1,2,3-H3BTC) and 4,4ʹ-bis(imidazol-1-ylmethyl)biphenyl (BIBPh) produced a crystalline solid {[Zn3(BIBPh)3(BTC)2]∙H2O}n. The product has been structurally characterised and investigated by X-ray diffraction, IR and thermogravimetric methods. The polymer has a bidimentional structure and crystallizes in the P21/c space group of the monoclinic system with the following unit cell parameters: a= 14.8687(16), b= 36.915(4), c= 13.8378(16) (Å), β= 105.584(6)°. The asymmetric unit of the crystal structure contains three zinc(II) ions, three BIBPh ligands and two BTC3- monodentate ligands with all three deprotonated carboxylate groups that balance the overall charge. All zinc centers have similar coordination environment: each metal ion is four coordinated exhibiting a slightly distorted tetrahedral coordination, where two positions are occupied by oxygen atoms of the carboxylic acid and the other two by nitrogen atoms of imidazole subunits. |
| first_indexed | 2024-03-12T14:51:49Z |
| format | Article |
| id | doaj.art-867c88b1fa3a471f883a0f690442d0a3 |
| institution | Directory Open Access Journal |
| issn | 1857-1727 2345-1688 |
| language | English |
| last_indexed | 2024-03-12T14:51:49Z |
| publishDate | 2023-06-01 |
| publisher | Academy of Sciences of Moldova, Institute of Chemistry |
| record_format | Article |
| series | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
| spelling | doaj.art-867c88b1fa3a471f883a0f690442d0a32023-08-15T11:15:40ZengAcademy of Sciences of Moldova, Institute of ChemistryChemistry Journal of Moldova: General, Industrial and Ecological Chemistry1857-17272345-16882023-06-01181707610.19261/cjm.2022.10211021A New 2d Coordination Polymer Based on Zinc(Ii), 1,2,3-Benzenetricarboxylic Acid And 4,4ʹ-Bis(Imidazol-1-Ylmethyl)Biphenyl: Synthesis and Crystal StructureIrina Voda0 Institute of Chemistry, State University of Moldova, 3, Academiei str., Chisinau MD 2028, Republic of Moldova The solvothermal reaction of zinc(II) nitrate with 1,2,3-benzenetricarboxylic acid (1,2,3-H3BTC) and 4,4ʹ-bis(imidazol-1-ylmethyl)biphenyl (BIBPh) produced a crystalline solid {[Zn3(BIBPh)3(BTC)2]∙H2O}n. The product has been structurally characterised and investigated by X-ray diffraction, IR and thermogravimetric methods. The polymer has a bidimentional structure and crystallizes in the P21/c space group of the monoclinic system with the following unit cell parameters: a= 14.8687(16), b= 36.915(4), c= 13.8378(16) (Å), β= 105.584(6)°. The asymmetric unit of the crystal structure contains three zinc(II) ions, three BIBPh ligands and two BTC3- monodentate ligands with all three deprotonated carboxylate groups that balance the overall charge. All zinc centers have similar coordination environment: each metal ion is four coordinated exhibiting a slightly distorted tetrahedral coordination, where two positions are occupied by oxygen atoms of the carboxylic acid and the other two by nitrogen atoms of imidazole subunits. http://cjm.ichem.md/sites/default/files/article_files/ChemJMold_10.19261cjm.2022.1021-Voda.pdf coordination polymerx-ray diffractionzinc1,2,3-benzenetricarboxylic acid4,4ʹ-bis(imidazol-1-ylmethyl)biphenyl |
| spellingShingle | Irina Voda A New 2d Coordination Polymer Based on Zinc(Ii), 1,2,3-Benzenetricarboxylic Acid And 4,4ʹ-Bis(Imidazol-1-Ylmethyl)Biphenyl: Synthesis and Crystal Structure Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry coordination polymer x-ray diffraction zinc 1,2,3-benzenetricarboxylic acid 4,4ʹ-bis(imidazol-1-ylmethyl)biphenyl |
| title | A New 2d Coordination Polymer Based on Zinc(Ii), 1,2,3-Benzenetricarboxylic Acid And 4,4ʹ-Bis(Imidazol-1-Ylmethyl)Biphenyl: Synthesis and Crystal Structure |
| title_full | A New 2d Coordination Polymer Based on Zinc(Ii), 1,2,3-Benzenetricarboxylic Acid And 4,4ʹ-Bis(Imidazol-1-Ylmethyl)Biphenyl: Synthesis and Crystal Structure |
| title_fullStr | A New 2d Coordination Polymer Based on Zinc(Ii), 1,2,3-Benzenetricarboxylic Acid And 4,4ʹ-Bis(Imidazol-1-Ylmethyl)Biphenyl: Synthesis and Crystal Structure |
| title_full_unstemmed | A New 2d Coordination Polymer Based on Zinc(Ii), 1,2,3-Benzenetricarboxylic Acid And 4,4ʹ-Bis(Imidazol-1-Ylmethyl)Biphenyl: Synthesis and Crystal Structure |
| title_short | A New 2d Coordination Polymer Based on Zinc(Ii), 1,2,3-Benzenetricarboxylic Acid And 4,4ʹ-Bis(Imidazol-1-Ylmethyl)Biphenyl: Synthesis and Crystal Structure |
| title_sort | new 2d coordination polymer based on zinc ii 1 2 3 benzenetricarboxylic acid and 4 4 bis imidazol 1 ylmethyl biphenyl synthesis and crystal structure |
| topic | coordination polymer x-ray diffraction zinc 1,2,3-benzenetricarboxylic acid 4,4ʹ-bis(imidazol-1-ylmethyl)biphenyl |
| url |
http://cjm.ichem.md/sites/default/files/article_files/ChemJMold_10.19261cjm.2022.1021-Voda.pdf
|
| work_keys_str_mv | AT irinavoda anew2dcoordinationpolymerbasedonzincii123benzenetricarboxylicacidand44ʹbisimidazol1ylmethylbiphenylsynthesisandcrystalstructure AT irinavoda new2dcoordinationpolymerbasedonzincii123benzenetricarboxylicacidand44ʹbisimidazol1ylmethylbiphenylsynthesisandcrystalstructure |