Dataset of the electrochemical potential windows for the Au(hkl)|ionic liquid interfaces defined by the cut-off current densities

This data article describes the linear sweep voltammetry (LSV) profiles of five ionic liquids (ILs) at the low-index (hkl) (hkl = 111, 100, and 110) planes of Au. The LSV profiles were recorded at 25 ± 1°C for the Au(hkl)|IL interfaces maintained in a hanging meniscus configuration in an inert Ar at...

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Main Authors: Hiroyuki Ueda, Soichiro Yoshimoto
Format: Article
Language:English
Published: Elsevier 2021-12-01
Series:Data in Brief
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S235234092100860X
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author Hiroyuki Ueda
Soichiro Yoshimoto
author_facet Hiroyuki Ueda
Soichiro Yoshimoto
author_sort Hiroyuki Ueda
collection DOAJ
description This data article describes the linear sweep voltammetry (LSV) profiles of five ionic liquids (ILs) at the low-index (hkl) (hkl = 111, 100, and 110) planes of Au. The LSV profiles were recorded at 25 ± 1°C for the Au(hkl)|IL interfaces maintained in a hanging meniscus configuration in an inert Ar atmosphere (with H2O and O2 concentrations being lower than 5 ppm). The width of the electrical double-layer regions (Edl) and the electrochemical potential windows (Epw) of the ILs were evaluated based on the cut-off current densities (jcut-off): ±5, ±10, and ±20 µA cm–2 for Edl and ±0.1, ±0.5, and ±1.0 mA cm–2 for Epw. The potential values were calibrated to the redox potential of ferrocene/ferrocenium in each IL. A detailed discussion on the electrochemical behaviors of the ILs on Au(hkl) is provided in the related article “Voltammetric Investigation of Anodic and Cathodic Processes at Au(hkl)|Ionic Liquid Interfaces”, published in the Journal of Electroanalytical Chemistry (Ueda and Yoshimoto, 2021).
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spelling doaj.art-8682146cd68d4ab2b111487f95d59cfc2022-12-21T18:13:12ZengElsevierData in Brief2352-34092021-12-0139107585Dataset of the electrochemical potential windows for the Au(hkl)|ionic liquid interfaces defined by the cut-off current densitiesHiroyuki Ueda0Soichiro Yoshimoto1Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, JapanInstitute of Industrial Nanomaterials, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan; Corresponding author.This data article describes the linear sweep voltammetry (LSV) profiles of five ionic liquids (ILs) at the low-index (hkl) (hkl = 111, 100, and 110) planes of Au. The LSV profiles were recorded at 25 ± 1°C for the Au(hkl)|IL interfaces maintained in a hanging meniscus configuration in an inert Ar atmosphere (with H2O and O2 concentrations being lower than 5 ppm). The width of the electrical double-layer regions (Edl) and the electrochemical potential windows (Epw) of the ILs were evaluated based on the cut-off current densities (jcut-off): ±5, ±10, and ±20 µA cm–2 for Edl and ±0.1, ±0.5, and ±1.0 mA cm–2 for Epw. The potential values were calibrated to the redox potential of ferrocene/ferrocenium in each IL. A detailed discussion on the electrochemical behaviors of the ILs on Au(hkl) is provided in the related article “Voltammetric Investigation of Anodic and Cathodic Processes at Au(hkl)|Ionic Liquid Interfaces”, published in the Journal of Electroanalytical Chemistry (Ueda and Yoshimoto, 2021).http://www.sciencedirect.com/science/article/pii/S235234092100860XAu(hkl)Electrical double layerElectrochemical potential windowInterfacial processesIonic liquidsLinear sweep voltammetry
spellingShingle Hiroyuki Ueda
Soichiro Yoshimoto
Dataset of the electrochemical potential windows for the Au(hkl)|ionic liquid interfaces defined by the cut-off current densities
Data in Brief
Au(hkl)
Electrical double layer
Electrochemical potential window
Interfacial processes
Ionic liquids
Linear sweep voltammetry
title Dataset of the electrochemical potential windows for the Au(hkl)|ionic liquid interfaces defined by the cut-off current densities
title_full Dataset of the electrochemical potential windows for the Au(hkl)|ionic liquid interfaces defined by the cut-off current densities
title_fullStr Dataset of the electrochemical potential windows for the Au(hkl)|ionic liquid interfaces defined by the cut-off current densities
title_full_unstemmed Dataset of the electrochemical potential windows for the Au(hkl)|ionic liquid interfaces defined by the cut-off current densities
title_short Dataset of the electrochemical potential windows for the Au(hkl)|ionic liquid interfaces defined by the cut-off current densities
title_sort dataset of the electrochemical potential windows for the au hkl ionic liquid interfaces defined by the cut off current densities
topic Au(hkl)
Electrical double layer
Electrochemical potential window
Interfacial processes
Ionic liquids
Linear sweep voltammetry
url http://www.sciencedirect.com/science/article/pii/S235234092100860X
work_keys_str_mv AT hiroyukiueda datasetoftheelectrochemicalpotentialwindowsfortheauhklionicliquidinterfacesdefinedbythecutoffcurrentdensities
AT soichiroyoshimoto datasetoftheelectrochemicalpotentialwindowsfortheauhklionicliquidinterfacesdefinedbythecutoffcurrentdensities