Effects of Horizontal Transport and Vertical Mixing on Nocturnal Ozone Pollution in the Pearl River Delta

Based on the meteorological, ozone (O<sub>3</sub>), and vertical observation data of 2020, this study sought to evaluate the daily variation in O<sub>3</sub>, particularly the characteristics of nocturnal ozone pollution. We also discuss the effect of local and mesoscale hori...

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Main Authors: Honglong Yang, Chao Lu, Yuanyuan Hu, Pak-Wai Chan, Lei Li, Li Zhang
Format: Article
Language:English
Published: MDPI AG 2022-08-01
Series:Atmosphere
Subjects:
Online Access:https://www.mdpi.com/2073-4433/13/8/1318
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author Honglong Yang
Chao Lu
Yuanyuan Hu
Pak-Wai Chan
Lei Li
Li Zhang
author_facet Honglong Yang
Chao Lu
Yuanyuan Hu
Pak-Wai Chan
Lei Li
Li Zhang
author_sort Honglong Yang
collection DOAJ
description Based on the meteorological, ozone (O<sub>3</sub>), and vertical observation data of 2020, this study sought to evaluate the daily variation in O<sub>3</sub>, particularly the characteristics of nocturnal ozone pollution. We also discuss the effect of local and mesoscale horizontal transport and vertical mixing on the formation of nocturnal O<sub>3</sub> pollution. Distinct seasonal characteristics of the daily O<sub>3</sub> variation in Shenzhen were identified. In particular, significant nocturnal peaks were found to regularly occur in the winter and spring (November–December and January–April). The monthly average of daily variation had a clear bimodal distribution. During the period, O<sub>3</sub> pollution frequently occurred at night, with the maximum hourly O<sub>3</sub> concentration reaching 203.5 μg/m<sup>3</sup>. Nocturnal O<sub>3</sub> pollution was closely associated with horizontal transport and vertical mixing. During the study period, the O<sub>3</sub> maximum values were recorded on 68 nights, primarily between 23:00 and 03:00, with occasional observation of two peaks. The impact of horizontal transport and vertical mixing on the nocturnal secondary O<sub>3</sub> maximum values was elaborated in two case studies, where vertical mixing was mainly associated with low-level jets, with strong wind shear enhancing turbulent mixing and transporting O<sub>3</sub> from the upper layers to the surface.
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spelling doaj.art-868d47bb3dba4c15880360b369774a332023-12-01T23:24:12ZengMDPI AGAtmosphere2073-44332022-08-01138131810.3390/atmos13081318Effects of Horizontal Transport and Vertical Mixing on Nocturnal Ozone Pollution in the Pearl River DeltaHonglong Yang0Chao Lu1Yuanyuan Hu2Pak-Wai Chan3Lei Li4Li Zhang5Shenzhen National Climate Observatory, Meteorological Bureau of Shenzhen Municipality, Shenzhen 518040, ChinaShenzhen National Climate Observatory, Meteorological Bureau of Shenzhen Municipality, Shenzhen 518040, ChinaShenzhen National Climate Observatory, Meteorological Bureau of Shenzhen Municipality, Shenzhen 518040, ChinaHong Kong Observatory, Hong Kong 999077, ChinaSchool of Atmospheric Sciences, Sun Yat-sen University, Zhuhai 519082, ChinaShenzhen National Climate Observatory, Meteorological Bureau of Shenzhen Municipality, Shenzhen 518040, ChinaBased on the meteorological, ozone (O<sub>3</sub>), and vertical observation data of 2020, this study sought to evaluate the daily variation in O<sub>3</sub>, particularly the characteristics of nocturnal ozone pollution. We also discuss the effect of local and mesoscale horizontal transport and vertical mixing on the formation of nocturnal O<sub>3</sub> pollution. Distinct seasonal characteristics of the daily O<sub>3</sub> variation in Shenzhen were identified. In particular, significant nocturnal peaks were found to regularly occur in the winter and spring (November–December and January–April). The monthly average of daily variation had a clear bimodal distribution. During the period, O<sub>3</sub> pollution frequently occurred at night, with the maximum hourly O<sub>3</sub> concentration reaching 203.5 μg/m<sup>3</sup>. Nocturnal O<sub>3</sub> pollution was closely associated with horizontal transport and vertical mixing. During the study period, the O<sub>3</sub> maximum values were recorded on 68 nights, primarily between 23:00 and 03:00, with occasional observation of two peaks. The impact of horizontal transport and vertical mixing on the nocturnal secondary O<sub>3</sub> maximum values was elaborated in two case studies, where vertical mixing was mainly associated with low-level jets, with strong wind shear enhancing turbulent mixing and transporting O<sub>3</sub> from the upper layers to the surface.https://www.mdpi.com/2073-4433/13/8/1318secondary ozone maximumadvectionvertical mixing
spellingShingle Honglong Yang
Chao Lu
Yuanyuan Hu
Pak-Wai Chan
Lei Li
Li Zhang
Effects of Horizontal Transport and Vertical Mixing on Nocturnal Ozone Pollution in the Pearl River Delta
Atmosphere
secondary ozone maximum
advection
vertical mixing
title Effects of Horizontal Transport and Vertical Mixing on Nocturnal Ozone Pollution in the Pearl River Delta
title_full Effects of Horizontal Transport and Vertical Mixing on Nocturnal Ozone Pollution in the Pearl River Delta
title_fullStr Effects of Horizontal Transport and Vertical Mixing on Nocturnal Ozone Pollution in the Pearl River Delta
title_full_unstemmed Effects of Horizontal Transport and Vertical Mixing on Nocturnal Ozone Pollution in the Pearl River Delta
title_short Effects of Horizontal Transport and Vertical Mixing on Nocturnal Ozone Pollution in the Pearl River Delta
title_sort effects of horizontal transport and vertical mixing on nocturnal ozone pollution in the pearl river delta
topic secondary ozone maximum
advection
vertical mixing
url https://www.mdpi.com/2073-4433/13/8/1318
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