Lithium-Ion Capacitors: A Review of Strategies toward Enhancing the Performance of the Activated Carbon Cathode

Lithium-ion capacitors (LiC) are promising hybrid devices bridging the gap between batteries and supercapacitors by offering simultaneous high specific power and specific energy. However, an indispensable critical component in LiC is the capacitive cathode for high power. Activated carbon (AC) is ty...

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Main Authors: Obinna Egwu Eleri, Fengliu Lou, Zhixin Yu
Format: Article
Language:English
Published: MDPI AG 2023-10-01
Series:Batteries
Subjects:
Online Access:https://www.mdpi.com/2313-0105/9/11/533
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author Obinna Egwu Eleri
Fengliu Lou
Zhixin Yu
author_facet Obinna Egwu Eleri
Fengliu Lou
Zhixin Yu
author_sort Obinna Egwu Eleri
collection DOAJ
description Lithium-ion capacitors (LiC) are promising hybrid devices bridging the gap between batteries and supercapacitors by offering simultaneous high specific power and specific energy. However, an indispensable critical component in LiC is the capacitive cathode for high power. Activated carbon (AC) is typically the cathode material due to its low cost, abundant raw material for production, sustainability, easily tunable properties, and scalability. However, compared to conventional battery-type cathodes, the low capacity of AC remains a limiting factor for improving the specific energy of LiC to match the battery counterparts. This review discusses recent approaches for achieving high-performance LiC, focusing on the AC cathode. The strategies are discussed with respect to active material property modifications, electrodes, electrolytes, and cell design techniques which have improved the AC’s capacity/capacitance, operating potential window, and electrochemical stability. Potential strategies and pathways for improved performance of the AC are pinpointed.
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spelling doaj.art-867fb955d1f74f0d9acf7833207c58ab2023-11-24T14:29:06ZengMDPI AGBatteries2313-01052023-10-0191153310.3390/batteries9110533Lithium-Ion Capacitors: A Review of Strategies toward Enhancing the Performance of the Activated Carbon CathodeObinna Egwu Eleri0Fengliu Lou1Zhixin Yu2Department of Energy and Petroleum Engineering, University of Stavanger, 4036 Stavanger, NorwayBeyonder AS, Stokkamyrveien 30, 4313 Sandnes, NorwayDepartment of Energy and Petroleum Engineering, University of Stavanger, 4036 Stavanger, NorwayLithium-ion capacitors (LiC) are promising hybrid devices bridging the gap between batteries and supercapacitors by offering simultaneous high specific power and specific energy. However, an indispensable critical component in LiC is the capacitive cathode for high power. Activated carbon (AC) is typically the cathode material due to its low cost, abundant raw material for production, sustainability, easily tunable properties, and scalability. However, compared to conventional battery-type cathodes, the low capacity of AC remains a limiting factor for improving the specific energy of LiC to match the battery counterparts. This review discusses recent approaches for achieving high-performance LiC, focusing on the AC cathode. The strategies are discussed with respect to active material property modifications, electrodes, electrolytes, and cell design techniques which have improved the AC’s capacity/capacitance, operating potential window, and electrochemical stability. Potential strategies and pathways for improved performance of the AC are pinpointed.https://www.mdpi.com/2313-0105/9/11/533activated carbonlithium-ion capacitorshigh energy densityhigh power density and long cycle life
spellingShingle Obinna Egwu Eleri
Fengliu Lou
Zhixin Yu
Lithium-Ion Capacitors: A Review of Strategies toward Enhancing the Performance of the Activated Carbon Cathode
Batteries
activated carbon
lithium-ion capacitors
high energy density
high power density and long cycle life
title Lithium-Ion Capacitors: A Review of Strategies toward Enhancing the Performance of the Activated Carbon Cathode
title_full Lithium-Ion Capacitors: A Review of Strategies toward Enhancing the Performance of the Activated Carbon Cathode
title_fullStr Lithium-Ion Capacitors: A Review of Strategies toward Enhancing the Performance of the Activated Carbon Cathode
title_full_unstemmed Lithium-Ion Capacitors: A Review of Strategies toward Enhancing the Performance of the Activated Carbon Cathode
title_short Lithium-Ion Capacitors: A Review of Strategies toward Enhancing the Performance of the Activated Carbon Cathode
title_sort lithium ion capacitors a review of strategies toward enhancing the performance of the activated carbon cathode
topic activated carbon
lithium-ion capacitors
high energy density
high power density and long cycle life
url https://www.mdpi.com/2313-0105/9/11/533
work_keys_str_mv AT obinnaegwueleri lithiumioncapacitorsareviewofstrategiestowardenhancingtheperformanceoftheactivatedcarboncathode
AT fengliulou lithiumioncapacitorsareviewofstrategiestowardenhancingtheperformanceoftheactivatedcarboncathode
AT zhixinyu lithiumioncapacitorsareviewofstrategiestowardenhancingtheperformanceoftheactivatedcarboncathode