One-step synthesis of FeSe0.45Te0.55 single crystals without excess Fe content

Excess interstitial Fe atoms in as-grown FeSe1−xTex single crystals are unavoidable in the self-flux growing procedure. As harmful defects to the study of superconductivity and Majorana fermions, the excess Fe atoms are usually removed by the post-annealing procedure. This two-step method is mostly...

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Bibliographic Details
Main Authors: Shuting Huang, Yubing Tu, Guanglei Han, Zhen Liu, Mingsheng Long, Xingyuan Hou, Tao Han, Lei Shan
Format: Article
Language:English
Published: AIP Publishing LLC 2022-04-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/5.0090367
Description
Summary:Excess interstitial Fe atoms in as-grown FeSe1−xTex single crystals are unavoidable in the self-flux growing procedure. As harmful defects to the study of superconductivity and Majorana fermions, the excess Fe atoms are usually removed by the post-annealing procedure. This two-step method is mostly used to obtain high quality FeSe1−xTex single crystals in present studies. Here, we carried out a one-step way to synthesize FeSe1−xTex single crystals without excess Fe content using a chemical vapor transport method. By combining transport measurement, magnetic measurement, and local scanning tunneling microscopy measurement, we prove that there is no excess Fe content in our one-step grown FeSe0.45Te0.55 single crystals. This work provides a new convenient way to obtain pure FeSe0.45Te0.55 single crystals and may be helpful to better study this exotic material.
ISSN:2158-3226