May the Piezoresistivity of GNP-Modified Cement Mortar Be Related to Its Fractal Structure?

High piezoresistivity of cement-based composites tuned by conductible fillers provides a feasible way to develop self-sensing smart structures and buildings. However, the microstructural mechanisms remain to be properly understood. In the present work, the piezoresistivity of cement mortar with diff...

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Main Authors: Nanxi Dang, Jin Tao, Qiang Zeng, Weijian Zhao
Format: Article
Language:English
Published: MDPI AG 2021-09-01
Series:Fractal and Fractional
Subjects:
Online Access:https://www.mdpi.com/2504-3110/5/4/148
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author Nanxi Dang
Jin Tao
Qiang Zeng
Weijian Zhao
author_facet Nanxi Dang
Jin Tao
Qiang Zeng
Weijian Zhao
author_sort Nanxi Dang
collection DOAJ
description High piezoresistivity of cement-based composites tuned by conductible fillers provides a feasible way to develop self-sensing smart structures and buildings. However, the microstructural mechanisms remain to be properly understood. In the present work, the piezoresistivity of cement mortar with different dosages of graphene nanoplatelets (GNPs) was investigated, and the microstructure was assessed by electron scanning microscopy (SEM) and mercury intrusion porosimetry (MIP). Two surface fractal models were introduced to interpret the MIP data to explore the multi-scale fractal structure of the GNP-modified cement mortars. Results show that the incorporation of GNPs into cement mortar can roughen the fracture surfaces due to the GNPs’ agglomeration. Gauge factor (GF) rises and falls as GNP content increases from 0% to 1% with the optimal piezoresistivity observed at GNP = 0.1% and 0.05%. The GF values of the optimum mortar are over 50 times higher than those of the reference mortar. Fractal dimensions in macro and micro fractal regions change with GNP content. Analysis shows that the fractal dimensions in micro region decrease first and then increase with the increase of GF values. GNPs not only impact the fractal structure of cement mortar, but also alter the tunneling and contact effects that govern the piezoresistivity of composite materials.
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spelling doaj.art-86f51688d5c344ecb3d18850c7f524562023-11-23T08:22:55ZengMDPI AGFractal and Fractional2504-31102021-09-015414810.3390/fractalfract5040148May the Piezoresistivity of GNP-Modified Cement Mortar Be Related to Its Fractal Structure?Nanxi Dang0Jin Tao1Qiang Zeng2Weijian Zhao3College of Civil Engineering and Architecture, Zhejiang University, Hangzhou 310058, ChinaCollege of Civil Engineering and Architecture, Zhejiang University, Hangzhou 310058, ChinaCollege of Civil Engineering and Architecture, Zhejiang University, Hangzhou 310058, ChinaCollege of Civil Engineering and Architecture, Zhejiang University, Hangzhou 310058, ChinaHigh piezoresistivity of cement-based composites tuned by conductible fillers provides a feasible way to develop self-sensing smart structures and buildings. However, the microstructural mechanisms remain to be properly understood. In the present work, the piezoresistivity of cement mortar with different dosages of graphene nanoplatelets (GNPs) was investigated, and the microstructure was assessed by electron scanning microscopy (SEM) and mercury intrusion porosimetry (MIP). Two surface fractal models were introduced to interpret the MIP data to explore the multi-scale fractal structure of the GNP-modified cement mortars. Results show that the incorporation of GNPs into cement mortar can roughen the fracture surfaces due to the GNPs’ agglomeration. Gauge factor (GF) rises and falls as GNP content increases from 0% to 1% with the optimal piezoresistivity observed at GNP = 0.1% and 0.05%. The GF values of the optimum mortar are over 50 times higher than those of the reference mortar. Fractal dimensions in macro and micro fractal regions change with GNP content. Analysis shows that the fractal dimensions in micro region decrease first and then increase with the increase of GF values. GNPs not only impact the fractal structure of cement mortar, but also alter the tunneling and contact effects that govern the piezoresistivity of composite materials.https://www.mdpi.com/2504-3110/5/4/148graphenemortarpiezoresistivityfractal dimensionmodel
spellingShingle Nanxi Dang
Jin Tao
Qiang Zeng
Weijian Zhao
May the Piezoresistivity of GNP-Modified Cement Mortar Be Related to Its Fractal Structure?
Fractal and Fractional
graphene
mortar
piezoresistivity
fractal dimension
model
title May the Piezoresistivity of GNP-Modified Cement Mortar Be Related to Its Fractal Structure?
title_full May the Piezoresistivity of GNP-Modified Cement Mortar Be Related to Its Fractal Structure?
title_fullStr May the Piezoresistivity of GNP-Modified Cement Mortar Be Related to Its Fractal Structure?
title_full_unstemmed May the Piezoresistivity of GNP-Modified Cement Mortar Be Related to Its Fractal Structure?
title_short May the Piezoresistivity of GNP-Modified Cement Mortar Be Related to Its Fractal Structure?
title_sort may the piezoresistivity of gnp modified cement mortar be related to its fractal structure
topic graphene
mortar
piezoresistivity
fractal dimension
model
url https://www.mdpi.com/2504-3110/5/4/148
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AT qiangzeng maythepiezoresistivityofgnpmodifiedcementmortarberelatedtoitsfractalstructure
AT weijianzhao maythepiezoresistivityofgnpmodifiedcementmortarberelatedtoitsfractalstructure