New Compounds from the Roots of Corsican <i>Calicotome Villosa</i> (Poir.) Link.: Two Pterocarpans and a Dihydrobenzofuran

Three new compounds, a dihydrobenzofuran (coumaran) derivative (compound <b>1</b>) and two pterocarpans (compounds <b>2</b> and <b>3</b>) were isolated from a root extract of <i>Calicotome villosa</i> growing wild in Corsica. Their structures were eluc...

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Main Authors: Doreen Stacy Palu, Mathieu Paoli, Hervé Casabianca, Joseph Casanova, Ange Bighelli
Format: Article
Language:English
Published: MDPI AG 2020-07-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/25/15/3467
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author Doreen Stacy Palu
Mathieu Paoli
Hervé Casabianca
Joseph Casanova
Ange Bighelli
author_facet Doreen Stacy Palu
Mathieu Paoli
Hervé Casabianca
Joseph Casanova
Ange Bighelli
author_sort Doreen Stacy Palu
collection DOAJ
description Three new compounds, a dihydrobenzofuran (coumaran) derivative (compound <b>1</b>) and two pterocarpans (compounds <b>2</b> and <b>3</b>) were isolated from a root extract of <i>Calicotome villosa</i> growing wild in Corsica. Their structures were elucidated using 1D and 2D NMR spectroscopy and MS/MS as 2-(1-methylethenyl)-5-hydroxy-6-carbomethoxy-2,3-dihydro-benzofuran, 4,9-dihydroxy-3-methoxy-2-dimethylallylpterocarpan, and 4,9-dihydroxy-3′,3′-dimethyl-2,3-pyranopterocarpan.
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spelling doaj.art-8688bb2a622d4b8495a9d5ecd1e132142023-11-20T08:29:39ZengMDPI AGMolecules1420-30492020-07-012515346710.3390/molecules25153467New Compounds from the Roots of Corsican <i>Calicotome Villosa</i> (Poir.) Link.: Two Pterocarpans and a DihydrobenzofuranDoreen Stacy Palu0Mathieu Paoli1Hervé Casabianca2Joseph Casanova3Ange Bighelli4Department of Chemistry, Equipe Chimie-Biomasse, Université de Corse-CNRS, UMR 6134 SPE, Route des Sanguinaires, F- 20000 Ajaccio, FranceDepartment of Chemistry, Equipe Chimie-Biomasse, Université de Corse-CNRS, UMR 6134 SPE, Route des Sanguinaires, F- 20000 Ajaccio, FranceInstitut des Sciences Analytiques, Université de Lyon, CNRS, Université Claude Bernard Lyon 1, UMR 5280, 5 rue de la Doua, F-69100 Villeurbanne, FranceDepartment of Chemistry, Equipe Chimie-Biomasse, Université de Corse-CNRS, UMR 6134 SPE, Route des Sanguinaires, F- 20000 Ajaccio, FranceDepartment of Chemistry, Equipe Chimie-Biomasse, Université de Corse-CNRS, UMR 6134 SPE, Route des Sanguinaires, F- 20000 Ajaccio, FranceThree new compounds, a dihydrobenzofuran (coumaran) derivative (compound <b>1</b>) and two pterocarpans (compounds <b>2</b> and <b>3</b>) were isolated from a root extract of <i>Calicotome villosa</i> growing wild in Corsica. Their structures were elucidated using 1D and 2D NMR spectroscopy and MS/MS as 2-(1-methylethenyl)-5-hydroxy-6-carbomethoxy-2,3-dihydro-benzofuran, 4,9-dihydroxy-3-methoxy-2-dimethylallylpterocarpan, and 4,9-dihydroxy-3′,3′-dimethyl-2,3-pyranopterocarpan.https://www.mdpi.com/1420-3049/25/15/3467<i>Calicotome villosa</i>root extractpterocarpandihydrobenzofuran1D and 2D NMR
spellingShingle Doreen Stacy Palu
Mathieu Paoli
Hervé Casabianca
Joseph Casanova
Ange Bighelli
New Compounds from the Roots of Corsican <i>Calicotome Villosa</i> (Poir.) Link.: Two Pterocarpans and a Dihydrobenzofuran
Molecules
<i>Calicotome villosa</i>
root extract
pterocarpan
dihydrobenzofuran
1D and 2D NMR
title New Compounds from the Roots of Corsican <i>Calicotome Villosa</i> (Poir.) Link.: Two Pterocarpans and a Dihydrobenzofuran
title_full New Compounds from the Roots of Corsican <i>Calicotome Villosa</i> (Poir.) Link.: Two Pterocarpans and a Dihydrobenzofuran
title_fullStr New Compounds from the Roots of Corsican <i>Calicotome Villosa</i> (Poir.) Link.: Two Pterocarpans and a Dihydrobenzofuran
title_full_unstemmed New Compounds from the Roots of Corsican <i>Calicotome Villosa</i> (Poir.) Link.: Two Pterocarpans and a Dihydrobenzofuran
title_short New Compounds from the Roots of Corsican <i>Calicotome Villosa</i> (Poir.) Link.: Two Pterocarpans and a Dihydrobenzofuran
title_sort new compounds from the roots of corsican i calicotome villosa i poir link two pterocarpans and a dihydrobenzofuran
topic <i>Calicotome villosa</i>
root extract
pterocarpan
dihydrobenzofuran
1D and 2D NMR
url https://www.mdpi.com/1420-3049/25/15/3467
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