Hydrocracking of Calophyllum inophyllum Oil Employing Co and/or Mo Supported on γ-Al2O3 for Biofuel Production
Cobalt and/or Molybdenum based catalysts were simply dispersed on γ-Al2O3 through wet impregnation. The set of prepared monometallic and bimetallic catalysts of aCoO/γ-Al2O3, aMoO/γ-Al2O3, aCoOaMoO/γ-Al2O3, and bCoObMoO/γ-Al2O3 were investigated and evaluated in the hydrocracking of Calophyllum inop...
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| Format: | Article |
| Language: | English |
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Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
2020-12-01
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| Series: | Bulletin of Chemical Reaction Engineering & Catalysis |
| Subjects: | |
| Online Access: | https://journal.bcrec.id/index.php/bcrec/article/view/8592 |
| _version_ | 1797677831248936960 |
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| author | Wega Trisunaryanti Triyono Triyono Mohammad Ali Ghoni Dyah Ayu Fatmawati Puspa Nindro Mahayuwati Endah Suarsih |
| author_facet | Wega Trisunaryanti Triyono Triyono Mohammad Ali Ghoni Dyah Ayu Fatmawati Puspa Nindro Mahayuwati Endah Suarsih |
| author_sort | Wega Trisunaryanti |
| collection | DOAJ |
| description | Cobalt and/or Molybdenum based catalysts were simply dispersed on γ-Al2O3 through wet impregnation. The set of prepared monometallic and bimetallic catalysts of aCoO/γ-Al2O3, aMoO/γ-Al2O3, aCoOaMoO/γ-Al2O3, and bCoObMoO/γ-Al2O3 were investigated and evaluated in the hydrocracking of Calophyllum inophyllum (CIO) which is not a food crop as well as rich in unsaturated fatty acid that potential to be converted into biofuel. Out of the prepared catalysts, aCoOaMoO/γ-Al2O3 with total metal content, acidity, and specific surface area of 13.62 wt%, 5.01 mmol.g-1, and 107.67 m2.g-1, respectively, showed the best catalytic performance. The high metal loading of aCoOaMoO/γ-Al2O3is favorable by producing 65.56 wt% liquid fraction through carbocation formation mechanism. It was selective to produce 8.61 wt% gasoline and 5.01 wt% diesel. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). |
| first_indexed | 2024-03-11T22:50:50Z |
| format | Article |
| id | doaj.art-87293a2a3b8d402f8f708bc01189557d |
| institution | Directory Open Access Journal |
| issn | 1978-2993 |
| language | English |
| last_indexed | 2024-03-11T22:50:50Z |
| publishDate | 2020-12-01 |
| publisher | Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) |
| record_format | Article |
| series | Bulletin of Chemical Reaction Engineering & Catalysis |
| spelling | doaj.art-87293a2a3b8d402f8f708bc01189557d2023-09-22T03:39:13ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932020-12-0115374375110.9767/bcrec.15.3.8592.743-7514088Hydrocracking of Calophyllum inophyllum Oil Employing Co and/or Mo Supported on γ-Al2O3 for Biofuel ProductionWega Trisunaryanti0Triyono Triyono1Mohammad Ali Ghoni2Dyah Ayu Fatmawati3Puspa Nindro Mahayuwati4Endah Suarsih5Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, IndonesiaChemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, IndonesiaChemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, IndonesiaChemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, IndonesiaChemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, IndonesiaChemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, IndonesiaCobalt and/or Molybdenum based catalysts were simply dispersed on γ-Al2O3 through wet impregnation. The set of prepared monometallic and bimetallic catalysts of aCoO/γ-Al2O3, aMoO/γ-Al2O3, aCoOaMoO/γ-Al2O3, and bCoObMoO/γ-Al2O3 were investigated and evaluated in the hydrocracking of Calophyllum inophyllum (CIO) which is not a food crop as well as rich in unsaturated fatty acid that potential to be converted into biofuel. Out of the prepared catalysts, aCoOaMoO/γ-Al2O3 with total metal content, acidity, and specific surface area of 13.62 wt%, 5.01 mmol.g-1, and 107.67 m2.g-1, respectively, showed the best catalytic performance. The high metal loading of aCoOaMoO/γ-Al2O3is favorable by producing 65.56 wt% liquid fraction through carbocation formation mechanism. It was selective to produce 8.61 wt% gasoline and 5.01 wt% diesel. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).https://journal.bcrec.id/index.php/bcrec/article/view/8592cobaltmolybdenumγ-al2o3hydrocrackingcalophyllum inophyllum |
| spellingShingle | Wega Trisunaryanti Triyono Triyono Mohammad Ali Ghoni Dyah Ayu Fatmawati Puspa Nindro Mahayuwati Endah Suarsih Hydrocracking of Calophyllum inophyllum Oil Employing Co and/or Mo Supported on γ-Al2O3 for Biofuel Production Bulletin of Chemical Reaction Engineering & Catalysis cobalt molybdenum γ-al2o3 hydrocracking calophyllum inophyllum |
| title | Hydrocracking of Calophyllum inophyllum Oil Employing Co and/or Mo Supported on γ-Al2O3 for Biofuel Production |
| title_full | Hydrocracking of Calophyllum inophyllum Oil Employing Co and/or Mo Supported on γ-Al2O3 for Biofuel Production |
| title_fullStr | Hydrocracking of Calophyllum inophyllum Oil Employing Co and/or Mo Supported on γ-Al2O3 for Biofuel Production |
| title_full_unstemmed | Hydrocracking of Calophyllum inophyllum Oil Employing Co and/or Mo Supported on γ-Al2O3 for Biofuel Production |
| title_short | Hydrocracking of Calophyllum inophyllum Oil Employing Co and/or Mo Supported on γ-Al2O3 for Biofuel Production |
| title_sort | hydrocracking of calophyllum inophyllum oil employing co and or mo supported on γ al2o3 for biofuel production |
| topic | cobalt molybdenum γ-al2o3 hydrocracking calophyllum inophyllum |
| url | https://journal.bcrec.id/index.php/bcrec/article/view/8592 |
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