catena-Poly[[bis[4-(dimethylamino)pyridine-κN1]cobalt(II)]-di-μ-azido-κ4N1:N3]
The title layered polymer, [Co(N3)2(C7H10N2)2]n, contains CoII, azide and 4-(dimethylamino)pyridine (4-DMAP) species with site symmetries m2m, 2 and m, respectively. The Co2+ ion adopts an octahedral coordination geometry in which four N atoms from azide ligands lie in the equatorial plane and two 4...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813005205 |
| _version_ | 1818997391588589568 |
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| author | Hocine Merazig Lamia Bendjeddou Nasreddine Hadjadj Ouahida Zeghouan Fatiha Guenifa |
| author_facet | Hocine Merazig Lamia Bendjeddou Nasreddine Hadjadj Ouahida Zeghouan Fatiha Guenifa |
| author_sort | Hocine Merazig |
| collection | DOAJ |
| description | The title layered polymer, [Co(N3)2(C7H10N2)2]n, contains CoII, azide and 4-(dimethylamino)pyridine (4-DMAP) species with site symmetries m2m, 2 and m, respectively. The Co2+ ion adopts an octahedral coordination geometry in which four N atoms from azide ligands lie in the equatorial plane and two 4-DMAP N atoms occupy the axial positions. The CoII atoms are connected by two bridging azide ligands, resulting in a chain parallel to the c axis. |
| first_indexed | 2024-12-20T21:44:53Z |
| format | Article |
| id | doaj.art-86b0f50fbe5c4834a1d2cafadafb8f10 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T21:44:53Z |
| publishDate | 2013-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-86b0f50fbe5c4834a1d2cafadafb8f102022-12-21T19:25:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-03-01693m175m17510.1107/S1600536813005205catena-Poly[[bis[4-(dimethylamino)pyridine-κN1]cobalt(II)]-di-μ-azido-κ4N1:N3]Hocine MerazigLamia BendjeddouNasreddine HadjadjOuahida ZeghouanFatiha GuenifaThe title layered polymer, [Co(N3)2(C7H10N2)2]n, contains CoII, azide and 4-(dimethylamino)pyridine (4-DMAP) species with site symmetries m2m, 2 and m, respectively. The Co2+ ion adopts an octahedral coordination geometry in which four N atoms from azide ligands lie in the equatorial plane and two 4-DMAP N atoms occupy the axial positions. The CoII atoms are connected by two bridging azide ligands, resulting in a chain parallel to the c axis.http://scripts.iucr.org/cgi-bin/paper?S1600536813005205 |
| spellingShingle | Hocine Merazig Lamia Bendjeddou Nasreddine Hadjadj Ouahida Zeghouan Fatiha Guenifa catena-Poly[[bis[4-(dimethylamino)pyridine-κN1]cobalt(II)]-di-μ-azido-κ4N1:N3] Acta Crystallographica Section E |
| title | catena-Poly[[bis[4-(dimethylamino)pyridine-κN1]cobalt(II)]-di-μ-azido-κ4N1:N3] |
| title_full | catena-Poly[[bis[4-(dimethylamino)pyridine-κN1]cobalt(II)]-di-μ-azido-κ4N1:N3] |
| title_fullStr | catena-Poly[[bis[4-(dimethylamino)pyridine-κN1]cobalt(II)]-di-μ-azido-κ4N1:N3] |
| title_full_unstemmed | catena-Poly[[bis[4-(dimethylamino)pyridine-κN1]cobalt(II)]-di-μ-azido-κ4N1:N3] |
| title_short | catena-Poly[[bis[4-(dimethylamino)pyridine-κN1]cobalt(II)]-di-μ-azido-κ4N1:N3] |
| title_sort | catena poly bis 4 dimethylamino pyridine 954 n1 cobalt ii di 956 azido 954 4n1 n3 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813005205 |
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