Treatment and characterization of phosphorus from synthetic wastewater using aluminum plate electrodes in the electrocoagulation process

Abstract The main objective of this study is treatment and characterization of phosphorus from synthetic wastewater using aluminum electrodes in the electrocoagulation process. EC experimental setups were designed and different parameters were optimized. The maximum amounts of phosphorus removal eff...

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Main Authors: Dessie Tibebe, Yezbie Kassa, Ashok N. Bhaskarwar
Format: Article
Language:English
Published: BMC 2019-08-01
Series:BMC Chemistry
Subjects:
Online Access:http://link.springer.com/article/10.1186/s13065-019-0628-1
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author Dessie Tibebe
Yezbie Kassa
Ashok N. Bhaskarwar
author_facet Dessie Tibebe
Yezbie Kassa
Ashok N. Bhaskarwar
author_sort Dessie Tibebe
collection DOAJ
description Abstract The main objective of this study is treatment and characterization of phosphorus from synthetic wastewater using aluminum electrodes in the electrocoagulation process. EC experimental setups were designed and different parameters were optimized. The maximum amounts of phosphorus removal efficiencies were observed at pH 7. The phosphorus removal efficiency increases from 85.16 to 97.65% as the temperature increases from 15 to 45 °C, beyond this temperature, there is small effect on removal efficiency. Pollutant removal efficiency increases with an increase in the electrolysis time. At lower initial concentrations the removal efficiencies reached to their maximum values while at the highest initial concentration, the phosphorus removal efficiency was decreased. The increase of current density improves the efficiency of phosphorus removal. Energy and aluminum consumption decreases with increasing initial concentration of phosphorus. Field Emission Scanning Electron Microscope (FESEM) image analysis demonstrated very fine structures for aluminum hydroxide/oxyhydroxides and aluminum phosphate. The existence of the different elemental composition in the sludge was proved by the help of Energy Dispersive X-ray Analysis (EDXS), indicating that the aluminum, oxygen and phosphorus were present in the product. From X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR) and Raman analyses of the sludge product, it is concluded that the chemical speciation of the by-products can be mostly aluminum hydroxide and aluminum phosphate.
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spelling doaj.art-86a39a6b391443089f8a74dcaf77b73e2022-12-22T00:55:11ZengBMCBMC Chemistry2661-801X2019-08-0113111410.1186/s13065-019-0628-1Treatment and characterization of phosphorus from synthetic wastewater using aluminum plate electrodes in the electrocoagulation processDessie Tibebe0Yezbie Kassa1Ashok N. Bhaskarwar2Department of Chemistry, College of Natural and Computational Sciences, University of GondarDepartment of Biology, College of Natural and Computational Sciences, University of GondarDepartment of Chemical Engineering, Institute of Indian Technology DelhiAbstract The main objective of this study is treatment and characterization of phosphorus from synthetic wastewater using aluminum electrodes in the electrocoagulation process. EC experimental setups were designed and different parameters were optimized. The maximum amounts of phosphorus removal efficiencies were observed at pH 7. The phosphorus removal efficiency increases from 85.16 to 97.65% as the temperature increases from 15 to 45 °C, beyond this temperature, there is small effect on removal efficiency. Pollutant removal efficiency increases with an increase in the electrolysis time. At lower initial concentrations the removal efficiencies reached to their maximum values while at the highest initial concentration, the phosphorus removal efficiency was decreased. The increase of current density improves the efficiency of phosphorus removal. Energy and aluminum consumption decreases with increasing initial concentration of phosphorus. Field Emission Scanning Electron Microscope (FESEM) image analysis demonstrated very fine structures for aluminum hydroxide/oxyhydroxides and aluminum phosphate. The existence of the different elemental composition in the sludge was proved by the help of Energy Dispersive X-ray Analysis (EDXS), indicating that the aluminum, oxygen and phosphorus were present in the product. From X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR) and Raman analyses of the sludge product, it is concluded that the chemical speciation of the by-products can be mostly aluminum hydroxide and aluminum phosphate.http://link.springer.com/article/10.1186/s13065-019-0628-1Wastewater treatmentElectrocoagulationCharacterizationAluminum electrode
spellingShingle Dessie Tibebe
Yezbie Kassa
Ashok N. Bhaskarwar
Treatment and characterization of phosphorus from synthetic wastewater using aluminum plate electrodes in the electrocoagulation process
BMC Chemistry
Wastewater treatment
Electrocoagulation
Characterization
Aluminum electrode
title Treatment and characterization of phosphorus from synthetic wastewater using aluminum plate electrodes in the electrocoagulation process
title_full Treatment and characterization of phosphorus from synthetic wastewater using aluminum plate electrodes in the electrocoagulation process
title_fullStr Treatment and characterization of phosphorus from synthetic wastewater using aluminum plate electrodes in the electrocoagulation process
title_full_unstemmed Treatment and characterization of phosphorus from synthetic wastewater using aluminum plate electrodes in the electrocoagulation process
title_short Treatment and characterization of phosphorus from synthetic wastewater using aluminum plate electrodes in the electrocoagulation process
title_sort treatment and characterization of phosphorus from synthetic wastewater using aluminum plate electrodes in the electrocoagulation process
topic Wastewater treatment
Electrocoagulation
Characterization
Aluminum electrode
url http://link.springer.com/article/10.1186/s13065-019-0628-1
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AT yezbiekassa treatmentandcharacterizationofphosphorusfromsyntheticwastewaterusingaluminumplateelectrodesintheelectrocoagulationprocess
AT ashoknbhaskarwar treatmentandcharacterizationofphosphorusfromsyntheticwastewaterusingaluminumplateelectrodesintheelectrocoagulationprocess