Temperature-Dependent Double-Step CO Occlusion of KCO under Moist Conditions
In this study, CO 2 occlusion of K 2 CO 3 was examined at different temperatures under moist conditions. The CO 2 occlusion rate increased with increasing temperatures, whereas the saturated occlusion amount decreased. The highest occlusion amount (i.e. 6.48 mmol·g −1 ) was obtained at 313 K. Result...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
SAGE Publications
2015-03-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1260/0263-6174.33.3.243 |
| _version_ | 1797288977261133824 |
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| author | Hideyuki Chioyama Hongchao Luo Tomonori Ohba Hirofumi Kanoh |
| author_facet | Hideyuki Chioyama Hongchao Luo Tomonori Ohba Hirofumi Kanoh |
| author_sort | Hideyuki Chioyama |
| collection | DOAJ |
| description | In this study, CO 2 occlusion of K 2 CO 3 was examined at different temperatures under moist conditions. The CO 2 occlusion rate increased with increasing temperatures, whereas the saturated occlusion amount decreased. The highest occlusion amount (i.e. 6.48 mmol·g −1 ) was obtained at 313 K. Results of X-ray powder diffraction analysis showed that the formation of bicarbonate as a result of the K 2 CO 3 decomposition with CO 2 and H 2 O involved two reactions with K 4 H 2 (CO 3 ) 3 ·1.5H 2 O as an intermediate. It was determined that the lower saturated occlusion amount at higher temperatures originated from the exothermic property of the second reaction. Because the equilibrium constant for the bicarbonate formation is smaller at higher temperatures, the reaction does not proceed as quickly or efficiently according to Le Châtelier's principle. Therefore, the CO 2 occlusion of K 2 CO 3 is suitable for the saturated occlusion amount at lower temperatures. |
| first_indexed | 2024-03-07T18:57:28Z |
| format | Article |
| id | doaj.art-86bf18f9d6e94ea587864591fb15b98f |
| institution | Directory Open Access Journal |
| issn | 0263-6174 2048-4038 |
| language | English |
| last_indexed | 2024-03-07T18:57:28Z |
| publishDate | 2015-03-01 |
| publisher | SAGE Publications |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj.art-86bf18f9d6e94ea587864591fb15b98f2024-03-02T00:07:34ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40382015-03-013310.1260/0263-6174.33.3.243Temperature-Dependent Double-Step CO Occlusion of KCO under Moist ConditionsHideyuki ChioyamaHongchao LuoTomonori OhbaHirofumi KanohIn this study, CO 2 occlusion of K 2 CO 3 was examined at different temperatures under moist conditions. The CO 2 occlusion rate increased with increasing temperatures, whereas the saturated occlusion amount decreased. The highest occlusion amount (i.e. 6.48 mmol·g −1 ) was obtained at 313 K. Results of X-ray powder diffraction analysis showed that the formation of bicarbonate as a result of the K 2 CO 3 decomposition with CO 2 and H 2 O involved two reactions with K 4 H 2 (CO 3 ) 3 ·1.5H 2 O as an intermediate. It was determined that the lower saturated occlusion amount at higher temperatures originated from the exothermic property of the second reaction. Because the equilibrium constant for the bicarbonate formation is smaller at higher temperatures, the reaction does not proceed as quickly or efficiently according to Le Châtelier's principle. Therefore, the CO 2 occlusion of K 2 CO 3 is suitable for the saturated occlusion amount at lower temperatures.https://doi.org/10.1260/0263-6174.33.3.243 |
| spellingShingle | Hideyuki Chioyama Hongchao Luo Tomonori Ohba Hirofumi Kanoh Temperature-Dependent Double-Step CO Occlusion of KCO under Moist Conditions Adsorption Science & Technology |
| title | Temperature-Dependent Double-Step CO Occlusion of KCO under Moist Conditions |
| title_full | Temperature-Dependent Double-Step CO Occlusion of KCO under Moist Conditions |
| title_fullStr | Temperature-Dependent Double-Step CO Occlusion of KCO under Moist Conditions |
| title_full_unstemmed | Temperature-Dependent Double-Step CO Occlusion of KCO under Moist Conditions |
| title_short | Temperature-Dependent Double-Step CO Occlusion of KCO under Moist Conditions |
| title_sort | temperature dependent double step co occlusion of kco under moist conditions |
| url | https://doi.org/10.1260/0263-6174.33.3.243 |
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