(1,10-Phenanthroline-κ2N,N′)bis(2,2,6,6-tetramethylheptane-3,5-dionato-κ2O,O′)nickel(II)
The title compound, [Ni(C11H19O2)2(C12H8N2)], was obtained from the reaction of bis(2,2,6,6-tetramethylheptane-3,5-dionato)nickel(II), [Ni(dpm)], and 1,10-phenanthroline (phen). The NiII ion is coordinated by four O atoms from two dpm ligands and two N atoms from a phen ligand in a slightly distorte...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680706672X |
| _version_ | 1819121829666619392 |
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| author | Branko Kaitner Krešo Mesarek Ernest Meštrović |
| author_facet | Branko Kaitner Krešo Mesarek Ernest Meštrović |
| author_sort | Branko Kaitner |
| collection | DOAJ |
| description | The title compound, [Ni(C11H19O2)2(C12H8N2)], was obtained from the reaction of bis(2,2,6,6-tetramethylheptane-3,5-dionato)nickel(II), [Ni(dpm)], and 1,10-phenanthroline (phen). The NiII ion is coordinated by four O atoms from two dpm ligands and two N atoms from a phen ligand in a slightly distorted octahedral environment. The methyl C atoms of two of the tert-butyl groups are disordered over two sites, having approximate occupancies of 0.85 and 0.15 for the two components. In the crystal structure, there are no direction-specific interactions. Thermal studies showed that the title complex is stable to 623 K. |
| first_indexed | 2024-12-22T06:42:47Z |
| format | Article |
| id | doaj.art-870b69b170554538b20311fee3207b00 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T06:42:47Z |
| publishDate | 2008-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-870b69b170554538b20311fee3207b002022-12-21T18:35:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m230m23110.1107/S160053680706672X(1,10-Phenanthroline-κ2N,N′)bis(2,2,6,6-tetramethylheptane-3,5-dionato-κ2O,O′)nickel(II)Branko KaitnerKrešo MesarekErnest MeštrovićThe title compound, [Ni(C11H19O2)2(C12H8N2)], was obtained from the reaction of bis(2,2,6,6-tetramethylheptane-3,5-dionato)nickel(II), [Ni(dpm)], and 1,10-phenanthroline (phen). The NiII ion is coordinated by four O atoms from two dpm ligands and two N atoms from a phen ligand in a slightly distorted octahedral environment. The methyl C atoms of two of the tert-butyl groups are disordered over two sites, having approximate occupancies of 0.85 and 0.15 for the two components. In the crystal structure, there are no direction-specific interactions. Thermal studies showed that the title complex is stable to 623 K.http://scripts.iucr.org/cgi-bin/paper?S160053680706672X |
| spellingShingle | Branko Kaitner Krešo Mesarek Ernest Meštrović (1,10-Phenanthroline-κ2N,N′)bis(2,2,6,6-tetramethylheptane-3,5-dionato-κ2O,O′)nickel(II) Acta Crystallographica Section E |
| title | (1,10-Phenanthroline-κ2N,N′)bis(2,2,6,6-tetramethylheptane-3,5-dionato-κ2O,O′)nickel(II) |
| title_full | (1,10-Phenanthroline-κ2N,N′)bis(2,2,6,6-tetramethylheptane-3,5-dionato-κ2O,O′)nickel(II) |
| title_fullStr | (1,10-Phenanthroline-κ2N,N′)bis(2,2,6,6-tetramethylheptane-3,5-dionato-κ2O,O′)nickel(II) |
| title_full_unstemmed | (1,10-Phenanthroline-κ2N,N′)bis(2,2,6,6-tetramethylheptane-3,5-dionato-κ2O,O′)nickel(II) |
| title_short | (1,10-Phenanthroline-κ2N,N′)bis(2,2,6,6-tetramethylheptane-3,5-dionato-κ2O,O′)nickel(II) |
| title_sort | 1 10 phenanthroline 954 2n n 8242 bis 2 2 6 6 tetramethylheptane 3 5 dionato 954 2o o 8242 nickel ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053680706672X |
| work_keys_str_mv | AT brankokaitner 110phenanthroline9542nn8242bis2266tetramethylheptane35dionato9542oo8242nickelii AT kre353omesarek 110phenanthroline9542nn8242bis2266tetramethylheptane35dionato9542oo8242nickelii AT ernestme353trovi263 110phenanthroline9542nn8242bis2266tetramethylheptane35dionato9542oo8242nickelii |